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101.
This article presents the impact of the ecological investment in ironworks (dust filter installation) and construction works
at a highly contaminated brownfield site on the chemical composition of household dust (HD) and street sediment (SS) in Celje,
Slovenia. The evaluation is based on two sampling campaigns: the first was undertaken 1 month before the ecological investment
became operational and the second 3 years later. The results show that dust filter installations reduced the content of Co,
Cr, Fe, Mn, Mo, W and Zn on average by 58% in HD and by 51% in SS. No reduction was observed at sampling points in the upwind
direction from the ironworks. By contrast, the impact of the construction works on the highly contaminated brownfield site
was detected by a significant increase (on average by 37%) of elements connected to the brownfield contamination in SS. Such
increase was not detected in HD. 相似文献
102.
Polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans (PCDD/Fs) are ubiquitous contaminants and can be considerably accumulated by natural plants. In order to elucidate the biochemical and physiological responses of plant to PCDD/Fs, tobacco Bright Yellow-2 (BY-2) cells were selected as model plant and treated with time- and concentration-dependent PCDD/Fs. The toxic effect and oxidative stress caused by PCDD/Fs were evident, which could be indicted by the reduction in fresh mass, the increase in malondialdehyde (MDA) content, and the damage of tobacco cell ultrastructure. PCDD/Fs tolerance was correlated with changes in antioxidant system and hormones of tobacco cells. Superoxide dismutase (SOD) and peroxidase (POD) exhibited peak enzyme activities at the PCDD/Fs concentration of 1000 ng WHO98-TEQ g−1 fresh weight. Glutathione reductase (GR) enzyme activity increased monotonically at high level PCDD/Fs, but the activity of catalase (CAT) was only slightly affected at all treatment. Meanwhile, the exposure to PCDD/Fs resulted in the changes of hormones content. With the increase of exposure concentration of PCDD/Fs, the levels of indole-3-acetic acid (IAA) and abscisic acid (ABA) increased, whereas the concentration of jasmonates (JAs) decreased. The above results suggest that tobacco cells had the ability to cope with the oxidative stress induced by low concentration of PCDD/Fs through increasing the activities of antioxidant enzymes and alternating plant hormones levels. However, oxidative stress and toxicity would burst out when plant cells were exposed to the high levels of PCDD/Fs. 相似文献
103.
Ore is considered as an important source of many elements such as the iron, phosphorus, and uranium. Concerning the natural radionuclides, their concentrations vary from an ore to other depending on the chemical composition of each site.In this work, two phosphate ores found in East of Algeria have been chosen to assess the activity concentration of natural radionuclides represented mainly by three natural radioactive series 238U, 235U and 232Th, and the primordial radionuclide 40K where they were determined using ultra-low background, high-resolution gamma-ray spectroscopy.The measured activity concentrations of radioactive series ranged from 6.2 ± 0.4 to 733 ± 33 Bq.kg−1 for the 232Th series, from 249 ± 16 to 547 ± 39 Bq.kg−1 for the 238U series, around 24.2 ± 2.5 Bq.kg−1 for the 235U series, and from 1.4 ± 0.2 to 6.7 ± 0.7 Bq.kg−1 for 40K.To assess exposure to gamma radiation in the two ores, from specific activities of 232Th, 40K and 226Ra, three indexes were determined: Radium equivalent (Raeq), external and internal hazard indexes (Hex and Hin), their values ranged from 831 ± 8 to 1298 ± 14 Bq.kg−1 for Raeq, from 2.2 ± 0.4 to 3.5 ± 0.7 Bq.kg−1 for Hex, and from 4.2 ± 0.7 to 4.5 ± 0.7 Bq.kg−1 for Hin. 相似文献
104.
Josué Ilunga Mubedi Naresh Devarajan Séverine Le Faucheur John Kayembe Mputu Emmanuel K. Atibu Periyasamy Sivalingam Kandasamy Prabakar Pius T. Mpiana Walter Wildi John Poté 《Chemosphere》2013
Physicochemical and ecotoxicological analyses have been performed to assess the quality of sediments receiving untreated hospital effluents from Indian and Democratic Republic of Congo (DRC) hospitals. The sediments were collected monthly and characterized for grain size, organic matter, total organic carbon, total carbon, nitrogen, phosphorus, toxic metals and ecotoxicity. The results highlight the high concentration of toxic metals from the Indian hospital effluent receiving systems, especially for Cr, Cu, As, Zn and Hg. On the other hand, the metal concentrations in the sediment receiving system from DRC are low (e.g. maximum Hg and Zn concentration were 0.46 and 48.84 mg kg−1 respectively). Ostracods exposed to sediment samples H2 (September month sample) and H3 (June and September month samples) were found dead after 6 d of exposure whereas the higher mortality rate for Congo sediments was 23% but was accompanied with 33 ± 7% of growth inhibition. The results of this study show the variation of sediment composition on toxic metal levels as well as toxicity related to both, the type of hospitals and the sampling period. Additionally, hospital effluent disposal practices at the study sites can lead to the pollution of water resources and may generate risks for aquatic organisms and human health. 相似文献
105.
This paper explores issues of governance and decision-making structures associated with the problem of hexachlorobenzene (HCB) waste at Botany in New South Wales. From a government perspective, the problem is ‘downstream’ of a well-known national controversy over whether Australia should have a high-temperature incinerator (HTI) to ‘dispose’ of such scheduled wastes. The 1992 decision not to proceed with HTI followed an extensive process of public consultation, which, against the expectations of industry and government, saw the emergence of Australia-wide community opposition. Alternative national management plans were formulated for the treatment of several types of organochlorine waste, with the scheme of these plans first approved in 1993 by the Australian and New Zealand Environment and Conservation Council (ANZECC). The HCB Management Plan is one of three such plans (the others being for PCBs and organochlorine pesticides). With this, ANZECC established the Scheduled Waste Management Group comprising government officials, and the National Advisory Body (NAB) made up of stakeholders. Officially the NAB had oversight of the HCB problem until 2002 when it was disbanded. As a result of the HTI experience, new community consultation protocols were introduced in association with the alternative management plans. For HCBs, which are confined almost entirely to Orica's Botany site in southeastern Sydney, this led to the establishment of the Community Participation and Review Committee (CPRC), a representative body with review and advisory functions. This paper draws conclusions from this history about government processes of decision making, the role of individual and institutional actors, the central importance of trust, and the democratisation of risk management. Using concepts delineated by McDonell [1991. Toxic waste management in Australia: why did policy reform fail? Environment 33(6), 11–13, 33–39; 1997. Scientific and everyday knowledge: trust and the politics of environmental initiatives. Social Studies of Science 27, 819–863.] we identify swings towards, then away from institutionalised trust. Across two decades, government and industry have placed faith in centrally controlled mechanisms for public participation, hoping to garner trust and legitimate privileged technological solutions. On the ‘backswings’, these processes have seen public trust dissipate in the face of government misunderstanding of the opportunities for effective bureaucratic interventions. 相似文献
106.
This work demonstrates the success of a recently developed technique in chemical amplification, non-biological inhibition-based sensing (NIBS), for the detection of toxic arsenic compounds. Screening for toxic arsenic compounds is especially important due to their prevalence in wastewater and water sources. The detection method presented in this work amplifies the chemical response of toxic arsenic compounds by developing a sensor chemistry where the analyte inhibits, rather than enhances, the rate of a catalytic reaction. This technique mimics the work done with enzyme inhibition; however, using non-biological molecules allows for selective detection without the shelf-life issue associated with biological molecules. Using NIBS we find that we can enhance the sensitivity of the system by two orders of magnitude with no apparent loss in selectivity. This work demonstrates the versatility of NIBS, showing that the technique can be of general use for the detection of toxic compounds. 相似文献
107.
北京市典型道路交通噪声排放特征 总被引:1,自引:1,他引:0
采用北京市道路交通噪声自动监测系统2013—2017年采集的等效连续A声级数据,对城市快速路、城市主干线、城市次干线、城市支路的代表性站点噪声排放情况进行了统计分析,结果显示,北京市不同等级的道路噪声排放具备一定的特征,排放水平从大到小依次为城市快速路城市主干线城市支路和城市次干线,道路噪声随时间变化存在较为一致的周期性排放特征,24 h变化特征比较明显。个别道路排放特征存在特异性,如城市主干线道路的一个代表监测站点噪声监测值出现了逐年下降趋势,分析发现,北京市非首都功能疏解对其噪声值的下降有一定贡献。采取一定的规划和管理措施有助于减少道路交通噪声的排放。 相似文献
108.
109.
Lloyd-Smith M 《Journal of environmental management》2009,90(4):1628-1635
In the environmental conflict that surrounds the sighting of hazardous waste facilities there is usually a volatile mix of disparities in power, expertise and information access as well as differing views on risk, which are all played out amidst commercial arrangements and environmental justice concerns. In recent times, the volatility of this mix has been further compounded by the growing climate of public concern and distrust surrounding scientific developments and technology. While there is no 'quick fix' to the complex conflict that this entails, community information systems (CISs) based on participatory models can help address the outstanding issues of capacity, information access, power inequities and environmental justice. CISs are an effective response to the five crucial elements of a toxic dispute, that is, the dialogue, capacity building, information access, evaluation of hazards and risk, and expertise. This paper will review the role of community accessible information systems in the dispute in Botany over the management and destruction of Orica Australia's stockpile of the persistent organic pollutant, hexachlorobenzene (HCB). It will focus on the role of CIS in responding to the challenges for expert information delivery, and in addressing the disparity of informational power within the toxic dispute. 相似文献
110.
运用环境多介质QWASI等量浓度模型模拟了三峡水库水环境中内分泌干扰物TBT在各环境介质中的浓度分布及迁移归趋,同时讨论了三峡水库运行方式对库区水环境中TBT环境行为的影响.结果表明,QWASI模型能够较为合理地给出各个物理化学过程的速率参数,可对TBT在三峡水库这种超大型河道型水库中跨介质间的迁移传输、各环境相分布等作出定性和定量的模拟估计,模型输出结果与实测结果较为吻合.研究表明,三峡水库的运行方式对TBT在库区水环境中沉积物和水相间的迁移转化有重要影响. 相似文献