Evaluation of life cycle inventory data for recycling systems

This paper reviews databases on material recycling (primary as well as secondary production) used in life cycle assessments (LCA) of waste management systems. A total of 366 datasets, from 1980 to 2010 and covering 14 materials, were collected from databases and reports. Totals for CO₂-equivalent emissions were compared to illustrate variations in the data. It was hypothesised that emissions from material production and the recycling industry had decreased over time due to increasing regulation, energy costs and process optimisation, but the reported datasets did not reveal such a general trend. Data representing the same processes varied considerably between databases, and proper background information was hard to obtain, which in turn made it difficult to explain the large differences observed. Those differences between the highest and lowest estimated CO₂ emissions (equivalents) from the primary production of newsprint, HDPE and glass were 238%, 443% and 452%, respectively. For steel and aluminium the differences were 1761% and 235%, respectively. There is a severe lack of data for some recycled materials; for example, only one dataset existed for secondary cardboard. The study shows that the choice of dataset used to represent the environmental load of a material recycling process and credited emissions from the avoided production of virgin materials is crucial for the outcome of an LCA on waste management. Great care and a high degree of transparency are mandatory, but advice on which datasets to use could not be determined from the study. However, from the gathered data, recycling in general showed lower emission of CO₂ per kg material than primary production, so the recycling of materials (considered in this study) is thus beneficial in most cases.     

Comparisons of four categories of waste recycling in China's paper industry based on physical input-output life-cycle assessment model

Waste recycling for paper production is an important component of waste management. This study constructs a physical input-output life-cycle assessment (PIO-LCA) model. The PIO-LCA model is used to investigate environmental impacts of four categories of waste recycling in China’s paper industry: crop straws, bagasse, textile wastes and scrap paper. Crop straw recycling and wood utilization for paper production have small total intensity of environmental impacts. Moreover, environmental impacts reduction of crop straw recycling and wood utilization benefits the most from technology development. Thus, using crop straws and wood (including wood wastes) for paper production should be promoted. Technology development has small effects on environmental impacts reduction of bagasse recycling, textile waste recycling and scrap paper recycling. In addition, bagasse recycling and textile waste recycling have big total intensity of environmental impacts. Thus, the development of bagasse recycling and textile waste recycling should be properly limited. Other pathways for reusing bagasse and textile wastes should be explored and evaluated. Moreover, imports of scrap paper should be encouraged to reduce large indirect impacts of scrap paper recycling on domestic environment.     

制浆造纸行业二恶英问题的探讨

二恶英对环境的污染和对人类的危害已引起全世界的关注,而制浆造纸行业的漂白工艺也是产生二恶英的主要来源之一。本文论述了制浆造纸行业二恶英产生的现状及可能的防治措施,并就二恶英潜在的长期污染特性给出相应建议。     

印钞废水处理工艺的研究

通过对印钞废水的水质分析以有对印钞废水进行实验小试的基础上，提出了4条并行的小试工艺路线，经实验比较，结果表明，化学沉淀＋水解酸化＋好氧工艺流程为处理印钞废水的可行工艺，处理后的污水可以达标排放。     

Model-based direct search optimization of the broke recirculation system in a newsprint mill

This work is concerned with the dynamic modelling of the papermaking section of an integrated newsprint mill, and the subsequent application of two direct search methods in a proof-of-concept optimization study of broke recirculation strategies. The effect of the current broke recirculation policy on the mixed pulp properties at the paper machine headboxes was quantified using a dynamic simulation generating data for an objective function which reflected the rate of change in measurable (flow, consistency and temperature) and immeasurable (total dissolved solids and fibre length distribution) parameters. Genetic Algorithm and the Nelder–Mead simplex methods were then linked dynamically to the simulation and used to find improved ways of recirculating broke pulp. Specifically, the profile of the changes to the broke ratio was modelled using a quadratic function and a second-order transfer function, and the coefficients of these functions were optimized. The optimized broke recirculation resulted in a significant reduction in the value of the objective function, thus, suggesting that the fluctuations in the properties of the mixed pulp stream could be dampened and paper machine headbox stability improved. It is expected that this process enhancement strategy would contribute to an increase in production yield (via a reduction in the occurrence of paper machine breaks), and thus an overall reduction in the waste of materials and energy.     

造纸达标废水回用的实验研究

通过实验论证了造纸达标废水回用于生产或农灌的可行性，同时对各种回用方法存在的问题提出了相应的对策和建议，为造纸废水的排放去向提供了新思路。     

厌氧—好氧序列间歇式反应器处理造纸中段废水的研究

采用厌氧－好氧序列间歇反应器－混凝沉淀组合工艺，处理碱法草浆造纸中段废水。结果表明，经8.0h厌氧搅拌处理和5.0h好氧曝气处理，进水CODcr为729.1-2239mg/L，出水CODCr小于550mg/L，CODCr去除率在66.2%-76.3%之间，再经混凝沉淀处理，出水CODCr小于200mg/L，色度小于50倍，满足国家造纸工业水污染物排放标准中的二级标准。     

Current EU-27 technical potential of organic waste streams for biogas and energy production

Anaerobic digestion of organic waste generated by households, businesses, agriculture, and industry is an important approach as method of waste treatment – especially with regard to its potential as an alternative energy source and its cost-effectiveness. Separate collection of biowaste from households or vegetal waste from public green spaces is already established in some EU-27 countries. The material recovery in composting plants is common for biowaste and vegetal waste. Brewery waste fractions generated by beer production are often used for animal feeding after a suitable preparation. Waste streams from paper industry generated by pulp and paper production such as black liquor or paper sludge are often highly contaminated with toxic substances. Recovery of chemicals and the use in thermal processes like incineration, pyrolysis, and gasification are typical utilization paths. The current utilization of organic waste from households and institutions (without agricultural waste) was investigated for EU-27 countries with Germany as an in-depth example. Besides of biowaste little is known about the suitability of waste streams from brewery and paper industry for anaerobic digestion. Therefore, an evaluation of the most important biogas process parameters for different substrates was carried out, in order to calculate the biogas utilization potential of these waste quantities. Furthermore, a calculation of biogas energy potentials was carried out for defined waste fractions which are most suitable for anaerobic digestion. Up to 1% of the primary energy demand can be covered by the calculated total biogas energy potential. By using a “best-practice-scenario” for separately collected biowaste, the coverage of primary energy demand may be increased above 2% for several countries. By using sector-specific waste streams, for example the German paper industry could cover up to 4.7% and the German brewery industry up to 71.2% of its total energy demand.     

Management of treated pulp and paper mill effluent to achieve zero discharge

Pulp and paper mills are one of the major effluent generating industries in the world. In most cases, mill effluent (treated or raw) is discharged back into a river, creek, stream or other water body; resulting in negative environmental impacts, as well as social concerns, among the downstream users. Pulp and paper mill effluent management, which could result in zero discharge into downstream water bodies, would present the best management option to address socio-environmental concerns. This paper presents such an effort aimed at closing the water cycle by using treated effluent from the mill to irrigate forage and fodder crops for producing animals feed. The treated effluent is delivered from the mill through gravity into a winter storage dam of 490ML capacity. For irrigation applications on 110ha of farmland, which is 42% of the total farmland, the water is pumped from the winter storage dam to five individual paddocks with Centre Pivot (CP) irrigators and one rectangular paddock with a Soft Hose Travelling (SHT) irrigator. From October 2001 to June 2006, a total of 2651mm of wastewater was applied at the farm. The impact assessment results, obtained from field monitoring, investigations and analysis, indicated that the closed water cycle effluent management strategy described had resulted in a lessening of the impact on water resources usually associated with paper mills. However, social attitudes to the use of crops that have been irrigated with recycled waters and the resulting impact on market value of the produce may still be a major consideration.     

Application of recycled paper sludge and biomass materials in manufacture of green composite pallet

Rice straw, rice husk and paper sludge are by-products and industrial waste, and are beneficial resources as raw biomass materials used for manufacturing value-added composite products. We investigated the effect on selected mechanical properties of adding rice straw, rice husk and paper sludge to wood composites to replace wood particles for manufacturing green pallets. Results showed that increasing the contents of rice straw and rice husk dramatically decreased the mechanical strength of the composites. This is because the wax and silicate coating of these materials obstructed the strong bonding with UF resin. When 10 wt.% of wood particle was replaced with 10 wt.% of paper sludge, the wood–paper sludge composites showed similar mechanical properties to those of wood particle. Wood particle can be replaced by 10 wt.% of dried paper sludge in accordance with the minimum requirement recommended by standards in green pallet manufacturing.