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21.
Mei Li Yao Zhang Chenglei Pei Jinwen Zhang Chunlei Cheng Xiufeng Lian Mubai Chen Bo Huang Zhong Fu Zhen Zhou 《环境科学学报(英文版)》2023,35(2):806-822
The real-time detection of the mixing states of polycyclic aromatic hydrocarbons (PAHs) and nitro-PAHs in ambient particles is of great significance for analyzing the source, aging process, and health effects of PAHs and nitro-PAHs; yet there is still few effective technology to achieve this type of detection. In this study, 11 types of PAH and nitro-PAH standard samples were analyzed using a high performance-single particle aerosol mass spectrometer (HP-SPAMS) in lab studies. The identification principles ‘parent ions’ and ‘mass-to-charge (m/z) = 77’ of each compound were obtained in this study. It was found that different laser energies did not affect the identification of the parent ions. The comparative experiments of ambient atmospheric particles, cooking and biomass burning emitted particles with and without the addition of PAHs were conducted and ruled out the interferences from primary and secondary organics on the identification of PAHs. Besides, the reliability of the characteristic ions extraction method was evaluated through the comparative study of similarity algorithm and deep learning algorithm. In addition, the real PAH-containing particles from vehicle exhaust emissions and ambient particles were also analyzed. This study improves the ability of single particle mass spectrometry technology to detect PAHs and nitro-PAHs, and HP-SPAMS was superior to SPAMS for detecting single particles containing PAHs and nitro-PAHs. This study provides support for subsequent ambient observations to identify the characteristic spectrum of single particles containing PAHs and nitro-PAHs. 相似文献
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System safety is of particular importance for many industries. Broadly speaking, it refers to the state or objective of striving to sustainably ensure accident prevention through actions on multiple safety levers (technical, organizational, and regulatory). While complementary to risk analysis, it is distinct in one important way: risk analysis is anticipatory rationality examining the possibility of adverse events (or accident scenarios), and the tools of risk analysis support and in some cases quantify various aspects of this analysis effort. The end-objective of risk analysis is to help identify and prioritize risks, inform risk management, and support risk communication. These tools however do not provide design or operational guidelines and principles for eliminating or mitigating risks. Such considerations fall within the purview of system safety.In this work, we propose a set of five safety principles, which are domain-independent, technologically agnostic, and broadly applicable across industries. While there is a proliferation of detailed safety measures (tactics) in specific areas and industries, a synthesis of high-level safety principles or strategies that are independent of any particular instantiation, and from which specific safety measures can be derived or related to, has pedagogical value and fulfills an important role in safety training and education. Such synthesis effort also supports creativity and technical ingenuity in the workforce for deriving specific safety measures, and for implementing these principles and handling specific local or new risks. Our set of safety principles includes: (1) the fail-safe principle; (2) the safety margins principle; (3) the un-graduated response principle (under which we subsume the traditional “inherently safe design” principle); (4) the defense-in-depth principle; and (5) the observability-in-depth principle. We carefully examine each principle and provide examples that illustrate their use and implementation. We relate these principles to the notions of hazard level, accident sequence, and conditional probabilities of further hazard escalation or advancement of an accident sequence. These principles are a useful addition to the intellectual toolkit of engineers, decision-makers, and anyone interested in safety issues, and they provide helpful guidelines during system design and risk management efforts. 相似文献
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SUMMARY Sustainable development has become the conceptual framework within which societal, economic and environmental issues are addressed at every level around the world. In 1993, a United States-Canada assembly of more than 250 Great Lakes leaders was convened to evaluate the efficacy of creative processes under way in the Great Lakes Basin relative to sustainable development and to identify key success factors and process characteristics which are consistent with principles of sustainable development. A combination of eight criteria for effective project management (i.e. stakeholder involvement; leadership; information and interpretation; planning; human resource development; results and indicators; review and feedback; stakeholder satisfaction) and six principles of sustainable development (i.e. long-range planning and intergenerational responsibility; carrying capacity; anticipation and prevention; full cost accounting; integration of economic, social and environmental factors; efficiency, innovation and continuous improvement) were developed to evaluate and help improve decision-making processes. Such criteria and principles may be useful in improving decision-making processes in other parts of the world. 相似文献
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The fast growing of urban areas in developing countries has brought serious problems on municipal solid waste (MSW) management. It will be rational to adopt an integrated approach to deal with such a challenge so that the overall eco-efficiency of MSW management could be improved. To better examine how attributes of integrated MSW management are being interpreted and put into practice, and to explore what changes should be made to improve the application of integrated MSW management, we employ a case study method so that lessons learned could be used to inform initiatives in other cities and the potential solution may offer feasible strategies. The case study city is Dalian, a typical seaport city with fast growing rate in economy. The outcomes of this case study show us that fragmented management structure, ineffective and inefficient enforcement of relevant regulations, backward technologies, limited financial resources and lack of public participation are main barriers for the implementation of integrated MSW management. Consequently, in order to overcome these barriers, we propose an integrated management framework on MSW management, aiming to maximize the overall eco-efficiency of MSW management. 相似文献
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为完善安全科学原理的内容,促进安全科学的理论发展,基于对安全科学理论体系和灾害化学的研究,提出灾害化学原理的定义及其研究内容。归纳出灾害化学的六个核心原理,即热平衡原理、过程控制原理、平衡移动原理、反应减速原理、条件阻隔原理、质能守恒原理,并分析这些原理的概念和内涵。最后,从本质化安全生产设计、职业安全健康与管理和安全经济效益的角度分析灾害化学原理的应用,并选取具体实例详细阐述了各原理的实用性。 相似文献
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提出用与碳排放“同步变化程度”来衡量配额指标重要性的思想,对中国各省份碳排放配额进行再分配.首先在公平和效率原则基础上选取碳排放的影响因素作为分配指标,其次采用灰色关联分析法分别测算出各地区各指标与碳排放量的同步变动程度,以得到各地区各指标在配额分配中的比重.最后测算出我国29个省区2020~2030年的碳排放配额与排放空间.结果表明,人口基数及经济发展指标对各地碳排放有较强的同步变动关联性,因此应该被赋予更高的权重;配额最多的地区包括广东、北京、江苏、山东、上海,最少的地区则包括宁夏、贵州、青海、吉林、新疆.盈余分析发现,北京地区的碳排放空间有较多盈余;浙江等5个省区已达较饱和状态;山东等4个省区则处于较严重的溢出状态,在未来10年内需承担较重的减排压力. 相似文献
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The humanitarian system has grown organically over the course of a generation to become a complex system bound by a common primary mandate. Its guiding principles provide it with a unique identity and separate humanitarian actors from other aid-related stakeholders. However, all of the evidence suggests that humanitarian actors will extend their reach and engage in new and unprecedented ways with an expanded mandate in years to come. Now, more than ever, they are challenged to retain the moral high ground and to put disaster-affected people at the centre of humanitarian action. Consequently, this paper proposes that the humanitarian system introduce a new principle: humanitarian subsidiarity. It moves the conception of subsidiarity beyond meanings ascribed by the Catholic Church and the European Union and links it instead to the attributes of agency, accountability, and trust to find accommodation with the core humanitarian principles of humanity, impartiality, neutrality, and independence. 相似文献
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Stanley A. Temple 《Environmental management》1996,20(6):873-878
The synthetic field of conservation biology uses principles derived from many different disciplines to address biodiversity issues. Many of these principles have come from ecology, and two simple ones that seem to relate to many issues involving the utility industry are: (1) Everything is interconnected (and should usually stay that way), and (2) We can never do merely one thing. The first principle can be applied to both the biotic and physical environments that are impacted by industrial activities. Habitat fragmentation and the loss of physical and biotic connectedness that results are frequently associated with transmission rights-of-way. These problems can be reduced—or even turned into conservation benefits—by careful planning and creative management. The second principle applies to the utility industry's programs to deal with carbon released by burning fossil fuels. Ecological knowledge can allow these programs to contribute to the preservation of biodiversity in addition to addressing a pollution problem. Without careful ecological analyses, industry could easily create new problems while implementing solutions to old ones. 相似文献