Reaction mechanism and metal ion transformation in photocatalytic ozonation of phenol and oxalic acid with Ag+/TiO2

Photocatalytic ozonation of phenol and oxalic acid （OA） was conducted with a Ag^＋/TiO2 catalyst and different pathways were found for the degradation of different compounds. Ag^＋ greatly promoted the photocatalytic degradation of contaminants due to its role as an electron scavenger. It also accelerated the removal rate of OA in ozonation and the simultaneous process for its complex reaction with oxalate. Phenol could be degraded both in direct ozonation and photolysis, but the TOC removal rates were much higher in the simultaneous processes due to the oxidation of hydroxyl radicals resulting from synergetic effects. The sequence of photo-illumination and ozone exposure in the combined process showed quite different effects in phenol degradation and TOC removal. The synergetic effects in different combined processes were found to be highly related to the properties of the target pollutants. The color change of the solution and TEM result confirmed that Ag＋ was easily reduced and deposited on the surface of Tit2 under photo-illumination, and dissolved again into solution in the presence of ozone. This simple cycle of enrichment and distribution of Ag^＋ can greatly benefit the design of advanced oxidation processes, in which the sequences of ozone and photo-illumination can be varied according to the needs for catalyst recycling and the different properties of pollutants.     

科技期刊常用量的符号、名称及释义

正~~     

Characterization of extracellular polymeric substances in the biofilms of typical bacteria by the sulfur K-edge XANES spectroscopy

A combined approach of physicochemical extraction and sulfur K-edge X-ray absorption near-edge structure（XANES） spectroscopy was applied to characterize the extracellular polymeric substances（EPS） of typical bacterial biofilms in this study. Physicochemical analysis showed variation of the contents of DNA,polysaccharide and protein in different fractions of EPS in different mediums. The sulfur K-edge XANES analysis yielded a variety of spectra.Spectral fitting of the XANES spectra utilizing a large set of model compounds showed that there was more reduced sulfur in both LB-EPS（loosely bound EPS） and TB-EPS（tightly bound EPS） of all the biofilms in LB medium than in R2 A medium. More oxidized sulfur was identified in LB-EPS than that in TB-EPS,suggesting different niches and physiological heterogeneity in the biofilms. Our results suggested that the sulfur K-edge XANES can be a useful tool to analyze the sulfur speciation in EPS of biofilms.     

科技期刊常用量的符号、名称及释义

正~~     

科技期刊常用量的符号、名称及释义

正~~     

科技期刊常用量的符号、名称及释义

正~~     

《环境工程技术学报》投稿须知

正文稿应具有创新性、科学性、先进性、实用性,内容务求论点明确、论证可信、论据充分、数据准确、逻辑推理正确,文章结构严谨、层次清楚、重点突出、文笔精练、图表规范,并且是未在其他公开发行期刊或正式出版的论文集发表的作品。稿件需要清楚地提出问题。对所研究问题的背景,研究工作的目的,主要方法、原理与主要仪器设备,结果(包括主要数据)与分析以及结论等内容有清楚的描述。稿件涉及的研究项目应具有一定的前沿性,在已有的环境工程技术研究存量上,研制出新的技术方法、新     

人工湿地各工艺段对含氮物质的去除效果分析

文章就马料河复合人工湿地的除氮效果进行分析结果表明,整个湿地系统的TN去除率约为55.9%,TN削减量为28.87 kg/d,其中表面流湿地最高,氧化塘湿地次之,潜流湿地最差。湿地系统的最佳水力负荷为0.1~0.4 m3/(m2·d),最佳污染负荷为:TN 1.0~10 mg/L,NH3-N 0.1~1.0 mg/L。4-10月份,人工湿地中植物处于生长旺盛期,氮净化效果处于最佳状态。     

不同含磷物质对重金属污染土壤-水稻系统中重金属迁移的影响

通过水稻盆栽试验研究磷酸氢二钠(DSP)和羟基磷灰石(HAP)对污染土壤中重金属(Pb、Cd、Zn)向水稻迁移的影响.结果表明,①DSP和HAP都显著提高了土壤pH值和有效磷含量(p0.05),降低了土壤中Pb、Cd、Zn交换态含量,且HAP降低重金属交换态的效果较DSP好.水稻地上部分重金属含量与土壤中重金属交换态含量呈明显正相关关系,说明DSP和HAP通过降低土壤中重金属交换态含量从而达到减少重金属向水稻中迁移的目的.②DSP和HAP明显降低了水稻各器官Pb、Cd的含量,同时使水稻根、壳、糙米中Zn含量降低,但增加了茎叶中Zn的含量.与对照相比,DSP和HAP分别使糙米中Pb、Cd、Zn最大降低了48.72%、22.22%、25.35%和62.82%、66.67%、39.88%,但是糙米中Pb、Cd含量仍未达到食品卫生标准限值(GB2762—2012).③DSP和HAP处理都使水稻根干重逐渐减少,使茎叶、壳、糙米干重先增加后降低,在0.12 g·kg-1时使水稻糙米产量最大.综上,DSP和HAP都能有效控制土壤中Pb、Cd、Zn向水稻中迁移,且HAP效果比DSP好,但磷添加量不宜过高.     

《环境工程技术学报》投稿须知

正文稿应具有创新性、科学性、先进性、实用性,内容务求论点明确、论证可信、论据充分、数据准确、逻辑推理正确,文章结构严谨、层次清楚、重点突出、文笔精练、图表规范,并且是未在其他公开发行期刊或正式出版的论文集发表的作品。稿件需要清楚地提出问题。对所研究问题的背景,研究工作的目的,主要方法、原理与主要仪器设备,结果(包括主要数据)与分析以及结论等内容有清楚的描述。