Short communication

Abstract

The presence of the insecticide carbaryl (Sevin) and its decomposition product l‐napthol was confirmed in irrigation and drainage canal water. However, their residues disappeared from the water 6 days after application.     

Biodegradation of Electrospun Poly-(ɛ-caprolactone) Non-woven Fabrics by Pure-Cultured Soil Filamentous Fungi

The biodegradation of electrospun nano-fibers of poly(-caprolactone) (PCL) was initially investigated with respect to the environmental application of PCL non-woven fabrics, using pure-cultured soil filamentous fungi, Aspergillus oryzae, Penicillium caseicolum, P. citrinum, Mucor sp., Rhizopus sp., Curvularia sp., and Cladosporium sp. Three kinds of non-woven PCL fabrics with different mean fiber diameters (330, 360, and 510 nm) were prepared by changing the viscosities of the pre-spun PCL solutions (150, 210, and 310 cPs, respectively). All of the pure-line soil filamentous fungi tested grew on the two fiber materials. Electron microscopy was used to observe the biodegradation processes revealing remarkable growth of two fungi, Rhizopus sp. and Mucor sp., along with the accompanying collapse of the nano-fiber matrices. In the biochemical oxygen demand (BOD) test, the biodegradation of the 330 nm PCL nano-fibers by Rhizopus sp. and Mucor sp. exceeded 20 and 30% carbon dioxide generation, respectively. The biodegradability of the PCL non-woven fabrics decreased with the mean fiber diameter and the 330 nm PCL nano-fiber that was made from 150 cPs solution (concentration, 7 wt%) exhibited the highest biodegradability. These results might offer some clues for the applications of the PCL non-woven fabrics having the controlled biodegradability in the environmental uses.     

NLGM（1，1^s,t）模型的建立与应用

运用灰色系统理论,建立了一种非线性GM（l,l^s,t）灰色新模型,并将其应用于某厂SO2排放量的预测之中。结果表明,NLGM（l,l^s,t）具有良好的模型品质,中长期预测定GM（l,l）更可靠。     

琉基葡聚糖凝胶分离富集-二溴对甲偶氮羧微乳液分光光度法测定微量镍

研究了在溴代十六烷基吡啶（CPB）、正丁醇、正庚烷、水自制微乳溶液存在下,镍与二溴对甲偶氮羧（DBpMCA）的显色反应,在pH值为9．07的Na2B4O7-HCl缓冲溶液中,镍与试剂形成淡红色配合物,最大吸收峰位于560nm波长处,表观摩尔吸光系数ε为2．8×10^5L／（mol·cm）。优化了试验条件,考察了共存离子的影响,方法在0．002mg／L～0．320mg／L范围内符合比尔定律,检出限为0．0006mg／L,生活垃圾、水、土壤样品测定的RSD为2．1％～5．2％,加标回收率为96．6％～104％。     

近海水体环境参数的SPC监控方法研究

结合目前近海海洋环境,提出了一种适用于多种水体环境参数的SPC监控方法。以溶解氧DO为研究对象,在分析了其统计特征的基础上,应用SPC方法构建了EWMA监控模型,同时讨论了控制界限宽度和平滑系数对EWMA控制图的平均运行链长(ARL)的影响。最后以2010年夏季舟山东福山海域30°N、122°E的水体环境参数溶解氧为例,监控近海水体环境参数DO的EWMA控制图波动情况。根据近海水体环境参数DO控制图的波动情况,结合目前已有的失控判别准则,并通过进一步的现场调研来分析近海水体环境参数DO发生变化的原因,从而为近海水体环境的保护提供支持。结果表明这一方法是可行的,且在近海水体环境参数DO的监控中具有良好的应用效果。     

南盘江上游水质水量综合分析与管理

南盘江上游水污染严重、水资源短缺，而且缺水与污染相互影响．本文以社会经济和水资源这个复杂的耦合系统为研究对象，以促进社会经济持续发展、改善水质、合理利用有限的水资源为总目标，在水污染和水资源供需现状分析、趋势预测的基础上，从水质水量综合决策出发，探讨了南盘江上游水资源的管理对策．     

鼠Tcp11l1基因的结构与表达分析

为了分析鼠Tcp11l1基因的结构和表达,从小鼠睾丸组织总cDNA中扩增鼠Tcp11l1基因的开读框架(Open reading frame,ORF),定向克隆到真核表达载体pEGFP-N1,构建融合表达质粒pTcp11l1-EGFP,转染HEK293细胞,荧光显微镜下观察Tcp11l1基因的亚细胞定位;设计跨小鼠Tcp11l1基因两个外显子的引物,RT-PCR分析此基因在小鼠各组织中的表达情况.并利用生物信息学的方法对鼠Tcp11l1基因的结构进行初步预测.转染pTcp11l1-EGFP后在胞质中能明显看到绿色荧光信号,而在胞核和胞膜中无绿色荧光信号,表明鼠Tcp11l1蛋白定位于细胞质;RT-PCR分析结果表明,鼠Tcp11l1基因在小鼠各组织中广泛表达.生物信息学结果表明,鼠Tcp11l1和鼠Tcp11的蛋白具有相同的TCP11结构域,不能确定是否存在跨膜序列.鼠Tcp11l1基因和鼠Tcp11基因具有相似的亚细胞定位和TCP11结构域,表明这两个基因可能具有相似的受体功能.但是与Tcp11特异表达于睾丸组织的延长精细胞和精子不同,Tcp11l1为广泛表达,说明Tcp11l1可能在多种组织细胞中发挥作用.     

Modified Edman degradation applied to hemoglobin for monitoring occupational exposure to alkylating agents

A method that can be used for the monitoring of exposure to alkylating agents in the environment is presented. It is based on the quantification of alkylated N‐terminal valines in hemoglobin, using a modified Edman degradation procedure. The detection limit (GC/electron capture detector or GC/MS) is increased by two magnitudes of ten when using pentafluorophenyl isothiocyanate instead of phenyl isothiocyanate in the derivatization step. As little as one nmole N‐(—2 hydroxyethyl)valine per gram hemoglobin can be detected under practical conditions.     

南京市某垃圾填埋场重金属污染现状调查

对南京市某垃圾填埋场的垃圾、土壤、植物、炉渣等样品中Cu、Pb、Cr、Zn、Cd、Hg、As、Sb、Mn重金属含量进行分析。结果表明,垃圾填埋场的填埋土中Cu、Zn、As3种重金属含量分别高出自然土壤背景值86％、250％,300％。潜在生态危害指数法评价的污染状况为：Cd、As〉Hg〉Cu〉Pb〉Cr、Zn;Cd和As的毒性贡献较大,存在极高的潜在生态风险。     

陕北黄土高原陡坡耕地土壤侵蚀变异的空间格局

利用环境放射性核素137-Cs技术定量评价陕北黄土高原典型山坡地顺坡断面(240 m)土壤重新分布的空间变化及其影响因素.结果表明,黄土高原坡地土壤侵蚀率存在明显的空间格局,即山坡中、上部是土壤侵蚀最为严重的地带,土壤平均侵蚀速率高达82.8 t/(hm2(a)以上;山顶和坡脚侵蚀速率较小,土壤平均侵蚀速率分别为17.1 t/(hm2(a)及22.3 t/(hm2(a),而坡下部土壤侵蚀速率居中,土壤平均侵蚀速率为46.8 t/(hm2(a).坡度变化是影响该地区土壤侵蚀速率空间变化的主导因子.本研究结果对黄土高原坡地土壤侵蚀的预测预报和准确防治土壤流失具有重要价值.