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41.
Influence of iron, nickel and cobalt on biogas production during the anaerobic fermentation of fresh residual biomass 总被引:2,自引:0,他引:2
We have investigated the dependence of the rate of the production of biogas upon the concentration of nickel, cobalt and iron at sub-toxic concentration and monitored its composition as amount of hydrogen, methane and carbon dioxide. The distribution of the added metals between the liquid and solid phase has also been monitored.
The results of our investigations show that the addition of any of the listed metals to the sludge may cause the production of a higher amount of biogas and influence the methane or carbon dioxide percentage. Conversely, the effect on the hydrogen production depends upon the metal added, the age of the active sludge used, and its adaptation to the susbtrate. As a general feature, during the acidogenesis phase, nickel reduces, while iron increases, the percentage of dihydrogen in the biogas, while cobalt has no influence. 相似文献
The results of our investigations show that the addition of any of the listed metals to the sludge may cause the production of a higher amount of biogas and influence the methane or carbon dioxide percentage. Conversely, the effect on the hydrogen production depends upon the metal added, the age of the active sludge used, and its adaptation to the susbtrate. As a general feature, during the acidogenesis phase, nickel reduces, while iron increases, the percentage of dihydrogen in the biogas, while cobalt has no influence. 相似文献
42.
镍对纤维藻(Ankistrodesmus.sp.)毒性作用研究 总被引:1,自引:0,他引:1
本文研究了重金属镍对一种淡水绿藻──纤维藻(Ankistrodesmus.sp.)的毒性作用.结果表明:纤维藻对镍毒作用反应敏感.镍对纤维藻的半数有效浓度96EC50为0.33μg/mL镍,当镍浓度≥0.4μg/mL时,纤维藻的生长受到明显抑制,生长滞期延长,光合作用受阻,细胞膜透性增加.当镍浓度为3.2μg/mL时,其蛋白质氨基酸含量明显下降. 相似文献
43.
We studied the impact of industrial pollution on population demography (age structure), growth and reproduction of crowberry, Empetrum nigrum L. Crowberry growing in severely polluted sites near non-ferrous smelters (at Harjavalta, Monchegorsk and Nikel) was on average twice as old as in unpolluted habitats, as indicated by the number of annual rings at root collar. Shoot length decreased both with plant ageing and due to pollution impact, while neither the proportion of generative plants nor berry production was affected by pollution or plant age. Our results suggest that death of the extant individuals of E. nigrum near the non-ferrous smelters is to a large extent explained by age-related damage of the main stem accelerated by pollution. Since vegetative propagation, seed germination and seedling establishment are hampered by soil toxicity, E. nigrum populations near the smelters continue to decline with ageing in spite of the gradual decline of emissions. 相似文献
44.
A. M. Markkola U. Ahonen-Jonnarth M. Roitto R. Strmmer M. Hyvrinen 《Environmental pollution (Barking, Essex : 1987)》2002,120(3)
Scots pine seedlings were exposed to wet-deposited nickel (Ni) and removal of lichen cover in a dry heath Scots pine forest. Ni deposition affected the colonization of roots by indigenous ectomycorrhizal fungi in contrasting ways in intact and skimmed quadrats. Highest frequencies of tubercle morphotypes of ectomycorrhiza were found in quadrats exposed to 100 mg m−2 year−1 Ni in lichen covered treatment, while in skimmed quadrats these peaked after the treatment with 10 mg Ni m−2 year−1. Removal of the lichen layer increased the value of diversity index (H′) of ectomycorrhizal fungal community, probably due to the increase in the evenness of the morphotype distribution. Lichen removal seemed also to improve the condition of the short roots, as the frequencies of poor and senescent short roots were decreased by the removal. 相似文献
45.
Schaefer CE Fuller ME Condee CW Lowey JM Hatzinger PB 《Journal of contaminant hydrology》2007,89(3-4):231-250
Biological and abiotic approaches for treating co-mingled perchlorate, nitrate, and nitramine explosives in groundwater were compared in microcosm and column studies. In microcosms, microscale zero-valent iron (mZVI), nanoscale zero-valent iron (nZVI), and nickel catalyzed the reduction of RDX and HMX from initial concentrations of 9 and 1 mg/L, respectively, to below detection (0.02 mg/L), within 2 h. The mZVI and nZVI also degraded nitrate (3 mg/L) to below 0.4 mg/L, but none of the metal catalysts were observed to appreciably reduce perchlorate ( approximately 5 mg/L) in microcosms. Perchlorate losses were observed after approximately 2 months in columns of aquifer solids treated with mZVI, but this decline appears to be the result of biodegradation rather than abiotic reduction. An emulsified vegetable oil substrate was observed to effectively promote the biological reduction of nitrate, RDX and perchlorate in microcosms, and all four target contaminants in the flow-through columns. Nitrate and perchlorate were biodegraded most rapidly, followed by RDX and then HMX, although the rates of biological reduction for the nitramine explosives were appreciably slower than observed for mZVI or nickel. A model was developed to compare contaminant degradation mechanisms and rates between the biotic and abiotic treatments. 相似文献
46.
Gang Yu Xiaoliu Lü Tao Xu Yihui Zhou Qingjuan Peng Jinhua Ou Bonian Hu Zhihui Xie Xiping Lei 《环境科学学报(英文版)》2023,35(2):823-834
Electrocoagulation (EC) has been widely used to treat the heavy metal wastewater in industry. A novel process of sinusoidal alternating current electrocoagulation (SACC) is adopted to remove Ni2+ in wastewater in this study. The morphology of precipitates and the distribution of the main functional iron configurations were investigated. Ferron timed complex spectroscopy can identify the monomeric iron configurations [Fe(a)], oligomeric iron configurations [Fe(b)] and polymeric iron configurations [Fe(c)]. The optimal operating conditions of SACC process were determined through single-factor experiments. The maximum Ni2+ removal efficiency [Re(Ni2+)] was achieved under the conditions of pH0=7, current density (j) = 7 A/m2, electrolysis time (t) = 25 min, c0(Ni2+) = 100 mg/L. At pH=7, the proportion of Fe(b) and Fe(c) in the system was 50.4 at.% and 23.1 at.%, respectively. In the SACC process, Fe(b) and Fe(c) are the main iron configurations in solution, while Fe(c) are the vast majority of the iron configurations in the direct current electrocoagulation (DCC) process. Re(Ni2+) is 99.56% for SACC and 98.75% for DCC under the same optimum conditions, respectively. The precipitates produced by SACC have a high proportion of Fe(b) configurations with spherical α-FeOOH and γ-FeOOH structures which contain abundant hydroxyl groups. Moreover, it is demonstrated that Fe(b) has better adsorption capacity than Fe(c) through adsorption experiments of methyl orange (MO) dye. Fe(a) configurations in the homogeneous solution had no effect on the removal of nickel. 相似文献
47.
An invertebrate embryo toxicity test with the ampullariid snail, Marisa cornuarietis, to assess the toxicity of pesticides and heavy metals recently was established. Snail embryos were treated with atrazine (100, 1000, 10 000, and 30 000 μg/L), imidacloprid (10 000, 25 000, and 50 000 μg/L), Ni2+ (0.1, 1, 10, and 100 μg/L) or Zn2+ (100, 200, 500, 1000, 2000, and 5000 μg/L). The effect of these substances was examined by monitoring the following endpoints: mortality, formation of tentacles and eyes, heart rate, hatching, and weight after hatching. Effects in term of a significant delay on the formation of both tentacles and eyes were found after treatment with 100 μg/L Ni2+ or 200 μg/L Zn2+. The heart rate was shown to significantly decrease at 25 000 μg/L imidacloprid or 1000 μg/L Zn2+. At 100 μg/L atrazine, 10 μg/L Ni2+, or 1000 μg/L Zn2+ a significant delay in hatching became visible. No significant mortality was observed for the tested concentrations of atrazine, imidacloprid, or Ni2+, while 5000 μg/L Zn2+ resulted in 100% mortality after 10 d. The weight of freshly hatched individuals remained unaffected in all treatments. On the basis of the lowest observed effect concentrations (LOECs) recorded, we could show the M. cornuarietis embryo toxicity test (MariETT) to react up to three orders of magnitude more sensitive (for metals) and at least one order of magnitude more sensitive (for the tested organics) than the established Danio rerio embryo test. 相似文献
48.
Robert D. Cairns 《Resources Policy》1982,8(1):59-64
The level of rents attributable to natural resource producers depends on the risk faced by those producers. This paper argues that estimates of risk in mining should control for characteristics of firms such as diversification and debt financing. The capital asset pricing model is applied to securities of three Canadian nickel mining firms over the period 1961–1974. It is concluded that the level of risk was not unusually high. 相似文献
49.
50.