燃气与燃煤电厂主要污染物排放估算分析

SO2、NOx和CO2是燃气和燃煤电厂排放的主要大气污染物,以三种污染物排放估算方法为基础,比较了几种机组容量下,燃气机组和燃煤机组污染物的排放量。结果表明:燃气电厂因其在环境保护方面的显著优越性,是解决电站环境污染的重要出路。     

Real-world fuel efficiency and exhaust emissions of light-duty diesel vehicles and their correlation with road conditions

The real-world fuel efficiency and exhaust emission profiles of CO, HC and NO_x for light-duty diesel vehicles were investigated. Using a portable emissions measurement system, 16 diesel taxies were tested on different roads in Macao and the data were normalized with the vehicle specific power bin method. The 11 Toyota Corolla diesel taxies have very good fuel economy of (5.9 ± 0.6) L/100 km, while other five diesel taxies showed relatively high values at (8.5 ± 1.7) L/100 km due to the variation in transmission systems and emission control strategies. Compared to similar Corolla gasoline models, the diesel cars confirmed an advantage of ca. 20% higher fuel efficiency. HC and CO emissions of all the 16 taxies are quite low, with the average at (0.05 ± 0.02) g/km and (0.38 ± 0.15) g/km, respectively. The average NO_x emission factor of the 11 Corolla taxies is (0.56 ± 0.17) g/km, about three times higher than their gasoline counterparts. Two of the three Hyundai Sonata taxies, configured with exhaust gas recirculation (EGR) + diesel oxidation catalyst (DOC) emission control strategies, indicated significantly higher NO₂ emissions and NO₂/NO_x ratios than other diesel taxies and consequently trigger a concern of possibly adverse impacts on ozone pollution in urban areas with this technology combination. A clear and similar pattern for fuel consumption and for each of the three gaseous pollutant emissions with various road conditions was identified. To save energy and mitigate CO₂ emissions as well as other gaseous pollutant emissions in urban area, traffic planning also needs improvement.     

新疆二氧化硫排放环境学习曲线及减排潜力研究

基于2005—2010年SO2排放量和经济发展数据,对该时段的SO2排放环境负荷变化进行分析并以此数据构建了新疆三大地区万元产值SO2排放量随人均GDP变化的环境学习曲线;以所建立的环境学习曲线为依据,分析2005—2010年万元产值SO,的减排潜力,并对新疆“十二五”期间不同地区万元SO2的节能减排潜力进行了预测。结果表明：经济发展水平越高的地区,万元产值SO2排放环境负荷越小,减排潜力越小;经济发展水平越低的地区,万元产值SO2排放环境负荷越大,减排潜力也越大。研究结果将为“十二五”自治区SO2排放总量控制及减排指标提供科学依据。     

Instrumental and bio-monitoring of heavy metal and nanoparticle emissions from diesel engine exhaust in controlled environment

In the present article we characterized the emissions at the exhaust of a Common Rail (CR) diesel engine, representative of lightduty class, equipped with a catalyzed diesel particulate filter (CDPF) in controlled environment. The downstream exhausts were directly analyzed (for PM, CO, CO2, O2, HCs, NOx) by infrared and electrochemical sensors, and SEM-EDS microscope; heavy metals were chemically analyzed using mosses and lichens in bags, and glass-fibre filters all exposed at the engine exhausts. The highest particle emission value was in the 7–54 nm size range; the peak concentration rose until one order of magnitude for the highest load and speed. Particle composition was mainly carbonaceous, associated to noticeable amounts of Fe and silica fibres. Moreover, the content of Cu, Fe, Na, Ni and Zn in both moss and lichen, and of Al and Cr in moss, was significantly increased. Glass-fibre filters were significantly enriched in Al, B, Ba, Cu, Fe, Na, and Zn. The role of diesel engines as source of carbonaceous nanoparticles has been confirmed, while further investigations in controlled environment are needed to test the catalytic muffler as a possible source of silica fibres considered very hazardous for human health.     

餐饮废弃油脂的生物柴油生命周期能耗与CO_2排放分析

对以餐饮废弃油脂为原料,利用化学催化法生产的生物柴油进行了生命周期能耗与CO2排放分析,以具有1 MJ能量的生物柴油产品为功能单位.结果表明:生物柴油生命周期总能耗为1.648 9 MJ,化石能耗为0.616 9 MJ,化石能效比为1.62,生命周期净能量产出为0.383 1 MJ,生命周期CO2净排放量为-10.34 g.与生产和使用1 MJ能量的石化柴油相比,生物柴油生命周期总能耗升高37%,化石能耗降低49%,可减少CO2排放90.99 g.     

Methane emissions during storage of different treatments from cattle manure in Tianjin

Many studies on methane emissions from animal manure have revealed that animal manure is a major source of methane emissions to the atmosphere that can have negative consequences for people,animals and environment.In general,the release of methane can be influenced by the type of feed taken by animals,temperature,manure characteristics and so on.This study aimed at quantifying and comparing methane release from dairy manure with different piling treatments.Four treatments were designed including manure piling height 30,45,60 cm and adding 6 cm manure every day until the piling height was 60 cm.Static chamber method and gas chromatography were adopted to measure the methane emissions from April to June in 2009.Methane emission rates of all four manure treatments were low in the first week and then increased sharply until reaching the peak values.Subsequently,all the methane emission rates decreased and fluctuated within the steady range till the end of the experiment.Wilcoxon nonparametric tests analysis indicated that methane emission rate was greatly influenced by manure piling height and manner.There were no significant relationships between methane emission rates and the temperatures of ambience and heap.However,regression analysis showed that the quadratic equations were found between emission rates of all treatments and the gas temperature in the barrels.     

水旱轮作稻田旱作季种植不同作物对CH4和N2O排放的影响

甲烷（CH4）和氧化亚氮（N2O）是仅次于二氧化碳（CO2）的重要温室气体,农田是大气CH4和N20的重要来源,但目前农业措施对CH4和N2O排放的影响尚不明确。以水旱轮作稻田旱作季休闲为对照,采用静态箱．气相色谱法研究了种植紫云英、黑麦草、冬小麦以及油菜等4种作物对稻田旱作季CH4和N2O排放及其温室效应的影响。结果表明：水旱轮作稻田旱作季CH4排放通量较低,而N2O排放较为明显。稻田旱作季CH4平均排放通量表现为油菜〉黑麦草〉冬小麦〉紫云英〉休闲,依次为8．96、7．19、6．94、6．52和6．02μg·m-2·h-1,季节N20平均排放通量的顺序是油菜（61．1lμg·m-2·h-1）〉冬小麦（52．5lag·m-2·h-1）〉黑麦草（34．0μg·m-2·h。）〉休闲（15.3lμg·m-2·h-1）〉紫云英（13．6lμg·m-2·h-1）。稻田旱作季种植不同作物对CH4和N2O季节总排放量的影响达到极显著水平（P〈0．01）,C144和N2O季节总排放量均以种植油菜为最大,分别达到43．2和294．7mg·m-2,比对照休闲增加49％和299％。种植油菜、冬小麦和黑麦草较对照休闲显著增加稻田旱作季总增温潜势（P〈0．05）,紫云英和休闲处理间总增温潜势无显著差异（P〉0．05）。研究表明,种植油菜、冬小麦和黑麦草等作物由于氮肥的施用增加了水旱轮作稻田旱作季温室效应。     

钢铁行业废水处理中的膜用阻垢剂的研究

介绍钢铁行业用水及排水现状,水质特点,水处理技术的水平,适用于钢铁行业水处理零排放工程的一般预处理及深度反渗透处理工艺,采用这种工艺存在的问题及国内外广泛采用的解决方法。针对中水水质特性、水质结垢特点、阻垢剂机制,研究出一种适用于钢铁行业中水回用的膜用阻垢剂,通过实验室动态试验,结果说明:该药剂具有良好的阻垢分散效果,达到国内外普遍采用的阻垢分散剂的阻垢效果,在钢铁行业废水回用处理中有良好的适用性。     

中国城市碳达峰趋势的聚类分析

中国在2020年9月提出2060年碳中和目标,并提出加快落实2030年国家碳达峰任务。考虑到城市在国家碳减排工作中的重要使命和极大潜力,以及其碳排放在总量、结构、行动进展和趋势上存在的显著差异,深入认识中国城市碳达峰趋势的类型特征,对地方政府设计和开展差异化达峰行动具有重要意义。本文综合考虑影响城市碳达峰趋势的静态因素和动态因素,采用蒙特卡洛方法与K均值聚类算法,对中国286个样本城市的达峰趋势进行了分类分析。结果表明,中国城市的达峰类型可以划分为5类,根据其特点可概括为低碳潜力型城市、低碳示范型城市、人口流失型城市、资源依赖型城市和传统工业转型期城市。其中,低碳潜力型城市和传统工业转型期城市是决定我国能否落实2030年达峰行动的关键。最后,针对不同类型城市,本文对城市碳达峰的目标设计和行动重点提出了切实建议。     

“双碳”目标下青岛高新区低碳发展路径研究

工业园区是我国工业发展的重要载体和强大引擎,是实现碳达峰和碳中和目标的重要抓手。本文以青岛高新区为研究对象,编制了2016—2020年该园区的温室气体排放清单,通过情景分析探讨了其碳达峰路径,并为中国工业园区的低碳发展提出了低碳发展政策建议。研究显示,2016—2020年,青岛高新区碳排放总量从32.88万t增加至43.78万t,碳排放强度由0.47 t/万元降至0.36 t/万元。工业能耗是青岛高新区碳排放的最大贡献者,也是其实现碳达峰的关键部门。生活用能的碳排放占比逐年增大,是青岛高新区实现碳达峰的重要影响因素。通过优化能源消费结构、提升能源利用效率、推进集中供热设施、煤改气等举措,青岛高新区预计在2025年实现碳达峰,碳排放总量达到71.58万t,碳排放强度降至0.27 t/万元。我国需制定统一的工业园区温室气体排放核算方法,建立工业园区温室气体排放数据库,将碳达峰碳中和目标要求纳入工业园区经济社会发展中长期规划,充分挖掘能源及环境基础设施的减排潜力,促进我国工业园区低碳发展。