套箍加固RC轴压中长柱的承载力理论研究∗

为研究套箍加固RC轴压中长柱的承载力理论计算分析方法,采用切线模量理论,根据材料本构关系和内外力平衡条件,推导了套箍加固RC轴压中长柱的弹塑性稳定承载力计算方法。将理论计算结果与试验结果进行了对比分析,结果表明:理论计算值均低于实测值,且二者的偏差在15%以内。根据所推导的计算分析方法,研究了核心柱初始荷载水平β、柱子长细比l0/b、套箍层混凝土强度、套箍层配筋量四种参数对加固柱承载力Nu的影响规律,结果表明:Nu总体上随β增大而减小,当β<0.7时,减小趋势不够明显,β>0.7后,减小趋势变得明显;l0/b对Nu有明显影响,Nu随l0/b的增大而减小,但二者不是线性关系;Nu随套箍层混凝土强度提高而增大,随套箍层配筋量增大而增大。     

酸预处理对整体式催化剂载体性能的影响研究

通过使用不同浓度,不同类型的酸溶液,在不同条件下对堇青石载体进行预处理,考察了酸预处理前后载体本征性能的改变和对甲苯催化性能的影响,测试了其失重率,吸水率,上载率本征性能,并通过XRF,BET,SEM等手段进行表征测试分析.结果发现,通过使用20% HCl对堇青石载体进行加热处理3h,可获得最优性能的堇青石载体.吸水率较处理前可提升48.0%以上,活性组分上载率可达14.5%,皮尔逊检验表明吸水率与上载率存在中度正相关的相关性.通过对甲苯催化活性测试,其结果表明,通过酸预处理,堇青石载体比表面积提升10倍以上,由其制得的整体式催化剂催化降解甲苯的T₁₀和T₉₀分别为142和200℃.     

蜂窝陶瓷固定化细胞气升式内循环生物反应器的水力学特性

在鼓泡塔式 (BubbleColumns ,BC)和气升式循环 (AirliftLoop ,AL)生物反应器基础上 ,于内循环管中加装蜂窝陶瓷载体 ,开发出蜂窝陶瓷固定化细胞的气升式内循环生物反应器 (Internal Airlift Loop Bioreactor with Cells Immobilized onto Ceramic Honeycomb Support,IALBR-CICHS) .采用示踪技术通过测定反应器的水力停留时间分布来考察上述 3种反应器的有效工作体积和反应器内走旁路流体的比例 .实验和理论分析表明 ,IALBR-CICHS可大大提高反应器的有效工作体积 ,减少流体走旁路的比例 .     

双酚A分子印迹聚合物的制备及其在水相中的吸附性能

以双酚A (BPA)为模板分子,α-甲基丙烯酸为功能单体,二乙烯基苯为交联剂,偶氮二异丁腈为引发剂,甲苯为溶剂,沉淀聚合法制备了BPA的分子印迹聚合物(MIPs).聚合物在BPA超纯水溶液中的吸附实验结果表明,MIPs对BPA的吸附量和吸附速率大于非印迹聚合物.通过Scatchard分析,MIPs对BPA的最大表观吸附...     

泡沫活性炭的制备及其对丙酮的吸附性能研究

以中间相沥青和原煤为原料,在高温高压下发泡成型,经过高温炭化和水蒸气活化后制得了比表面积为672m2/g、中孔发达的泡沫状成型活性炭(MACFoam).该成型活性炭中含有大量的微米级孔道并具有良好的透气性,可以作为气流通道.由其所装填的吸附床层对丙酮的吸附行为与颗粒活性炭相似,可以使用Yoon-Nelson方程对实验穿...     

Stability of titania nanoparticles in soil suspensions and transport in saturated homogeneous soil columns

The stability of TiO₂ nanoparticles in soil suspensions and their transport behavior through saturated homogeneous soil columns were studied. The results showed that TiO₂ could remain suspended in soil suspensions even after settling for 10 days. The suspended TiO₂ contents in soil suspensions after 24 h were positively correlated with the dissolved organic carbon and clay content of the soils, but were negatively correlated with ionic strength, pH and zeta potential. In soils containing soil particles of relatively large diameters and lower solution ionic strengths, a significant portion of the TiO₂ (18.8-83.0%) readily passed through the soils columns, while TiO₂ was significantly retained by soils with higher clay contents and salinity. TiO₂ aggregate sizes in the column outflow significantly increased after passing through the soil columns. The estimated transport distances of TiO₂ in some soils ranged from 41.3 to 370 cm, indicating potential environmental risk of TiO₂ nanoparticles to deep soil layers.     

火灾下型钢混凝土异形柱温度场分析

为了分析型钢混凝土异形柱的耐火极限及火灾后的力学性能,为试验研究做好充分的前期准备,本文采用有限元分析软件ANSYS对型钢混凝土异形柱截面温度场进行数值模拟,得出了柱截面在不均匀受火情况下的温度场分布规律。结果表明,在两面受火的情况下,L形柱的凹角处的温升低于其它部位;由于型钢的存在,加快了柱截面内部温度的热传导;距离受火面相同的深度处的混凝土与型钢的温度不同,因此有必要研究损伤差异对承载力和两者粘结滑移造成的影响。     

Impact of repeated pesticide applications on the binding and release of methyl 14C-monocrotophos and U-ring labelled 14C-carbaryl to soil matrices under field conditions

The dissipation of (O-methyl-¹⁴C) monocrotophos and U-ring labelled ¹⁴C-carbaryl was monitored for over two years in absence and presence of other insecticides using in situ soil columns. The dissipation of ¹⁴C-monocrotophos from soil treated with methomyl and carbaryl showed a faster rate of downward movement than in a control column tagged with the labelled insecticide alone. The same trend was observed in experiments with ¹⁴C-carbaryl that dissipated more readily in soil treated with non-labelled monocrotophos and methomyl. In the presence of other insecticides the percentage of bound residues was generally lower than in control experiments. The bound residues at the top of the column are released at a low rate under conditions prevailing in the field. The overall time required for dissipation of 50% of monocrotophos and carbaryl (t₅₀) as estimated from control experiment was approximately 20 and 24 weeks, respectively. The data indicate that repeated applications of pesticides might enhance the release of ¹⁴C-bound residues.     

Removal of phenolic estrogen pollutants from different sources of water using molecularly imprinted polymeric microspheres

The efficiency and effects of using Bisphenol A-molecularly imprinted polymeric microspheres (MIPMs) to remove phenolic estrogens from different sources of water were evaluated. MIPMs prepared by precipitation polymerization removed a group of phenolic estrogens from different kinds of water selectively and effectively. The highest removal efficiency was observed at pH=5. Fifty millimoles per litre ions or 10mg/L humid acid improved removal efficiency. MIPMs were more suitable to remove trace estrogens in large volume than high concentration of estrogens in small volume. The removal efficiency of spiked tap water, lake water and river water were better than that of distilled water. Hundred milligrams of MIPMs had higher removal selectivity and efficiency than those of 100mg or 300mg activated carbons. Moreover, MIPMs can be re-used for at least 30 times without losing any removal efficiency. MIPMs provided a selective, simple, reliable and practicable solution to remove trace phenolic estrogens from different sources of water.     

钢筋混凝土异形柱框架-短肢剪力墙结构振动台试验研究

异形柱框架-短肢剪力墙结构是介于异形柱框架和异形柱框架-剪力墙结构之间的一种新型结构体系。本文通过对一幢12层钢筋混凝土异形柱框架-短肢剪力墙结构1/7比例模型的地震模拟振动台试验,系统研究了该结构体系的动力特性、地震反应及破坏机理等。试验结果表明,该结构体系属于梁铰破坏机制,能满足延性设计要求,且具有良好的抗震性能和较强的抗震能力,达到了抗震设防标准。因此,该结构体系较适用于小高层住宅结构设计。