卟啉作为人体早期砷暴露生物标志的研究

采用氢化物发生原子吸收分析了贵州省燃煤污染型砷中毒区和非砷中毒区（对照）居民尿样中砷浓度,采用高效液相色谱法分析了卟啉浓度,考察了燃煤污染造成的人体砷暴露与尿液中卟啉排泄改变的关系,寻求慢性砷中毒早期健康效应的生物标志物.结果显示,与对照组相比,砷暴露组尿卟啉Ⅲ（uroporphyrin-Ⅲ）和粪卟啉Ⅲ（coproporphyrin-Ⅲ）显著增高（P＜0.01,P＜0.01）,粪卟啉Ⅰ（coproporphyrin-Ⅰ）比对照组增高,但不显著;不同性别组间比较,对照组和暴露组的中龄（20～40岁）群体尿液中,尿卟啉Ⅲ的浓度在男性和女性群体之间呈显著性的差异（P<0.01）,其它年龄组中,这一指标在不同性别群体之间未见显著性差异;不同年龄分层比较,低龄组（＜20岁）尿卟啉Ⅲ和粪卟啉Ⅲ比对照显著增高（P＜0.01,P＜0.01）,中龄组（20～40岁）和高龄组（＞40岁）粪卟啉Ⅲ比对照显著增高（P＜0.05,P＜0.05）;此外,砷暴露组尿液中砷与总粪卟啉和总卟啉呈正相关（r=0.623,r=0.549）.结果表明,人体砷暴露会导致尿液中卟啉排泄的改变,提示卟啉有可能作为慢性砷中毒早期健康效应的生物标志.     

Yard waste prediction from estimated municipal solid waste using the grey theory to achieve a zero-waste strategy

Environmental Science and Pollution Research - Yard waste is one of the key components of municipal solid waste and can play a vital role in implementing zero-waste strategy to achieve sustainable...     

Quantification of solid waste management system efficiency using input–output indices

Journal of Material Cycles and Waste Management - The assessment of solid waste management systems is vital for continued improvement in the efficiency of waste management systems (WMSs). Many...     

Employee voice behavior: A meta‐analytic test of the conservation of resources framework

Although voice (i.e. expressing change‐oriented ideas and suggestions) has frequently been investigated as a way for workers to reciprocate to their employers for the positive treatment they receive, much less is known about how workers use voice to deal with stress. This study takes a conservation of resources perspective to examine the relationships among workplace stress, voice behavior, and job performance. We first examined the strength of relationships of three major groups of workplace stressors and strains (job based, social based, and organization based) with voice behavior. We then examined the relationships of voice behavior with performance variables (e.g. in‐role performance and creativity) to investigate how voice may help workers preserve or accumulate resources to enhance their performance. The meta‐analytic findings presented here provide support for a negative relationship between workplace stress and voice and a positive relationship between voice behavior and performance outcomes. Copyright © 2011 John Wiley & Sons, Ltd.     

Risky driving and the perception of motorcycle accident causes among chinese motorcyclists in Hong Kong

Objective: The primary purposes of this study were to explore the relationship between risk-taking acts while driving motorcycles and perceived causes of motorcycle accidents, as well as their contribution to active involvement in traffic accidents among Chinese motorcyclists in Hong Kong. Active involvement means the riders was likely at fault for the crash. Methods: A total of 774 motorcyclists were recruited, of whom 292 had been involved in active motorcycle accident in the previous 3?years. All were asked to fill in a questionnaire, which was developed to assess their risk-taking acts while driving a motorcycle and perception of motorcycle accident causes. Results: The results of the study revealed 3 dimensions of accident causes, namely, driving-related, environment-related, and belief-related causes. These motorcycle accident causes were correlated with risk-taking acts while driving a motorcycle. A multivariate logistic regression analysis showed that risk-taking acts while driving motorcycles (adjusted odds ratio [OR]: 1.036, 95% confidence interval [CI]: 1.020-1.052), perception of driving-related cause (adjusted OR: 0.941, 95% CI: 0.916-0.967), and belief-related cause (adjusted OR: 1.134, 95% CI: 1.088-1.182) were significant factors contributing to involvement in active traffic accidents by motorcycle riders after controlling for concurrent demographic variables. Conclusions: The study highlights that perceived causes of motorcycle accidents are multidimensional, including those areas related to driving, the environment, and beliefs. It substantiates previous studies that a higher degree of driving-related risk perception is related to a lower degree of risk-taking acts while driving. Further research is needed to understand why belief-related causes, sometimes called superstitions, lead riders to believe that it is beyond their ability to affect accident causation and prevention.     

Evaluation of in situ catalysed hydrogen peroxide propagation (CHP) for phenanthrene and fluoranthene removals from soil and its associated impacts on soil functionality

Extensive contamination of soils by highly recalcitrant contaminants such as polycyclic aromatic hydrocarbons (PAHs) is an environmental problem arising from rapid industrialisation. This work focusses on the remediation of soil contaminated with 3- and 4-aromatic ring PAHs (phenanthrene (PHE) and fluoranthene (FLUT)) through catalysed hydrogen peroxide propagation (CHP). In the present work, the operating parameters of the CHP treatment in packed soil column was optimised with central composite design (H₂O₂/soil 0.081, Fe³⁺/soil 0.024, sodium pyrophosphate (SP)/soil 0.024, pH of SP solution 7.73). The effect of contaminant aging on PAH removals was also investigated. Remarkable oxidative PAH removals were observed for the short aging and extended aging period (up to 86.73 and 70.61 % for PHE and FLUT, respectively). The impacts of CHP on soil biological, chemical and physical properties were studied for both spiked and aged soils. Overall, the soil functionality analyses after the proposed operating condition demonstrated that the values for soil respiration, electrical conductivity, pH and iron precipitation fell within acceptable limits, indicating the compatibility of the CHP process with land restoration.     

Source Apportionment of Particulate Matter (PM10) and Indoor Dust in a University Building

A study on source apportionment of indoor dust and particulate matter (PM₁₀) composition was conducted in a university building by using chemometrics. The objective of this study was to investigate the potential sources of selected heavy metals and ionic species in PM₁₀ and indoor dust. PM₁₀ samples were collected using a low-volume sampler (LVS) and indoor dust was collected using a soft brush. Inductively coupled plasma spectrometry (ICP-MS) was used to determine the concentration of heavy metals, while the concentration of cations and anions was determined by atomic absorption spectrometer (AAS) and ion chromatography (IC), respectively. The concentration of PM₁₀ recorded in the building throughout the sampling period ranged from 20 ± 10 μgm^?3 to 80 ± 33 μgm^?3. The composition of heavy metals in PM₁₀ and indoor dust were dominated by zinc (Zn), followed by lead (Pb), copper (Cu), and cadmium (Cd). Principle component analysis (PCA) and multiple linear regression (MLR) showed that the main sources of pollutants in PM₁₀ came from indoor renovations (73.83%), vehicle emissions (16.38%), earth crust sources (9.68%), and other outdoor sources (0.11%). For indoor dust, the pollutant source was mainly earth crust. This study suggests that chemometrics can be used for forensic investigation to determine the possible sources of indoor contaminants within a public building.     

进水与曝气方式对SBR中活性污泥产率和性能的影响

在实验室SBR几种运行方式研究的基础上，分析了不同进水与曝气方式对SBR中活性污泥产率和性能的影响原因。结果表明：（1）在反应阶段分级曝气方式下，SBR反应器的污泥产率明显低；而短时进水方式下，反应器的污泥性能最佳。（2）克服了SBR反应初期的高需氧率，能大大加速此后的生化反应。     

Specific resistance to filtration of biomass from membrane bioreactor reactor and activated sludge: effects of exocellular polymeric substances and dispersed microorganisms.

This study investigates the effect of dispersed microorganisms and exocellular polymeric substances on biomass dewaterability. Specific resistance to filtration (SRF) was measured for biomass from a membrane bioreactor and a completely mixed activated sludge system. Both laboratory-scale reactors were fed with synthetic wastewater and operated at a high food-to-microorganism ratio (F/M) (1 to 11 kilograms chemical oxygen demand per kilogram mixed liquor volatile suspended solids per day [kgCOD/(kg MLVSS.d)]) and short solids retention times (0.25 to 5 d). The SRF values were affected by strong interactions of three parameters: (1) the mixed liquor suspended solids concentration, (2) the amount of dispersed microorganisms, and (3) the exocellular polymeric substances (EPS) concentration. At F/M smaller than 2 kg COD/(kg MLSS.d) and mixed liquor suspended solids (MLSS) concentration higher than 2000 mg/L, increasing amount of dispersed microorganisms in the biomass yielded higher SRF values. However, at high F/M (> 5 kg COD/kg MLSS.d) and low MLSS concentrations (< 600 mg/L), lower EPS concentrations resulted in slightly smaller SRF values, even though the amount of dispersed microorganisms in the biomass was much higher. Thus, at low MLSS concentrations, EPS concentrations rather than the amount of dispersed microorganisms tend to control SRF.