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51.
Sana Ullah Xuejun Guo Xiaoyan Luo Xiangyuan Zhang Siwen Leng Na Ma Palwasha Faiz 《Frontiers of Environmental Science & Engineering》2020,14(5):89
52.
Nima Kamali Abdollah Rashidi Mehrabadi Maryam Mirabi Mohammad Ali Zahed 《Frontiers of Environmental Science & Engineering》2020,14(4):70
53.
Products and stability of phosphate reactions with lead under freeze-thaw cycling in simple systems 总被引:1,自引:0,他引:1
Hafsteinsdóttir EG White DA Gore DB Stark SC 《Environmental pollution (Barking, Essex : 1987)》2011,159(12):3496-3503
Orthophosphate fixation of metal contaminated soils in environments that undergo freeze-thaw cycles is understudied. Freeze-thaw cycling potentially influences the reaction rate, mineral chemical stability and physical breakdown of particles during fixation. This study determines what products form when phosphate (triple superphosphate [Ca(H2PO4)2] or sodium phosphate [Na3PO4]) reacts with lead (PbSO4 or PbCl2) in simple chemical systems in vitro, and assesses potential changes in formation during freeze-thaw cycles. Systems were subjected to multiple freeze-thaw cycles from +10 °C to −20 °C and then analysed by X-ray diffractometry. Pyromorphite formed in all systems and was stable over multiple freeze-thaw cycles. Low temperature lead orthophosphate reaction efficiency varied according to both phosphate and lead source; the most time-efficient pyromorphite formation was observed when PbSO4 and Na3PO4 were present together. These findings have implications for the manner in which metal contaminated materials in freezing ground can be treated with phosphate. 相似文献
54.
The effect of carbonate sediment in regulating phosphate concentrations in sea water was investigated by laboratory incubation experiments using different sediment types. Incubation experiments were made with two types of sediments: uncontaminated sediment from a marine reserve and contaminated sediment with deposited phosphate powders. Fluxes of inorganic nitrogen and phosphate were estimated from linear regressions of solute concentrations over incubation periods. Ammonium and phosphate fluxes were about twofold higher in the uncontaminated sediment that had significantly lower organic carbon and total phosphate concentrations than in the phosphate-contaminated sediment. To test the effect of dissolved phosphate on increasing nitrogen fixation, additional incubation experiments were carried out using treated carbonate and silicate sediments with added dissolved phosphate (20 μM). Incubations were made under sterile conditions with HgCl2 added to distinguish between biologically enhanced processes and pure physicochemical processes. The adsorption rate of phosphate onto carbonate sediment was about twice that onto silicate sediments. No nitrogen elevation either as ammonium or as nitrate was observed in the soluble phosphate enrichment incubations. In conclusion, this study demonstrates the importance of the regulation of soluble phosphate concentrations in carbonate sediment environments where the carbonate sediment acts as a buffering system keeping soluble phosphate concentrations at certain steady-state levels. The study also demonstrates the lack of evidence on enhancement of nitrogen concentrations due to the increase phosphate concentrations. 相似文献
55.
Organophosphonate, characterized by the presence of a stable, covalent, carbon to phosphorus (C-P) bond, is a group of synthetic or biogenic organophosphorus compounds. The fate of these organic phosphorus compounds in the environment is not well studied. This study presents the first investigation on the sorption of phosphorus (P) in the presence of two model phosphonate compounds, 2-aminothylphosphonoic acid (2-AEP) and phosphonoformic acid (PFA), on marine carbonate sediments. In contrast to other organic P compounds, no significant inorganic phosphate exchange was observed in seawater. P was found to adsorb on the sediment only in the presence of PFA, not 2-AEP. This indicated that sorption of P from phosphonate on marine sediment was compound specific. Compared with inorganic phosphate sorption on the same sediments, P sorption from organic phosphorus is much less in the marine environment. Further study is needed to understand the potential role of the organophosphonate compounds in biogeochemical cycle of phosphorus in the environment. 相似文献
56.
According to almost all forward-looking studies, the world′s energy consumption will increase in the future decades, mostly because of the growing world population and the long-term development of emerging countries. The effort to contain global warming makes it hard to exclude nuclear energy from the global energy mix. 相似文献
57.
In this study, the optimum conditions of dissolution of calcinated bone in HCl solutions with different concentrations are investigated. Recovery of phosphate from calcinated bone by dissolution with hydrochloric acid solutions was investigated in a batch reactor, it was observed that a 32% hydrochloric acid solution can dissolve the calcinated bone effectively. Using the Taguchi fractional design method, it was found that the optimum process conditions, at which 67.2% P2O5 dissolution was reached, were as follows: Reaction temperature: 318 K, solid-to-liquid ratio: 1/5 (g ml−1), acid concentrations:32 (% w/v), stirring speed:400 min−1 and reaction time: 60 min. 相似文献
58.
In this study, a copper-resistant plant growth promoting bacterial (PGPB) strain Ax10 was isolated from a Cu mine soil to assess its plant growth promotion and copper uptake in Brassica juncea. The strain Ax10 tolerated concentrations up to 600 mg CuL(-1) on a Luria-Bertani (LB) agar medium and utilized 1-aminocyclopropane-1-carboxylic acid (ACC) as a sole N source in DF salts minimal medium. The strain Ax10 was characterized as Achromobacter xylosoxidans based on its 16S rDNA sequence homology (99%). The bacterium A. xylosoxidans Ax10 has also exhibited the capability of producing indole acetic acid (IAA) (6.4 microg mL(-1)), and solubilizing inorganic phosphate (89.6 microg mL(-1)) in specific culture media. In pot experiments, inoculation of A. xylosoxidans Ax10 significantly increased the root length, shoot length, fresh weight and dry weight of B. juncea plants compared to the control. This effect can be attributed to the utilization of ACC, production of IAA and solubilization of phosphate. Furthermore, A. xylosoxidans Ax10 inoculation significantly improved Cu uptake by B. juncea. Owing to its wide action spectrum, the Cu-resistant A. xylosoxidans Ax10 could serve as an effective metal sequestering and growth promoting bioinoculant for plants in Cu-stressed soil. The present study has provided a new insight into the phytoremediation of Cu-contaminated soil. 相似文献
59.
Sisr L Mihaljevic M Ettler V Strnad L Sebek O 《Environmental monitoring and assessment》2007,135(1-3):465-473
The mobility of arsenic in Cambisol under the influence of added barnyard manure and application of a phosphate solution to
the soil was described on the basis of column experiments. A soil sample containing 126 mg/kg total As and 3.72 mg/kg specifically-sorbed
As was extracted using demineralized water (DIW) or a 28 μmol/l phosphate solution in a column containing untreated soil and
in a column with added barnyard fertilizer. The pH, Eh, alkalinity, main components, including DOC, and selected trace elements
(Al, Mn, Pb, Cu, Zn, Cd, Cr, Co, Ni, Ba and As) were determined in the extracts. Hydrodynamic tests of the flow and transport
of the substances in the columns were carried out. The addition of barnyard manure was manifested in elevated concentrations
of the main inorganic components, DOC and Al and a decrease in the Eh value and Mn concentration. Application of a phosphate
solution was manifested in a decrease in the NO3 and SO4 concentrations, probably as a result of the effect of increased biological fixation. The As concentration in extracts varied
from 8.8 to 15.5 μg/l and was not dependent on the composition of the extracting solution or the addition of barnyard fertilizer. 相似文献
60.
以纳米氢氧化钛(NTH)作为吸附水溶液中磷酸根的吸附剂,考察了NTH不同焙烧温度下的分子式及其对PO43-吸附效果的影响.选择PO43-初始浓度为50 mg/L,通过正交试验确定在pH=2、吸附剂用量为0.1g、吸附时间为40min、温度25℃时,NTH吸附效果达到最佳,吸附量为55.5 mg/g,经200、300、400及500℃焙烧后的NTH对磷酸根的吸附量逐渐减小;吸附量分别为494、40.6、25.5及16.8 mg/g;NTH经800℃焙烧后,焙烧产物TiO2不具有吸附性.TG、XRD分析表明随着焙烧温度的升高,NTH的表面活性基团(-OH)数量逐渐减少.结果表明,吸附剂的吸附性与吸附剂表面羟基的数量有直接关系. 相似文献