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Exposure of polycyclic aromatic hydrocarbons (PAHs) to sunlight results in rapid structural photomodification generally via oxidation reactions. These PAH modification products are in many cases more toxic than their parent compounds. In this study, anthracene (ANT), a rapidly photooxidized PAH, was irradiated with simulated solar radiation (SSR, 100 μmol m−2 s−1) in aqueous solution to examine the photomodification pathway. The photoproducts formed were identified by HPLC. The ANT product profile after 9 h in SSR was very complex, with more than 20 compounds detected. The photoproducts formed were anthraquinones, benzoic acids, benzaldehydes and phenols showing the process to be oxidative in nature. Some of the anthraquinones were themselves subject to photooxidation, and were thus intermediates in the product pathway. The kinetics of ANT photooxidation revealed a pseudo first-order reaction with a half-life of 2 h under the SSR source used. The kinetics of product formation allowed deduction of a probable photomodification pathway. This study indicates that PAH photooxidation products are likely to exist as complex, dynamically changing mixtures in PAH contaminated aquatic environments. 相似文献
84.
Environmental impact of diuron transformation: a review 总被引:3,自引:0,他引:3
Diuron is a biologically active pollutant present in soil, water and sediments. A synthesis of literature data on its physicochemical properties, partitioning behaviour, abiotic and biotic transformations, toxicological and ecotoxicological impacts has been here performed. Data have shown that diuron is generally persistent in soil, water and groundwater. It is also slightly toxic to mammals and birds as well as moderately toxic to aquatic invertebrates. However, its principal product of biodegradation, 3,4-dichloroaniline exhibits a higher toxicity and is also persistent in soil, water and groundwater. Thus, diuron indirectly possesses a significant amount of toxicity and could be a potential poisoning pesticide contaminant of groundwater. Unfortunately, groundwater contamination will still persist despite the progressive suppression of diuron (Directive 200/60/CE). Therefore, determining the main factors influencing its degradation and its ecotoxicological effects on the environment and health could provide a basis for further development of bioremediation processes. 相似文献
85.
Effects of pyridaphenthion on growth of five freshwater species of phytoplankton. A laboratory study
The acute toxicity of the insecticide and acaricide pyridaphenthion to five species of freshwater phytoplankton, Scenedesmus acutus, Scenedesmus subspicatus, Chlorella vulgaris, Chlorella saccharophila and Pseudanabaena galeata was determined. Insecticide concentrations eliciting a 50% growth reduction over 96 h (EC50) ranged from 2.2 to 30.9 mg/l. The two species of Chlorella and the cyanobacteria P. galeata were more tolerant than the two species of Scenedesmus. Concentrations of pyridaphenthion detected in some natural waters were less than the toxic threshold for these species. 相似文献
86.
对原水处理剂S絮凝剂进行了大鼠急性毒性和90d喂养试验。S絮凝剂大鼠经口半数致死量雄性为8710mg/kg,B.W.,雌性为10965mg/kgB.W.,属实际无毒类物质。90d喂试验结果表明,剂量≥0.8%,时对大鼠生长发育,血液学、生化学及病理组织学等各项指标水见有不良影响,S絮凝剂最大无作用剂量为0.8%,相当于实际作用量的1000倍。 相似文献
87.
Inorganic mercury and methylmercury in surface sediments and mussel tissues from a microtidal lagoon (Bizerte, Tunisia) 总被引:1,自引:0,他引:1
N. Mzoughi T. Stoichev M. Dachraoui A. El Abed D. Amouroux O. F. X. Donard 《Journal of Coastal Conservation》2002,8(2):141-145
The aim of this study was to investigate the distribution of mercury compounds in marine sediments and mussel tissues collected
in the lagoon of Bizerte, Tunisia, during two seasons (summer and winter). Inorganic mercury (Hg2+) concentrations in sediments were found to be highly variable, ranging from 0.04 nmol.g1 to 3.22 nmol.g−1 (dry weight) with a mean value of 0.52 nmol.g−1. Anthropogenic sources of Hg2+, most probably metallurgy or tire production industries, have been evidenced. The mean concentration of monomethylmercury
(MeHg+) in the surface sediments is 2.32 pmol g−1 ranging from below the detection limit (0.45 pmol.g−1) to 14.6 pmol.g−1. No significant variation was observed between winter and summer seasons for both mercury species concentration in the sediments.
The Hg2+ concentrations in mussel tissues are also variable, ranging from 0.007 to 1.347 nmol.g−1 (dry weight). The mean concentration is 0.70 nmol.g−1. In these tisssues, Hg2+ is generally the major compound, making up ca. 88% of total mercury concentrations. However, methylmercury concentrations
are significant and homogeneous, ranging from 62 to 121 pmol.g−1 (mean 96 pmol.g−1). The results suggest that a fraction of the inorganic mercury load in the sediments of the lagoon undergoes methylation
pathways. MeHg+ produced is assimilated in the mussels more readily than Hg2+. 相似文献
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89.
研究了铜对缘管浒苔(Enteromorphalinza)的毒性效应,试验了不同的配合剂对铜的毒性效应及累积量的影响。结果发现,铜对缘管浒苔的毒性效应阈值为0.10mg/L;0.50mg/LCu ̄(2+)可使缘管浒苔迅速死亡,培养96h后光合作用强度下降为零。EDTA可抑制铜在藻体中的累积,缓解毒性;8-羟基喹啉则促进铜在藻体中的累积,加刷了毒性。和铜污染的培养介质短期接触(<1m后,加入足量EDTA,藻体生长和对照组相当,较长时间接触(>4h)后,ED-TA不能使藻恢复生长。结合EDTA“洗脱”实验提出,Cu ̄(2+)可能首先经离子交换机制结合于藻体表面,之后,才逐步向细胞内转移。 相似文献
90.
多效唑是一种新开发的植物生长调节剂类农药。试验采用微生物毒性检测的力法,以混合细菌为材料,研究多效唑对细菌的生长速度、总脱氢酶活性和硝化作用的影响。结果表明,多效唑属低毒性农药,在一定范围内,各观察指标与多效唑浓度呈显著性负相关,即较低浓度的多效唑对细菌的生理活动有一定的刺激作用。 相似文献