跨界水体联合监测中总磷测定的问题探讨

研究了不同分析方法、去浊度手段和预处理方式对地表水总磷测定的影响。结果表明:钼酸铵分光光度法在跨界水体联合监测中较连续流动分析法、氯化亚锡还原光度法、孔雀绿-磷钼杂多酸分光光度法更为适用;在水样没有色度的情况下,采用浊度-色度补偿法和离心法都能有效消除浊度干扰,相对误差±10%;预处理方式的不同是导致各监测单位测定结果可比性差的最关键因素。     

浅议现代垃圾填埋场的大气污染及监测分析方法

造成垃圾填埋场大气污染的两大类污染物,其对环境、人体、动植物、器物和材料都有一定的危害,文章针对现代垃圾填埋场的大气环境污染,以硫化氢、氨、甲硫醇等重点大气污染因子为监测对象,结合实践总结了一部分垃圾填埋场的大气污染监测方案,包括布点原则、采样频率和时间、采样方法和分析技术,该监测方案可为现代垃圾填埋场的大气污染监测提供参考.     

固相萃取-高效液相色谱法测定水中微囊藻毒素质量控制指标研究

采用固相萃取－液相色谱法，通过统计全国多家实验室的测定数据，对水中微囊藻毒素测试的平行样测定相对偏差、空白加标回收率、实际样品加标回收率、空白加标回收率平行样相对偏差以及样品加标回收率平行样相对偏差5个质控指标进行了研究，并给出了质控指标评价标准，提出在概率P和γ均为0.90时，其平行样测定允许最大相对偏差应控制在7.3%；空白加标质量浓度为0.005~20 μg/L时，回收率的控制范围为61%~125%；样品测定浓度为未检出、加标质量浓度在0.2~3.6 μg/L时，实际样品加标回收率控制范围为66%~108%；空白加标、样品加标回收率平行样最大相对偏差应分别控制在3.9%和8.9%。在概率P和γ均为0.95时，其平行样测定允许最大相对偏差应控制在8.3%；空白加标质量浓度为0.005~20 μg/L时，回收率的控制范围为49%~137%；样品测定浓度为未检出、加标质量浓度在0.2~3.6 μg/L时，实际样品加标回收率控制范围为60%~114%；空白加标、样品加标回收率平行样最大相对偏差应分别控制在5.2% 和14.8%。     

非甲烷总烃样品保存时限探讨

非甲烷总烃在监测过程中,废气样品保存容器的选择和保存时间的长短对分析结果有重要影响。研究结果表明:使用玻璃注射器保存样品,应在8 h内完成分析;使用泰德拉惰性气袋保存样品,保存时间可延长至48 h,如废气中主要组分为沸点高于150℃的高沸点化合物,则应在8 h内完成非甲烷总烃的测定。     

A comprehensive waste collection cost model applied to post-consumer plastic packaging waste

Post-consumer plastic packaging waste (PPW) can be collected for recycling via source separation or post-separation. In source separation, households separate plastics from other waste before collection, whereas in post-separation waste is separated at a treatment centre after collection. There are also two collection schemes, either curb side or via drop-off locations. These different schemes have impact on total costs of collection at the municipal level. It can also influence the facility choices and network design. Therefore, a method which can compare costs of various collection schemes is needed.A comprehensive cost model was developed to compare costs of municipal collection schemes of PPW. The ‘municipal waste collection cost model’ is based on variables including fixed and variable costs per vehicle, personnel cost, container or bag costs as well as on emission costs (using imaginary carbon taxes). The model can be used for decision support when strategic changes to the collection scheme of municipalities are considered. The model takes into account the characteristics of municipalities, including urbanization degree and taxation schemes for household waste management.The model was applied to the Dutch case of post-consumer plastic packaging waste. Results showed that that in general post-separation collection has the lowest costs and curb side collection in urban municipalities without residual waste collection taxing schemes the highest. These results were supported by the conducted sensitivity analysis, which showed that higher source separation responses are negatively related to curb side collection costs. Greenhouse gas emission costs are a significant part of the total costs when collecting post-consumer plastic packaging waste due to the low density to weight ratio of the materials collect. These costs can amount to 15% of the total collection costs.     

环境样品中农药的前处理及检测技术研究进展

综述了近年来农药环境样品的前处理及检测技术,介绍了各种前处理和检测技术的应用情况,在此基础上对环境中残留农药的前处理及检测技术的发展进行了展望.