Organotin Compounds and Selected Metals in the Marine Environment of Northern Adriatic Sea

The extent of pollution with organotin compounds and Cd, Pb, Ni, Cu, Zn, Cr, Mn, V, Co and Al was investigated in sediments and mussels (Mytilus galloprovincialis) from the Slovenian costal area of the Northern Adriatic Sea. Sampling was performed in Marina Portorož, Dockyard Izola, non exposed area of the Bay of Mesečev zaliv and in Mariculture Sečovlje. Mussels were taken in the summer and winter time, while sediments were collected during the winter sampling. Organotin compounds were determined by gas chromatography—mass spectrometry and metals by flame or electrothermal atomic absorption spectrometry. The accuracies of the analytical procedures were checked by the analysis of standard reference materials CRM 477 mussel tissue and PACS 2 marine sediment (organotin compounds) and SRM 2976 mussel tissue and CRM 320 river sediment (metals). Good agreements between certified and determined values were obtained. Normalization procedure to Al was applied to estimate the anthropogenic inputs of metals in sediments. The analyses of sediments demonstrated moderate pollution with organotin compounds in Marina Portorož and in Dockyard Izola. Concentrations of tributyltin species were higher than those of dibutyltin and monobutyltin. In mussels substantial contamination with tributyltin was observed in Marina Porotrož and Dockyard Izola. The extent of pollution was higher in the winter time. The analysis of metals in sediments exhibited elevated concentrations in Marina Portorož and Dockyard Izola. Data from the normalization procedure indicated the anthropogenic inputs of Cu, Zn and Cr in Marina Portorož and Mn in Bay of Mesečev zaliv and Dockyard Izola. Mussels, as accumulators of pollutants, in general contained higher metal concentrations during winter time in Dockyard Izola.     

Determination of heavy metals (Cd, Cr, Cu, Fe, Ni, Pb, Zn) by ICP-OES and their speciation in Algerian Mediterranean Sea sediments after a five-stage sequential extraction procedure

Surface sediment samples (n = 18) were collected from the Algerian Mediterranean coasts and analyzed for seven metals using inductively coupled plasma-optical emission spectrometry in order to asses the distribution and bioavailability of metals and to study the anthropogenic factors affecting their concentrations. Sediment samples were size-fractionated into three sizes: 1,080–500 (coarse), 500–250 (medium), and <250 mm (fine). Bulk sediments were subjected to both sequential extraction and total digestion to evaluate the reliability of the sequential extraction procedure (SEP), while the fractions have been only sequentially extracted for metals speciation. The metals were sequentially extracted into five phases namely exchangeable (P1), carbonates (P2), Fe–Mn oxides (P3), organic (P4) and residual (P5). Metal recoveries in sequential extractions were ±20% of the independently measured total metal concentrations; the high recovery rates indicate the good reliability of the SEP used in this study. Correlation coefficients indicated that the grain size has an effect on the distribution of metals in the investigated samples. The order of metal levels in the fractions was medium > fine > coarse for all the metals. The average total extractable metal concentrations for Cd, Cr, Cu, Fe, Ni, Pb, and Zn were 1.1, 8.8, 4.7, 1,291.3, 13.9, 5.7 and 20.4 μg/g, respectively. The northeastern shelf had the lowest metal levels while the highest were in northwestern part mainly due to the significant tourism activities in the northwestern part. Comparison of our results to Earth’s crust values and to previous studies points out that our samples were relatively unpolluted with respect to the heavy metals investigated; most of the metals are not from anthropogenic sources. Enrichment factors as the criteria for examining the impact of the anthropogenic sources of heavy metals were calculated, and it was observed that the investigated samples were not contaminated with Cr, Cu, and Fe, moderately contaminated with Ni, Pb, and Cd, and contaminated with Cd in some sites. The P5 phase had the highest percents of Cr, Cu, Fe, Ni, and Zn. Cadmium and lead were predominant in the P4 phase, while Cu, Fe and Zn were distributed in the order P5 > P3 > P4 > P2 > P1. The following order of bioavailability was found with the heavy metals Pb > Cr > Cd > Ni > Zn > Cu > Fe.     

四川省土地承载力研究的系统动力学仿真模型

本文利用系统动力学理论,建立了四川省土地承载能力的动态仿真模型,模型中包括土地利用、人口、种植业、畜牧业、渔业等子系统,文中阐述了土地承载力模型的建立过程和方法,模拟了四川未来45年土地承载力系统的动态变化轨迹,提出了两种方案,并对其仿真结果进行了分析。     

Radioactive Isotopes of Strontium, Caesium and Plutonium in Sediments of the Northern Adriatic Sea

Sediment samples of different strata (0-3 and 12-15 cm) were collected between 1990 and 1992 during seasonal cruises in the Northern Adriatic Sea. A complete mapping of the Sr-90, Cs-137, Pu-238 and Pu-239(240) concentrations was obtained for samples covering a wide area, stretching from the Gulf of Trieste towards the Ancona shoreline. Sr-90 concentrations varied between 1.5 and 6.5 Bq kg^-1 dw, Cs-137 was in the range 0.9-38.9 Bq kg^-1 dw, Pu-239(240) in the range 0.08-1.5 Bq kg^-1 dw and Pu-238 around 0.03 Bq kg^-1 dw. Special reference was also put on the comparison between the off-shore environment and data obtained from samples collected inside the Po river delta. in spite of the major accumulation of Cs-137 inside the estuarine environment, higher concentrations of strontium and plutonium isotopes were detected in the offshore environment.     

中国自然保护区的困境与出路

任何事物的发展总免不了挫折和失败,中国自然保护区在其发展过程中也是如此.经过50年的发展,我国的自然保护区面积与国土面积的比例已经超过了世界平均水平,但在其土地权属、与当地人民之间的利益关系上存在着很大的问题.在此,从与当地人民之间的关系出发,主要考察自然保护区的困境与出路.     

关于耕地总量动态平衡的思考

中国是一个人多地少的国家，伴随着80年代经济高速增长而加剧的人地矛盾已经成为区域可持续发展面临的一个重要问题。本文以大量的数据分析了自耕地总量动态平衡实施以来的1999-2001年耕地数量和质量的变化，其中用播面单产和复种指数来度量耕地质量，得出了我国总体耕地质量下降的结论，指出仅仅从数量上实施耕地总量动态平衡，保证不了我国粮食安全的需要。并在此基础上提出了相关的建议。     

土地利用规划在风景名胜保护中的应用研究

探讨了土地利用规划与风景名胜保护的关系，并以武汉市为例。进行了实证分析。将武汉市土地利用风景名胜资源分为极度、重度、中度、轻度和非敏感区5个等级。并提出了相应的保护对策。为该市的土地利用规划修编提供科学依据。     

城镇用地扩张的影响分析

社会经济条件的变化是推动城镇用地扩张的重要力量。城镇用地规模不断扩大，不仅促进了城镇本身功能的完善、经济实力的提高，带动了周围农村地区社会经济的发展。而且，城镇用地大量、快速向外扩张也给城镇本身及其周围农村带来了较大的负面影响。     

嘉陵江流域坡耕地“生态农业旅游”垂直景观模式

从治理水土流失角度出发，提出了坡耕地“生态农业旅游”技术与示范。其垂直生态景观模式按坡度和等高线布置：在坡度大于25°的山坡顶形成水保林木区，坡上15°～25°的陡坡种植桃树，坡中5°～15°的斜坡种植枇杷，坡下小于5°的缓坡地带种植特种水果、瓜类及蔬菜，坡底形成“稻—鱼”和“藕—鱼”特色水域区。道路系统设计为环山而下的水泥主路、观景石板干路、埂边地界小路三级，道路两侧实施还林还草。“农家乐”型旅游接待自然分布在试验区内，同时在坡上建立旅游“一条街”、坡底试验旅游产业化经营。果园内实施多熟作物覆盖、间种套种。垂直生态景观产生了独特而丰富的景观效果，并具有较好的生态功能、经济功能和社会功能。     

Partitioning of Cs-137 Between Sediment and Water From the Black Sea

As part of a joint USA/USSR Environmental Agreement to determine the distribution and concentration of Chernobyl radioactivity in the northwest Black Sea area, the sediment from eight stations was collected and analyzed to assess the ability of this material to adsorb radiocaesium. Batch tests were conducted in which Cs-137 tracer was added to mixtures of sediment and bottom water, with contact solutions ranging from 85 Bq ml^-1 to 1,760 Bq ml^-1. This work was done in an argon atmosphere at 9.5°C, which is the average temperature of the sediment. Isotherms were linear for all cores and distribution ratios (R_D) calculated from the slopes of the isotherms ranged from 660 to 1,660 ml g^-1. These isotherms fit a simplified Freundlich isotherm. Correlations of R_D to a number of sediment parameters describing texture and mineralogy were determined. A close relationship was observed between R_D for caesium and the percentage of illite contained in the samples.