Physico-chemical characterization of Residual Household Waste for energy recovery in insular territories: Case study of Reunion Island

Waste-to-energy is a promising approach to face the current challenge of waste overproduction in Reunion Island, a French territory. In this particular context of an isolated and tropical territory, it is essential to study the properties of potential feedstocks to choose the most appropriate conversion process. This article reports on the composition of Residual Household Waste from Reunion Island and its physico-chemical parameters. Twelve representative samples of Residual Household Waste were subjected to thermal and elemental analysis. The results showed that their composition had a significant influence on the physico-chemical properties, including calorific value. Residual Household Waste from the selective sorting (rich in wood, plastic, and sanitary textiles) as well as dry mixed RHW are the most interesting for energy recovery. Due to their high volatile matter and high carbon content, and their low moisture content, these types of waste have a high calorific value exceeding 18 MJ/kg. Furthermore, the RHW sample comply with the environmental and health criteria applied by French regulations concerning halogen and heavy metal. Thus, it seems that Residual Household Waste can be an alternative to conventional fuels used in incineration or pyro-gasification processes. However, the study also points the need for a pre-treatment process for these wastes. Indeed, it is necessary to sort them correctly in order to avoid the risks of pollution and important maintenance. And more importantly, drying beforehand is unavoidable to improve combustibility and obtain optimal energy conversion.     

Environmental pollution,hydropower and nuclear energy generation before and after catastrophe: Bathtub-Weibull curve and MS-VECM methods

In this paper, the life span of hydro and nuclear energy generations and the relationship between hydro and nuclear energy generations, environmental pollution, and economic growth were investigated for Japan covering the period of 1960–2018 by employing the Bathtub-Weibull curve and Markov switching-vector error correcting (MSVEC) method, respectively. According to the Bathtub-Weibull curve analysis, a rising failure rate for nuclear energy was found, indicating that the life of nuclear energy has expired, but a decreasing failure rate for hydroelectric energy has been detected. Then two different MSVEC models were used. The MSVEC method, unlike traditional approaches, determines the relationship between variables under different regimes. The results of MSVEC methods indicate three important points. First, regime-dependent asymmetry and regime changes are crucial for policy recommendations. Second, the shocks to hydropower and nuclear energy generations cause temporary deviations from the long-run growth path in both regimes. Lastly, the increase in hydropower generation leads to a decrease in environmental pollution and an increase in GDP, and an increase in nuclear power generation increases pollution and growth in both regimes.     

Effect of pyrolysis and oxidation characteristics on lauric acid and stearic acid dust explosion hazards

The effect of pyrolysis and oxidation characteristics on the explosion sensitivity and severity parameters, including the minimum ignition energy MIE, minimum ignition temperature MIT, minimum explosion concentration MEC, maximum explosion pressure P_max, maximum rate of pressure rise (dP/dt)_max and deflagration index K_st, of lauric acid and stearic acid dust clouds was experimentally investigated. A synchronous thermal analyser was used to test the particle thermal characteristics. The functional test apparatuses including the 1.2 L Hartmann-tube apparatus, modified Godbert-Greenwald furnace, and 20 L explosion apparatus were used to test the explosion parameters. The results indicated that the rapid and slow weight loss processes of lauric acid dust followed a one-dimensional diffusion model (D1 model) and a 1.5 order chemical reaction model (F1.5 model), respectively. In addition, the rapid and slow weight loss processes of stearic acid followed a 1.5 order chemical reaction model (F1.5 model) and a three-dimensional diffusion model (D3 model), respectively, and the corresponding average apparent activation energy E and pre-exponential factor A were larger than those of lauric acid. The stearic acid dust explosion had higher values of MIE and MIT, which were mainly dependent on the higher pyrolysis and oxidation temperatures and the larger apparent activation energy E determining the slower rate of chemical bond breakage during pyrolysis and oxidation. In contrast, the lauric acid dust explosion had a higher MEC related to a smaller pre-exponential factor A with a lower amount of released reaction heat and a lower heat release rate during pyrolysis and oxidation. Additionally, due to the competition regime of the higher oxidation reaction heat release and greater consumption of oxygen during explosion, the explosion pressure P_m of the stearic acid dust was larger in low concentration ranges and decayed to an even smaller pressure than with lauric acid when the concentration exceeded 500 g/m³. The rate of explosion pressure rise (dP/dt)_m of the stearic acid dust was always larger in the experimental concentration range. The stearic acid dust explosion possessed a higher P_max, (dP/dt)_max and K_st mainly because of a larger pre-exponential factor A related to more active sites participating in the pyrolysis and oxidation reaction. Consequently, the active chemical reaction occurred more violently, and the temperature and overpressure rose faster, indicating a higher explosion hazard class for stearic acid dust.     

肥煤自燃全过程热动力学特征参数研究

实验测定了林西矿肥煤样品30~900℃煤自燃全过程热动力学特征参数,得出:TG/DTG曲线显示煤样DTG初始临界温度45℃,干裂温度122℃,活性温度195℃,增速温度265℃,质量极大值温度342℃,着火温度465℃,最大热失重速率温度515℃和燃尽温度690℃;DSC曲线显示,煤样初始放热温度60℃、最大热释放速率温度511℃。结合TG-DTG-DSC曲线综合分析可知,煤温达到510℃左右时煤样反应最剧烈。由煤自燃标志气体测定实验系统得出:煤温130℃后CO,CO 2释放量迅速增加,210℃增加速度下降;CH 4,C 2 H 6含量变化具有规律性且两者变化相近;C 2 H 4出现温度为130℃;C 2 H 4/C 2 H 6比值在190~350℃有较强的规律性,呈上升趋势且上升速度较快;350℃之后,CH 4,C 2 H 6,C 2 H 4体积分数均开始急剧增大;C 2 H 4/CO与C 2 H 4/CO 2变化趋势大致相同,在130~350℃时缓慢增长,达到350℃后比值呈指数形式上升。经拟合曲线,得到活化能的3个突变点温度:70,180,220℃,其中180℃与交叉点温度相吻合。通过以上研究,得到了肥煤自燃全过程的热力学特征参数,为实际生产中防治煤自燃提供了理论依据。     

液氮泡沫发生器内流动特性研究

低温液氮与泡沫混合液直接接触产生氮气泡沫是一种新型的掺混形式,利用液氮高汽化比的特点,搭建液氮泡沫可视化实验装置,进行氮气-水两相流及液氮泡沫流动特性的研究。结果表明,液氮相变产生大量氮气,其与泡沫液混合产生泡沫,温度有所回升,最终趋于泡沫混合液温度;管路沿程压降较小;液氮射流破碎及流动过程可分为6个区域:低温液氮区、向上循环翻滚区、滞留区、泡沫与泡沫混合液混合区、致密泡沫区、泡沫混合液区。流体向下游流动过程中持续发泡;为防止管路结冰,需合理控制泡沫混合液与液氮流量。     

Effects of falling weight impact on industrial safety helmets used in conjunction with eye and face protection devices

Industrial workplaces pose concurrent hazards to the upper part of the head and the eyes. Under the circumstances, workers may use protective helmets in conjunction with protective goggles or spectacles. In order to assess the compatibility of this equipment, a method and a test stand for evaluating the behavior of safety helmets and protective goggles/spectacles upon the impact of a falling weight were designed. The results of tests concerning the displacement and deformation of helmets and spectacles/goggles, the forces acting on the helmets, as well as the forces exerted by the spectacles/goggles on the headform upon falling weight impact are presented. The results revealed the ways in which the tested equipment interacted with each other. The influence of equipment construction on the test results was analyzed and inferences concerning the safety of the studied protective devices were made. Some general construction guidelines were formulated for the compatibility of the equipment.     

Toward sustainable use of natural resources: Nexus between resource rents,affluence, energy intensity and carbon emissions in developing and transition economies

Sustainable use of natural resources would entail ensuring that derived economic benefits today do not undermine the welfare of generations to come. On this basis, this study examines the nexus between natural resource rents and carbon dioxide (CO₂) emissions disaggregated into production and consumption-based (i.e., trade-adjusted) CO₂ emissions for a selected panel of 45 developing and transition economies over the period 1995–2017. The empirical model also incorporates the impacts of population, affluence, and energy intensity. The results show that affluence increases production-based CO₂ emissions by 1.407%, with the EKC's predicted inverted U-shaped curve only explaining consumption-based CO₂ emissions. Economic reliance on natural resource rents and energy intensification contribute 0.022% and 0.766%, respectively, to CO₂ emissions embedded in territorial production inventories and 0.035% and 0.583%, respectively, to CO₂ emissions embedded in consumption inventories. The bootstrap non-causality test shows that historical data on each variable has significant predictive power for future CO₂ emissions from both sources. The historical information about natural resource rents has significant predictive power over the future levels of affluence and energy intensity. Clearly, the results show that the environmental impact of natural resource rents is stronger when CO₂ emissions are adjusted for trade and varies among the countries, with Bangladesh, Guinea, India, Malaysia, Mexico, Nigeria, Pakistan, Saudi Arabia, Vietnam, and Zimbabwe among the most affected countries. Overall, this study provides motivation for policies to keep the use of natural resources within sustainable limits.     

Study of lignocellulosic biomass ignition properties estimation from thermogravimetric analysis

In the last decade, the use of renewable resources has increased significantly in order to reduce the energetic dependence on fossil fuels, as they have an important contribution to the global warning and greenhouse gasses effect. Because of that, research on biofuels has been increased in the last years as its characteristics of use match those of the conventional fuel's: solid biomass can be used instead of coals, and biodiesel could replace diesel. Research on solid biomass ignition properties has been considerably developed because of the amount of industrial accidents related to the treatment and use of solid biomass (self-ignition, dust explosions, etc.). On the other hand, thermogravimetric analysis (TGA) is becoming and important characterization technique as it can be used to determine a wide spectrum of properties, such as kinetics, composition, proximate analysis, etc. This research aims to combine thermal analysis and ignition properties, by using the TGA to obtain the elemental composition of lignocellulosic biomass and compare those results to Minimum Ignition Energy (MIE) values test output, so a relation between composition and MIE can be found.To achieve this aim, biomass samples from different origins have been used: oil palm wastes (empty fruit bunches, mesocarp fiber and palm kernel shell), agricultural wastes (straw chops) and forestry wastes (wood chips and wood powder). Also, raw materials and torrefied biomass were compared. The hemicellulose/cellulose ratio was calculated and compared to different flammability properties, finding out that the greater the ratio and the lower the onset temperature (temperature at which the pyrolysis reaction accelerates), the lower was the minimum ignition energy. From this basis it was possible to define “tendency areas” that grouped the samples whose MIE values were similar. Three tendency areas were found: high minimum ignition energy, medium minimum ignition energy, and low ignition energy.     

两种有机锌络合物处理棉花的霉变及热解行为研究

棉花是纺织业的重要原料,是人民群众生活不可或缺的必需品,同时也是我国进出口重要的商品。研究如何安全有效地进行棉花的储备具有十分重要的现实意义。棉纤维本身含有脂肪、蜡质和果胶等适合微生物生长繁殖的营养物质。在棉花储备中,高的回潮率会加速微生物的繁殖,进而产生热量。热量的累积会引起温度升高以及棉花霉变,不利于棉花的安全有效储存。因此,通过静电吸附法将安全无毒的有机锌络合物附着在棉纤维表面,研究表明,相同条件下,处理棉的霉变状况明显得到抑制。加速发霉条件下,未处理棉的相对于白纸的平均色差值为28.10,而双乙酸锌以及苯甲酸锌防霉处理棉的色差值分别为5.16和5.86,下降了81.6%和79.1%。自然发霉条件下,双乙酸锌以及苯甲酸锌防霉处理棉的色差值分别下降了53.8%和50.7%。同时研究了纯棉以及处理棉氮气下的热分解动力学,相比于未处理棉,双乙酸锌防霉处理后活化能下降了15.8%,而苯甲酸锌防霉处理后活化能下降了10.9%。此外,利用实时红外和热重红外联用技术得到了样品在热解过程中固相以及气相的裂解产物的红外谱图,发现防霉处理能一定程度上抑制棉花热解。     

单轴应力对煤自燃特性参数和导热系数的影响研究

为探究单轴应力作用下煤氧化和传热特性，利用自制荷载加压煤自燃特性参数测定装置对炉体内长焰煤煤样进行程序升温。结合程序升温过程中煤临界温度Tc和Tg，对其进行阶段划分:阶段1为30℃~Tc；阶段2为Tc~Tg。计算了不同单轴应力下2个阶段煤表观活化能和平均耗氧速率。根据能量守恒得出程序升温过程煤导热系数随温度的变化，进一步分析煤导热系数与单轴应力的关系。结果表明:阶段1单轴应力为4 MPa时为临界轴压，煤表观活化能最大，平均耗氧速率最小；阶段2煤表观活化能和平均耗氧速率随单轴应力增大均呈抛物线变化，单轴应力为2.7 MPa时为临界轴压，煤表观活化能最大，平均耗氧速率最小；阶段1和2煤导热系数随温度升高均先减小后增大，并且煤导热系数随单轴应力增大呈三次函数变化。