全文获取类型
收费全文 | 425篇 |
免费 | 41篇 |
国内免费 | 168篇 |
专业分类
安全科学 | 93篇 |
废物处理 | 36篇 |
环保管理 | 44篇 |
综合类 | 294篇 |
基础理论 | 57篇 |
污染及防治 | 83篇 |
评价与监测 | 26篇 |
灾害及防治 | 1篇 |
出版年
2023年 | 8篇 |
2022年 | 9篇 |
2021年 | 14篇 |
2020年 | 19篇 |
2019年 | 16篇 |
2018年 | 15篇 |
2017年 | 16篇 |
2016年 | 18篇 |
2015年 | 37篇 |
2014年 | 23篇 |
2013年 | 25篇 |
2012年 | 51篇 |
2011年 | 39篇 |
2010年 | 23篇 |
2009年 | 45篇 |
2008年 | 21篇 |
2007年 | 33篇 |
2006年 | 37篇 |
2005年 | 20篇 |
2004年 | 32篇 |
2003年 | 21篇 |
2002年 | 14篇 |
2001年 | 15篇 |
2000年 | 17篇 |
1999年 | 15篇 |
1998年 | 10篇 |
1997年 | 5篇 |
1996年 | 8篇 |
1995年 | 5篇 |
1994年 | 9篇 |
1993年 | 4篇 |
1992年 | 2篇 |
1991年 | 3篇 |
1990年 | 4篇 |
1989年 | 1篇 |
排序方式: 共有634条查询结果,搜索用时 78 毫秒
101.
Wanpeng Chen Jiahui Song Shaojie Jiang Qiang He Jun Ma Xiaoliu Huangfu 《Frontiers of Environmental Science & Engineering》2022,16(2):16
102.
Global emissions trading allows for agricultural measures to be accounted for the carbon sequestration in soils. The Environmental Policy Integrated Climate (EPIC) model was tested for central European site conditions by means of agricultural extensification scenarios. Results of soil and management analyses of different management systems (cultivation with mouldboard plough, reduced tillage, and grassland/fallow establishment) on 13 representative sites in the German State Baden-Württemberg were used to calibrate the EPIC model. Calibration results were compared to those of the Intergovernmental Panel on Climate Change (IPCC) prognosis tool. The first calibration step included adjustments in (a) N depositions, (b) N2-fixation by bacteria during fallow, and (c) nutrient content of organic fertilisers according to regional values. The mixing efficiency of implements used for reduced tillage and four crop parameters were adapted to site conditions as a second step of the iterative calibration process, which should optimise the agreement between measured and simulated humus changes. Thus, general rules were obtained for the calibration of EPIC for different criteria and regions. EPIC simulated an average increase of +0.341 Mg humus-C ha−1 a−1 for on average 11.3 years of reduced tillage compared to land cultivated with mouldboard plough during the same time scale. Field measurements revealed an average increase of +0.343 Mg C ha−1 a−1 and the IPCC prognosis tool +0.345 Mg C ha−1 a−1. EPIC simulated an average increase of +1.253 Mg C ha−1 a−1 for on average 10.6 years of grassland/fallow establishment compared to an average increase of +1.342 Mg humus-C ha−1 a−1 measured by field measurements and +1.254 Mg C ha−1 a−1 according to the IPCC prognosis tool. The comparison of simulated and measured humus C stocks was r2 ≥ 0.825 for all treatments. However, on some sites deviations between simulated and measured results were considerable. The result for the simulation of yields was similar. In 49% of the cases the simulated yields differed from the surveyed ones by more than 20%. Some explanations could be found by qualitative cause analyses. Yet, for quantitative analyses the available information from farmers was not sufficient. Altogether EPIC is able to represent the expected changes by reduced tillage or grassland/fallow establishment acceptably under central European site conditions of south-western Germany. 相似文献
103.
纳米硫化镉量子点细胞毒性作用机制 总被引:3,自引:3,他引:0
为初步探讨硫化镉量子点(CdS QDs)的细胞毒性作用机制,采用MTT毒性实验比较了CdS QDs和常规CdS对仓鼠肺细胞(CHL)的毒性效应以及细胞内外活性氧水平.结果表明,1)在较低暴露浓度(≤20μg·mL-1)时,CdS QDs细胞毒性显著高于常规CdS,而在较高暴露浓度(>20μg·mL-1)时,两者相差不大.2)在较低暴露浓度(≤40μg·mL-1)时,添加N-乙酰半胱氨酸(NAC)可显著降低CdS QDs的细胞毒性,而在较高暴露浓度(>40μg·mL-1)时,添加NAC对CdS QDs的细胞毒性没有明显影响.添加NAC对常规CdS细胞毒性没有显著影响.综合实验结果推测CdS QDs的细胞毒性与暴露剂量有关:在低浓度(<20μg·mL-1)时,主要是活性氧的氧化损伤作用;在中等浓度(20~40μg·mL-1)时,活性氧和Cd2+的释放共同作用;在高浓度(>40μg·mL-1)时,则是Cd2+的释放占主导地位. 相似文献
104.
硫化氢废气治理研究进展 总被引:9,自引:0,他引:9
综合评述了硫化氢废气的各类净化方法及最新的研究进展。硫化氢废气的净化有吸收法、吸附法、氧化法、分解法和生物法。本文对超级克劳斯法和分解法研究进展进行了重点阐述。 相似文献
105.
采用多孔聚合物载体固定化微生物在厌氧流化床(AFB)反应器中处理含硫废水,研究反应器抗硫化物(S2-)毒性抑制和抗硫酸盐毒性抑制的能力;探索解除 S2-毒性的方法.研究表明,当进料基质 COD浓度为 5000mg/L,HRT为5.2-5.4h,S2-<200mg/L时,反应器去除 COD效果不受影响,S2-350mg/L时,厌氧消化受到明显抑制,反应器可容忍530mg/L S2-浓度而未造成消化系统的破坏;SO42-浓度高达3521mg/L,COD去除率仍可达77%-80%,但SO42-去除率明显下降;当COD/SO42-的比值大于1.45时,硫酸盐还原菌和产甲烷菌的生长未受到明显抑制,此时容积负荷为22-24kgCOD/(m3>·d),COD去除率为80%,SO42-去除率为58.8%;向反应器投加适量FeCl2可很好地解除S2-的抑制. 相似文献
106.
There is a noticeable discrepancy in the ability to control reduced explosion overpressure between flat bursting panels and curved bursting panels with the same static activation overpressure. Flat bursting plates were observed to leak at approximately 80% of the static activation overpressure lower than curved bursting plates. A new experimental technique is proposed in our paper. Three different vent areas of flat and curved bursting panels were tested, there was significant difference in structural stiffness between flat bursting panels and curved bursting panels, which is the reason the discrepancy in the ability to control reduced explosion overpressure. The structural stiffness of the flat bursting panels is poorer than that of the other, and a greater deformation of the flat bursting panels occurs under the same load. The membrane stress caused by the explosion overpressure therefore produces a larger value in the flat bursting panels which causes it to open prematurely. Moreover, the smaller the vent area that is, the more significant discrepancy in controlling the reduced explosion overpressure between both bursting panels is. This experimental and theoretical result in our paper provides some useful experience for the method of explosion venting. 相似文献
107.
硫化氢是油气田伴生气中的有害组分。在含硫油气田的采出水中,硫化氢的存在对于安全生产和和油田环境均会产生危害。采出水经处理后通常需作为地层回注水使用,由于油气生产的特殊性,常用的硫化氢脱除方法在使用中受到限制,探索适合于油气田生产的水处理方法十分必要。本文探讨了通常可用于油田水中硫化氢脱除的各种方法,对比了各类方法的优缺点,提出以次氯酸钠为主要脱硫剂的水处理方法,通过对模拟采出水的室内试验,证明次氯酸法可以快速有效地去除采出水中的硫化氢,并提出了消除过量氧化剂的后续处理方法。实验表明经处理后的水质可以达到油气田回注水质要求,处理成本较低。 相似文献
108.
采用高温固相法合成具有不同Nb/Ti摩尔比的复合钛铌酸钾盐,通过Ag+离子交换对其进行改性。在静态下评价了Ag+改性复合钛铌酸钾盐对二甲基硫醚(DMS)和乙硫醇(EM)的吸附与紫外光催化氧化作用,使用红外光谱技术对催化剂表面滞留物种进行表征。结果表明,Ag+改性复合钛铌酸钾盐对DMS的吸附作用力比EM弱。随着Nb/Ti摩尔比增加,Ag+改性复合钛铌酸钾盐对EM的吸附作用力增强。在紫外光辐射下,Ag+改性的复合钛铌酸钾盐将DMS氧化为亚砜、砜和硫酸盐,而EM则被氧化为磺酸和单齿硫酸盐。 相似文献
109.
酸性洗涤塔-生物滤塔-生物曝气池组合工艺处理恶臭气体NH3和H2S 总被引:1,自引:0,他引:1
采用酸性洗涤塔、生物滤塔和生物曝气池的组合工艺处理NH3、H2S恶臭混合气体,研究表明,该组合工艺对NH3和H2S有很好的去除效果,在进气流量为35 L/min,喷淋量45 L/h时,NH3进气浓度50.15~525.4 mg/m3,H2S进气浓度10.23~110.36 mg/m3时,NH3单一进气去除率稳定在99%以上,H2S单一进气去除率90%以上。混合进气后,NH3去除率几乎为100%,H2S的去除率提高至98%以上。在一定的浓度范围内,NH3和H2S之间的相互作用对两者的去除效果没有明显的影响,而且起到了相互促进降解的作用。同时,进气流量和填料层高度都会影响NH3、H2S的去除率。系统对进气容积负荷变化的缓冲能力强,在偶尔超负荷条件下运行并不能使系统崩溃,并且微生物对高负荷逐渐表现出适应性。大部分溶于水的氨由生物曝气池去除,去除率达到96.9%。 相似文献
110.