首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   4365篇
  免费   220篇
  国内免费   1627篇
安全科学   307篇
废物处理   281篇
环保管理   337篇
综合类   2449篇
基础理论   740篇
污染及防治   1577篇
评价与监测   160篇
社会与环境   152篇
灾害及防治   209篇
  2024年   3篇
  2023年   63篇
  2022年   230篇
  2021年   180篇
  2020年   127篇
  2019年   144篇
  2018年   149篇
  2017年   230篇
  2016年   229篇
  2015年   249篇
  2014年   315篇
  2013年   479篇
  2012年   359篇
  2011年   433篇
  2010年   276篇
  2009年   270篇
  2008年   346篇
  2007年   270篇
  2006年   256篇
  2005年   166篇
  2004年   122篇
  2003年   169篇
  2002年   133篇
  2001年   103篇
  2000年   128篇
  1999年   112篇
  1998年   102篇
  1997年   114篇
  1996年   82篇
  1995年   86篇
  1994年   61篇
  1993年   61篇
  1992年   56篇
  1991年   44篇
  1990年   27篇
  1989年   9篇
  1988年   6篇
  1987年   6篇
  1986年   5篇
  1985年   2篇
  1984年   3篇
  1983年   3篇
  1982年   3篇
  1981年   1篇
排序方式: 共有6212条查询结果,搜索用时 268 毫秒
1.
Environmental Science and Pollution Research - Hydrothermal liquefaction (HTL) of biomass used HTL reaction under high temperature and pressure to produce bio-oil. This technology is considered as...  相似文献   
2.
• Magnetotactic bacteria (MTB) synthesize magnetic nanoparticle within magnetosomes. • The morphologic and phylogenetic diversity of MTB were summarized. • Isolation and mass cultivation of MTB deserve extensive research for applications. • MTB can remove heavy metals, radionuclides, and organic pollutants from wastewater. Magnetotactic bacteria (MTB) are a group of Gram-negative prokaryotes that respond to the geomagnetic field. This unique property is attributed to the intracellular magnetosomes, which contains membrane-bound nanocrystals of magnetic iron minerals. This review summarizes the most recent advances in MTB, magnetosomes, and their potential applications especially the environmental pollutant control or remediation. The morphologic and phylogenetic diversity of MTB were first introduced, followed by a critical review of isolation and cultivation methods. Past research has devoted to optimize the factors, such as oxygen, carbon source, nitrogen source, nutrient broth, iron source, and mineral elements for the growth of MTB. Besides the applications of MTB in modern biological and medical fields, little attention was made on the environmental applications of MTB for wastewater treatment, which has been summarized in this review. For example, applications of MTB as adsorbents have resulted in a novel magnetic separation technology for removal of heavy metals or organic pollutants in wastewater. In addition, we summarized the current advance on pathogen removal and detection of endocrine disruptor which can inspire new insights toward sustainable engineering and practices. Finally, the new perspectives and possible directions for future studies are recommended, such as isolation of MTB, genetic modification of MTB for mass production and new environmental applications. The ultimate objective of this review is to promote the applications of MTB and magnetosomes in the environmental fields.  相似文献   
3.
赵光骞 《环境与发展》2020,(2):148-148,150
在我国社会经济快速发展的过程中,人们对自然资源需求无度,造成生态环境破坏问题非常严重。通过环境监测可以及时分析空气中有毒有害的物质成分,并且对环境污染问题进行及时有效的解决。但是在监测的过程中所采用大量的空气试剂很容易造成环境二次污染等问题,为此必须要积极加强对环境监测中重金属污染的合理控制,对空气试剂产生的大量废弃物进行及时的回收处理,从而有效避免出现二次污染的情况,充分发挥环境监测的作用。  相似文献   
4.
Concentrations of eight trace metals (TMs) in road dust (RD) (particles?<?25 μm) from urban areas of Xinxiang, China, were determined by inductively coupled plasma mass spectrometry. The geometric mean concentrations of Zn, Mn, Pb, As, Cu, Cr, Ni and Cd were 489, 350, 114, 101, 60.0, 39.7, 31.6, and 5.1 mg kg?1, respectively. When compared with TM levels in background soil, the samples generally display elevated TM concentrations, except for Cr and Mn, and for Cd the enrichment value was 69.6. Spatial variations indicated TMs in RD from park path would have similar sources with main roads, collector streets and bypasses. Average daily exposure doses of the studied TMs were about three orders of magnitude higher for hand-to-mouth ingestion than dermal contact, and the exposure doses for children were 9.33 times higher than that for adults. The decreasing trend of calculated hazard indexes (HI) for the eight elements was As?>?Pb?>?Cr?>?Mn?>?Cd?>?Zn?>?Ni?>?Cu for both children and adults.  相似文献   
5.

Efficient abatement of an iodinated X-ray contrast media iohexol by an emerging sulfite autoxidation advanced oxidation process is demonstrated, which is based on transition metal ion–catalyzed autoxidation of sulfite to form active oxidizing species. The efficacy of the combination of sulfite and transition metal ions (Ag(I), Mn(II), Co(II), Fe(II), Cu(II), Fe(III), or Ce(III)) was tested for iohexol abatement. Co(II) and Cu(II) are proven to show more pronounced catalytic activity than other metals at pH 8.0. According to the quenching studies, sulfate radical (SO4??) is identified to be the primary species for oxidation of iohexol. Increasing dosages of metal ion or sulfite and higher pH values are favorable for iohexol abatement. Inhibition of iohexol abatement is observed in the absence of dissolved oxygen, which is vital for the production of SO5?? and subsequent formation of SO4??. Overall, activation of sulfite to produce reactive radicals with extremely low Co(II) or Cu(II) concentrations (in the range of μg L?1) in circumneutral conditions is confirmed, which offers a potential SO4??-based advanced oxidation process in treatment of aquatic organic contaminants.

  相似文献   
6.
Chang  Xiaoqiang  Chen  Xingyu  Zhang  Shuaichen  Lu  Sixian  Zhao  Yifan  Zhang  Dong  Yang  Lan  Ma  Yue  Sun  Peng 《Environmental Chemistry Letters》2023,21(2):681-687
Environmental Chemistry Letters - Branched allylic sulfones are scaffolds widely distributed in bioactive molecules and organic functional materials. The synthesis of allylic sulfones has been...  相似文献   
7.
Environmental Geochemistry and Health - By investigating three dominant mangrove species, namely Aegiceras corniculatum, Kandelia candel, Ceriops tagal and their rhizosediment in Mangrove wetlands...  相似文献   
8.
Environmental Science and Pollution Research - The scope of this study is to analyze the carbon emissions intensity of electricity generation in “Belt and Road Initiative” (BRI)...  相似文献   
9.
Chen  Hui  Mao  Wei  Shen  Yiqiu  Feng  Weiwei  Mao  Guanghua  Zhao  Ting  Yang  Lanqin  Yang  Liuqing  Meng  Chunfeng  Li  Yong  Wu  Xiangyang 《Environmental science and pollution research international》2019,26(24):24609-24619

Phthalates (PAEs) in drinking water sources such as the Yangtze River in developing countries had aroused widespread concern. Here, the water, suspended particulate matter (SPM), and sediment samples were collected from 15 sites in wet and dry seasons in Zhenjiang, for the determination of six PAEs (DMP, DEP, DIBP, DBP, DEHP, and DOP) using the solid-phase extraction (SPE) or ultrasonic extraction coupled with gas chromatography-mass spectrometry (GC-MS). The total concentrations of six PAEs (Σ6PAEs) spanned a range of 2.65–39.31 μg L?1 in water, 1.97–34.10 μg g?1 in SPM, and 0.93–34.70 μg g?1 in sediment. The partition coefficients (Kd1) of PAEs in water and SPM phase ranged from 0.004 to 3.36 L g?1 in the wet season and from 0.12 to 2.84 L g?1 in the dry season. Kd2 of PAEs in water and sediment phase was 0.001–9.75 L g?1 in the wet season and 0.006–8.05 L g?1 in the dry season. The dominant PAEs were DIBP, DBP, and DEHP in water and SPM, DIBP, DEHP, and DOP in sediment. The concentration of DBP in water exceeded the China Surface Water Standard. The discharge of domestic sewage and industrial wastewater might be the main potential sources of PAEs. The risk quotient (RQ) method used for the risk assessment revealed that DBP (0.01 < RQ < 1) posed a medium risk, while DIBP and DEHP (RQ > 1) posed a high environmental risk in water, DIBP (RQ > 1) also showed a high risk in sediment.

  相似文献   
10.
Environmental Science and Pollution Research - In this study, a composite aerogel (WP-MMT) composed of wastepaper (WP) and montmorillonite (MMT) was prepared by ambient pressure drying technology...  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号