萘乙二胺偶氮光度法测定苯胺的改进

在萘乙二胺偶氮光度法测定苯胺中，对试样ｐＨ值调节方法进行了改进，分析精度得到了提高。     

环境中萘和甲基萘的气相色谱测定

针对发生的甲基萘油车泄漏事故进行了水样和空气样品中萘和甲基萘的测定，水样中直接进样，对空气样品则以甲醇为吸收液吸收，富集，氢火焰毛细管色谱法测定。     

萘与人体健康

不久前,国务院经贸委和卫生部联合发出通知,宣布停止生产和销售萘丸卫生球,原因是萘丸卫生球对人体健康有害.那么萘究竟是何物质,它有哪些毒性,对人体又有什么危害呢?一、萘的理化性质及用途萘是一种从蒸镏煤焦油所得的中油中提取(约占焦油重量的11%)的化学物质,分子式为C_(10)H_8,分子量128.16,密度1.145g/cm~3(4～20℃时).凝固点80℃.沸点218℃.蒸气压近于10.93Pa(25℃),蒸气比重4.4.空气中饱和度(1.013×10~5Pa,25℃)为0.01%.水中溶解度为100mL中3mg(20℃),乙醇中为每100mL溶解4.2g(20℃),易溶于乙醚.较苯活泼,容易氧化.萘呈闪亮的鳞片状粉末,具有特殊的刺鼻气味.市售萘中     

治理催化超临界水氧化处理1,5-萘二磺酸

采用Mn2O3γAl2O3和V2O5γAl2O3为催化剂,在一连续流固定床反应器中进行了超临界水氧化1,5萘二磺酸实验。实验结果表明,在380～440℃,24MPa条件下,Mn2O3γAl2O3和V2O5γAl2O3催化剂对1,5萘二磺酸的氧化降解具有显著的促进作用,TOC去除率达到90%以上;催化剂的催化效果随反应温度的升高而增强,随pH值的降低而增强,随停留时间的延长先增强后趋于平缓。     

萘系化合物臭氧化对其COD,DOC及可生化性影响研究

本文研究了六种萘系化合物在水溶液中与臭氧的反应，发现１－萘酚，２－萘酚，２－萘胺，吐氏酸臭氧氧化降解明显比周位酸，２－萘磺酸迅速。在试验的臭氧投加量下，它们的可生化性得到较大提高，对前四种化合物进行预臭氧加生化处理将有较好的治理效果。同时发现臭氧化后，ＣＯＤ有不同程度的减小，溶液的ｐＨ值随反应的进行不断降低，而ＤＯＣ变化不大。     

Sensitized effect of β-cyclodextrin on the fluorescence in the determination of carbaryl

Based on the significant enhancement of fluorescence intensity of carbaryl in inclusion complex, a spetrofluorimetdc method with high sensitivity was developed for the determination of carbaryl in aqueous solution. Under the optimum conditions, the complex had excitation and emission maxima at 278 nm and 332 nm, respectively. The linear range of the method was 7.0 ng/ml-1500 ng/ml with a detection limit of 1.2 ng/ml. The proposed method was successfully used to determine quantitativelv of carbarvl in cottonseeds.     

Water solubility enhancements of PAHs by sodium castor oil sulfonate microemulsions

Water solubility enhancements of naphthalene( Naph), phenantherene(Phen) and pyrene(Py) in sodium castor oil sulfonate(SCOS) microemulsions were evaluated. The apparent solubilities of PAHs are linearly propertional to the concentrations of SCOS microemulsion, and the enhancement extent by SCOS solutions is greater than that by ordinary surfactants on the basis of weight solubilization ratio(WSR). ThelogKcm values of Naph, Phen, and Py are 3.13, 4.44 and 5.01 respectively, which are about the same as the logKow values. At 5000 mg/L of SCOS conccentration, the apparent solubilities are 8.80, 121, and 674 times as the intrinsic solubilities for Naph, Phen, and Py. The effects of inorganic ions and temperature on the solubilization of solutes are also investigated. The solubilization is improved with a moderate addition of Ca^2 , Na^ , NH4^ and the mixture of Na^ , K^ , Ca^2 , Mg^2 and NH4^ . WSR values are enhanced by 22.0% for Naph,23.4% for Phen, and 24.6% for Py with temperature increasing by 5~C. The results indicated that SCOS microemulsions improve the performance of the surfactant-enhanced remediation(SER) of soil, by increasing solubilities of organic pollutants and reducing the level of surfactant pollution and remediation expenses.     

催化超临界水氧化处理1,5-萘二磺酸

采用Mn2O3/γ-AL2O3和V2O5/γ-Al2O/为催化剂,在一连续流固定床反应器中进行了超临界水氧化1,5-萘二磺酸实验.实验结果表明,在380～440℃,24 MPa条件下,Mn2O3/γ-Al2O3和V2O5/y-Al2O3催化剂对1,5-萘二磺酸的氧化降解具有显著的促进作用,TOC去除率达到90%以上;催化剂的催化效果随反应温度的升高而增强,随pH值的降低而增强,随停留时间的延长先增强后趋于平缓.