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141.
37个含硫芳香族化合物理化参数的相关性分析 总被引:2,自引:1,他引:2
本文对37个含硫(S,SO,SO_2)芳香族化合物的理化参数作了统计分析,在水解速率常数k与取代基常数之间建立了几个多元回归方程,并根据各化合物的因子得分和实验设计方法为生物试验挑选出了8个有代表性的化合物。 相似文献
142.
In French Guiana, parabiotic societies (natural mixed colonies) are frequently found in ant gardens. Crematogaster limata parabiotica (Myrmicinae), often associated with Camponotus femoratus (Formicinae), was found for the first time in parabiosis with ponerine ants: Pachycondyla goeldii and Odontomachus mayi. A detailed study of the relationships between Cr. l. parabiotica and O. mayi showed that each species is aggressive towards allospecific or conspecific individuals belonging to another colony, but tolerates
allospecific individuals from the multi-species society. Studies of cuticular substances of the four ant species were made
using gas chromatography. The results showed that each species, living alone or in parabiosis, possesses a specific chemical
profile. Thus, the ants are able to recognise nestmate and non-nestmate individuals of the associated species, even though
their cuticular profiles are different. The hypothesis that the nestmate allospecific profile is learned is suggested to explain
this pattern of recognition.
Received: 5 June 1996 / Accepted after revision: 17 October 1996 相似文献
143.
厌氧条件下微生物对芳香族化合物分解的研究进展 总被引:2,自引:0,他引:2
本文总结了国内外芳香族化合物厌氧微生物分解的代谢类型和途径,指出厌氧条件下微生物对芳香族化合物的分解,包括光和代谢作用、硝酸盐还原作用、发酵作用、硫酸盐还原作用和产甲烷作用五种类型.厌氧条件下芳环的生物裂解包括还原性和非还原性两种类型,讨论了参与芳环裂解过程的一些酶类. 相似文献
144.
Summary Life stages of the primitive Australian ithomiine butterflyTellervo zoilus and its larval hostplant, the apocynaceous vineParsonsia straminea, were quantitatively assayed for pyrrolizidine alkaloids (PAs). PAs were found in all stages, mainly as N-oxides, being most concentrated in larvae and freshly-emerged adults. Although adults feed at various confirmed PA sources this probably does not compensate for losses, as wild-caught adults had considerably lower concentrations of PAs. The main alkaloid present in both freshly-emerged adults and in leaves of the host-plant was lycopsamine (1b), stored by butterflies in the N-oxide form. Its presence in higher proportion, in relation to intermedine (1a), in larvae, pupae and adults ofTellervo in relation to the host-plants suggests the inversion of intermedine to lycopsamine by the insects. No 14-member ring macrocyclic PAs were detected in either food-plant or butterflies. Several other PAs were found in wild-caught adults reflecting visits to other PA sources. PAs were also found in high concentrations in freshly-emerged individuals of the danaineEuploea core bred onParsonsia straminea. Wild-caughtDanaus affinis had high PA levels acquired from adult feeding. Freshly emergedEuploea raised onIschnocarpus frutescens andDanaus raised onIschnostemma carnosum (both PA-free) were preyed on by the orb weaving spiderNephila maculata, and showed no PAs. In all cases where PAs were present, most butterflies were liberated, usually cut out of the web unharmed, byNephila. The spider's response was not closely linked to PA concentration, however, and may also depend on hunger levels and previous experience with PA-containing butterflies. All control and other non-PA containing butterflies were consumed although rejection of some body parts of freshly-emergedDanaus affinis suggests that compounds other than PAs may be involved. 相似文献
145.
鲤鱼对三种硝基芳族化合物的摄取、释放和生物富集 总被引:7,自引:0,他引:7
用第二松花江水和鱼体中多次检出的三种硝基芳族化合物来分别测定鲤鱼体中的生物富集系数(BCF),摄取和释放动力学参数,以及在肌肉、肠、肝和鳃等组织中的分布。试验在半静态条件下进行。硝基芳族化合物在鲤鱼体内的释放可用双区一级动力学模型很好地描述。鲤鱼对2,4-二硝基甲苯和对硝基氯苯的富集过程中发现有未知的代谢产物生成。 相似文献
146.
147.
1 IntroductionVolatileorganiccompounds (VOCs)areimportantairpollutantsintheurbanatmosphere .SomeVOCsaretoxicandpotentiallycarcinogenic.ExposuretoVOCsisofconcernasitmayresultinsignificantrisktohumanhealth .AmbientVOCsareemittedfromvariousurban ,industrial… 相似文献
148.
Helena Bichão Anna-Karin Borg-Karlson Atle Wibe Jorge Araújo Hanna Mustaparta 《Chemoecology》2005,15(4):211-226
Summary. An important question in insect-plant interactions is which of the numerous plant compounds contribute to the perception of
odour qualities in herbivorous insects and are likely to be used as cues in host-searching behaviour. In order to identify
which plant-produced volatiles the strawberry blossom weevil Anthonomus rubi detects, we have used electrophysiological recordings from single olfactory neurones linked to gas chromatography and mass
spectrometry. We here present 15 receptor neurone types specialised for naturally produced compounds present in the host and
nonhost plants and two types for two aggregation pheromone components. The active compounds were terpenoids, aromatic and
aliphatic esters, alcohols and aldehydes, some of which are induced by feeding activity of the weevils. The neurones were
characterised by a strong response to one or two primary odorants and weaker responses to a few others having similar chemical
structure. With one exception, the molecular receptive range of each neurone type was within one chemical group. Enantiomers
of linalool separated on a chiral column activated two neurone types with different enantioselectivity. Inhibition by linalool
of another neurone type, excited by α-pinene, indicated an additional mechanism for coding the information about this compound.
Altogether, detection of 54 compounds by olfactory receptor neurones is shown, of which 40 have been chemically identified
in this study. Thus A. rubi has the ability to detect a large number of odorants that may be used in host selection behaviour. 相似文献
149.
Sabine?HeimEmail author Jan?Schwarzbauer Ralf?Littke 《Environmental Chemistry Letters》2004,2(1):21-25
Specific anthropogenic substances derived from seepage and leakage water from a waste deposit landfill were analysed in groundwater and drainage effluents using gas chromatography-mass spectrometry (GC/MS). Here, we demonstrate the application of an organic marker approach to study lateral and vertical distribution of contamination as well as the long-term emission behaviour. Source-specific and environmentally-stable pesticides, plasticisers and pharmaceuticals, such as N,N-diethyl toluamide, N-butyl benzene sulfonamide, clofibric acid, mecoprop and bisphenol A, were quantitatively analysed. A distinct lateral expansion was detected. Although temporal variations were high, no significant trend was observed. 相似文献
150.
Potential allelopathic effect of Pinus halepensis in the secondary succession: an experimental approach 总被引:1,自引:0,他引:1
Catherine Fernandez Benjamin Lelong Bruno Vila Jean-Philippe Mévy Christine Robles Stéphane Greff Sylvie Dupouyet Anne Bousquet-Mélou 《Chemoecology》2006,16(2):97-105
Summary. Recent economic and social changes in north Mediterranean regions have led to an important rural depopulation. Consequently,
meadows developed on abandoned agricultural lands (characterized by high species richness) undergo reforestation. These former
fields are mainly colonized by Pinus halepensis Miller, which is known to synthetize a wide range of secondary metabolites, among these, some could influence plant succession
through allelopathy. The allelopathic potential of P. halepensis, was tested against two target species (Lactuca sativa L. and Linum strictum L.) with aqueous extracts obtained from different organs (root and needle) taking into account the individual age (±10, ±30
and > 60 years old). Root and needle extracts affected differently germination and growth of the two target species, the responses
varying with concentration of extracts, age and organs tested. The strongest inhibitory effect was observed on the germination
and growth of L. strictum, exposed to needle extracts of young P. halepensis (±10 years old), and root extracts of older P. halepensis (> 30 years old). These extracts contained several phenolic acids (e.g. 4-hydroxybenzoic acid and p-coumaric acid), which are known as allelochemicals and their concentrations vary with age and
organ tested. Hence, P. halepensis could influence secondary succession through the release of potential allelochemicals in the environment by leaf leachates
or root exudates. 相似文献