One-Component Spray Polyurethane Foam from Liquefied Pinewood Polyols: Pursuing Eco-Friendly Materials

The use of petroleum-derived products should be avoided regarding the principles of green and sustainable chemistry. The work reported herein, is aimed at the liquefaction of pine shavings for the production of an environmentally-friendly polyol suitable to be used in the formulations of sprayable polyurethane foams. The biopolyols were obtained in high yield and were used to replace those derived from fossil sources, to produce more “greener” polyurethane foams and therefore, less dependent on petroleum sources, since the polyol component was substituted by products resulting from biomass liquefaction. The partial and fully exchange of the polyols was accomplished, and the results compared with a reference foam. The foams were afterward, chemical, physical, morphological, and mechanically characterized. The complete replacement of polyether polyol and polyol polyester has presented some similar characteristics as that used as a reference, validating that the path chosen for the development of more sustainable materials is on the right track for the contribution to a cleaner world.     

Mechanical Properties of Layered Laminated Woven Bamboo <Emphasis Type="Italic">Gigantochloa Scortechinii</Emphasis>/Epoxy Composites

This study investigated the application of bamboo as a natural composite, in which its potential as a composite material had been examined for 2–6 layers. In precise, the woven bamboo (BW) formed the culm fiber composite with an average of 0.5 mm thickness and 5.0 mm width strip. In addition, this study looked into a specific type of bamboo species known as Gigantochloa Scortechinii (Buluh Semantan), which can be found in Malaysia. This laminated plain BW, which had been reinforced with epoxy (EP), was developed by applying the hand lay-up technique. After that, the specimens were characterized via mechanical analyses, for instance, tensile, flexural, hardness, and impact tests. As a result, the 2-layer BW had displayed rather excellent results chiefly due to the incorporation of epoxy composite, although this is exceptional hardness value.     

Challenges for modelling and integrating environmental performances in concept design: the case of an automotive component lightweighting

The objective of this paper is to discuss the main barriers for modelling and integrating the environmental performances in the automotive concept design. Incorporating environmental assessment in the early design phase of a vehicle component is known as an important challenge that car makers need to face in order to develop more sustainable design solutions; in this regard, the Life Cycle Assessment is the most widespread methodology for the environmental assessment and comparison of alternatives. The present work illustrates the combination of such methodology with the traditional design procedure at two different levels of the component design phase, material choice and concept design. In particular, the potential benefits originated by a lightweight solution for the automotive component Throttle Body are evaluated by considering environmental and technical implications at the same level. The case study shows that a multi-disciplinary approach for design effectively allows the integration of the environmental issue in the company’s established procedures. However, interpretation of results is still a challenging aspect due to the inevitable contradicting elements which should not discourage to develop comprehensive sustainability assessment within the early design stage.     

A synoptic survey of select wastewater-tracer compounds and the pesticide imidacloprid in Florida’s ambient freshwaters

Current wastewater treatment technologies do not remove many unregulated hydrophilic compounds, and there is growing interest that low levels of these compounds, referred to as emerging contaminants, may impact human health and the environment. A probabilistic-designed monitoring network was employed to infer the extent of Florida’s ambient freshwaters containing the wastewater (Includes reuse water, septic systems leachate, and wastewater treatment effluent.) indicators sucralose, acetaminophen, carbamazepine, and primidone and those containing the widely used pesticide imidacloprid. Extent estimates with 95% confidence bounds are provided for canals, rivers, streams, small and large lakes, and unconfined aquifers containing ultra-trace concentrations of these compounds as based on analyses of 2015 sample surveys utilizing 528 sites. Sucralose is estimated to occur in greater than 50% of the canal, river, stream, and large lake resource extents. The pharmaceuticals acetaminophen, carbamazepine, and primidone are most prevalent in rivers, with approximately 30% of river kilometers estimated to contain at least one of these compounds. Imidacloprid is estimated to occur in 50% or greater of the canal and river resource extents, and it is the only compound found to exceed published toxicity or environmental effects standards. Geospatial analyses show sucralose detection frequencies within Florida’s drainage basins to be significantly related to the percentage of urban land use (R²?=?0.36, p?<?0.001), and imidacloprid detection frequencies to be significantly related to the percentage of urban and agricultural land use (R²?=?0.47, p?<?0.001). The extent of the presence of these compounds highlights the need for additional emerging contaminant studies especially those examining effects on aquatic biota.     

Pastoralists in a changing environment: The competition for grazing land in and around the W Biosphere Reserve,Benin Republic

Pastoralists face increasing competition for land with crop farmers and nature in and around the W Biosphere Reserve (WBR) in Benin. Our aim was to describe and analyse land use changes in order to understand their drivers, and to describe and analyse the viewpoints of relevant stakeholders in order to understand the competition for land. To this end, remote sensing data, regional statistics, and survey data were collected. We found that crop land expansion around the WBR was the direct driver of decrease of the grazing land area. Population growth and rising demand for food crops, and government support to the cotton sector were indirect drivers of grazing land reduction. Furthermore, competing claims on land among users arose from the complex interaction of crop expansion, presence of WBR and the way it is governed, the lack of support to pastoralists, and the increasing shift of pastoralists’ lifestyle into one of settled crop farmers. Pastoralism is under threat and its survival depends on the successful implementation of policies to support pastoralists and protect grazing lands.     

The Response of Hydrophytes to Environmental Pollution with Heavy Metals

The effects of Cu²⁺, Cd²⁺, and Ni²⁺ at low and high concentrations (0.025 and 0.25 mg/ml) on the accumulation capacity, the state of the pigment complex, and photosynthesis rate have been studied in model experiments with three floating hydrophytes (Hydrocharis morsus-ranae L., Lemna gibba L., and Potamogeton natans L.) and four submerged hydrophytes (Elodea canadensis Michx., Lemna trisulka L., Ceratophyllum demersum L., and Potamogeton lucens L.). Copper and cadmium are especially toxic at the concentrations studied. The effect of Cu²⁺ was the strongest in hydatophytes, and the effect of Cd²⁺, in pleustophytes. It is hypothesized that the differences between hydrophytes with respect to accumulation of metals and decrease in photosynthesis rate may cause predominant elimination of submerged species. Therefore, changes in the species structure of hydrophyte communities may be expected in waters polluted with metals.     

A Simulation Study to Assess the Sensitivity of a Forest Health Monitoring Network to Outbreaks of Defoliating Insects

The sensitivity of the United States Forest Health Monitoring network to outbreaks of defoliating insects was examined by means of a simulation study. A model constructed specifically for the study was used to generate a wide variety of defoliation patterns in forested landscapes. Forest configuration was that of Minnesota, USA, as expressed by the GAP land cover classification. Combinations of model parameters were based on a Latin Hypercube sample. The relationship between the average number of plots defoliated and outbreak characteristics was then examined via multiple regression. Both theoretical and model results pointed to a strong, linear relationship between the average number of plots defoliated and outbreak size. Model results provided additional insight, suggesting a significant relationship between the average number of plots defoliated and other outbreak characteristics after outbreak size was taken into account.     

Biomonitoring in the Boulder River Watershed, Montana, USA: Metal Concentrations in Biofilm and Macroinvertebrates, and Relations with Macroinvertebrate Assemblage

Portions of the Boulder River watershed contain elevated concentrations of arsenic, cadmium, copper, lead, and zinc in water, sediment, and biota. We measured concentrations of As, Cd, Cu, Pb, and Zn in biofilm and macroinvertebrates, and assessed macroinvertebrate assemblage and aquatic habitat with the objective of monitoring planned remediation efforts. Concentrations of metals were generally higher in downstream sites compared with upstream or reference sites, and two sites contained metal concentrations in macroinvertebrates greater than values reported to reduce health and survival of resident trout. Macroinvertebrate assemblage was correlated with metal concentrations in biofilm and macroinvertebrates. However, macroinvertebrate metrics were significantly correlated with a greater number of biofilm metals (8) than metals in invertebrates (4). Lead concentrations in biofilm appeared to have the most significant impact on macroinvertebrate assemblage. Metal concentrations in macroinvertebrates were directly proportional to concentrations in biofilm, indicating biofilm as a potential surrogate for monitoring metal impacts in aquatic systems.     

Introduced and cryptogenic species in Port Phillip Bay, Victoria, Australia

Port Phillip Bay (PPB) is a large (1,930 km²), temperate embayment in southern Victoria, Australia. Extensive bay-wide surveys of PPB have occurred since 1840. In 1995/1996 the Commonwealth Scientific and Industrial Research Organization (CSIRO) Centre for Research on Introduced Marine Pests (CRIMP) undertook an intensive evaluation of the region with the aims of developing a comprehensive species list of native and introduced biota and contrasting previous bay-wide assessments with a current field survey in order to detect new incursions and discern alterations to native communities. Two methods were used to meet these aims: a re-evaluation of regional museum collections and published research in PPB to identify and determine the timing of introductions; and field surveys for benthic (infauna, epifauna and encrusting) organisms between September 1995 to March 1996. One hundred and sixty introduced (99) and cryptogenic (61) species were identified representing over 13% of the recorded species of PPB. As expected, the majority of these are concentrated around the shipping ports of Geelong and Melbourne. Invasions within PPB appear to be increasing, possibly due to an increase in modern shipping traffic and an increase in aquaculture (historically associated with incidental introductions); however the records of extensive biological surveys suggest that this may, in part, be an artefact of sampling effort. In contrast to Northern Hemisphere studies, PPB (and Southern Hemisphere introductions in general) have significantly different suites of successfully invading taxa. PPB is presented as one of the most invaded marine ecosystems in the Southern Hemisphere.Communicated by M.S. Johnson, Crawley