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1.
有机污染物在被动采样材料与环境介质之间的平衡分配系数(K_P),是测定环境中有机污染物浓度的重要参数,但K_P值大部分都需要经过繁琐的实验测定获取,无法逐个测定数量繁多的污染物,因此需开发一种预测K_P值的方法。为此,搜集整理了一些多环芳香烃(PAHs)和多氯联苯(PCBs)的低密度聚乙烯(LDPE)-空气分配系数(K_PA)的实测值,基于理论线性溶解能(TLSER)和定量结构性质关系(QSPR),利用逐步多元线性回归(MLR)分别构建了预测K_PA值的模型。模型的决定系数R2adj分别为0.927和0.956,交叉验证系数Q2LOO分别为0.915和0.946,外部系数Q2ext分别为0.913和0.960。结果表明,2种模型具有良好的拟合优度、稳健性和预测能力,并解释了模型的机理。所构建的2种模型均可用来预测应用域内有机污染物的LDPE膜-空气分配系数。  相似文献   
2.
Simulation of helio-photovoltaic system is continuously undergoing revolution through diverse parameter modifications which closely mimic the experimental data. In retrospect, the current work has presented a nonlinear modification of equivalent circuit parameters and simulated the same for different semiconductors (crystalline and thin films); furthermore, established a mathematical relation between the coefficients of solar irradiance and module temperature (SIMT); moreover, investigated the influence of SIMT on the model parameters. The simulation upshot reveals that increment in solar irradiance (SI) intensifies the output current whereas an increase in module temperature (MT) diminishes the output voltage; the SIMT coefficients developed validated well with the manufacturers data; the influence of SI was evident on the photon current, diode current, and shunt resistance whereas the effect of MT was pronounced on the diode current, ideality factor, and shunt resistance. Thus, the provision made by this work is essential for advanced design and simulation of helio-photovoltaic systems.  相似文献   
3.
In this communication, a new design of solar-energy-based water distillation cum drying unit with parabolic reflector has been designed, fabricated, and tested. Bitter gourd and potato slices are chosen as a drying commodity. Thermal performance of the developed system has been evaluated based on the experimental results and using linear regression analysis. Heat transfer coefficients (convective, evaporative, and radiative) for solar distillation system have been observed to be 2.48–4.09, 13.25–52.38, and 8.75–9.66 W/m2°C, respectively. Overall thermal efficiency and exergy efficiency for the distillation system has been found to be 18.77% and 1.2%, respectively. The convective heat transfer coefficient for potato slices are observed higher for initial hours and decreases as the day progresses. The average convective heat transfer coefficients for bitter gourd and potato slices have been observed as 2.18 and 5.04 W/m2°C, respectively. Experimental error in terms of percent uncertainty for bitter gourd and potato slices are found to be 42.93% and 37.06%, respectively. The present design of solar distillation and drying in a single unit could be beneficial for the development of remote, arid, and rural areas.  相似文献   
4.
从安全投入产出分析的角度为安全投入决策提出一个新视角,相比于直接用生产函数等数学方法得到安全投入与安全产出的关系,通过软件分析得出各个要素与安全产出的关系,再进行拟合,最后得到安全产出回归方程,这样得到的分析结果更准确和可信。通过实例可以证明如果要确定安全投入要素之间的分配比例可以采用生产函数分析方法,如要预测安全产出可以采用根据散点图做出的回归方程。另外,在分析安全投入要素相对重要度时,因为各个投入要素的数量级和单位的不同,回归方程系数应选择标准化回归系数;要预测安全投入产生的安全产出则应采用非标准化回归系数。  相似文献   
5.

Octanol‐water partition coefficients (P) of a number of organochlorine insecticides (OCs) are presented. The merits of log‐log regressions between experimental ? values and calculated estimates of P, solute activity coefficients in water, solute molecular surface area data, and reversed‐phase liquid‐chromatographic net retention data, are critically evaluated for several classes of pollutants: polycyclic aromatic hydrocarbons (PAHs), chlorinated benzenes, chlorinated biphenyls and OCs. Special attention is paid to the predictive accuracy of such semi‐empirical regressions in connection with possible effects of solute molecular shape and polarity.

Finally, bioconcentration and ‐accumulation of hydrophobic pollutants in fish are briefly discussed.  相似文献   
6.
Microbial inhibitors such as mercuric chloride are frequently used to sterilize soil or soil–water slurries in experimental studies on the fate of xenobiotics in the environment. This study examined the influence of mercuric chloride additions to soil–water slurries on the sorptive behaviour of a phenoxy herbicide (2,4-D) in soil. The results demonstrated that mercuric chloride strongly decreased the capacity of the soil to retain herbicides, and that the interference of mercuric chloride with herbicide sorption increased with increasing soil organic carbon contents. Because of the competitive sorption between mercuric chloride and the phenoxy herbicide, we conclude that mercuric chloride may not be a good soil sterilization procedure for use in xenobiotic fate studies.  相似文献   
7.
The effect of the spatial variability of Kd on calculations of contaminant travel time in the vadose zone was determined. Depth discrete measurements of Kd were made for a suite of radionuclides (109Cd, 57Co, 60Co, 85Sr, 137Cs, and 88Y) utilizing a sediment core from the E-Area at the Savannah River Site. The Kd’s were ordered as 85Sr2+ < 137Cs+ < 109Cd2+ < 57Co2+ = 60Co2+ << 88Y3+ and the values generally fell below or near the lowest quartile of values reported in the literature. Correlations were generally weak between soil properties and Kd values. Most importantly, all of the Kd distributions could be reasonably approximated as log-normal. Deterministic and stochastic calculations of contaminant travel time to the water table were made. The deterministic calculations were based on each of three conceptual models of the vadose zone: complete stratification (17 strata, each with a different Kd), two strata (two sections of the vadose zone, each characterized by a single, average Kd), and unstratified (a single zone with an average Kd). Stochastic calculations were based on log-normal fits to the Kd data. The two strata model generally yielded travel times 2× greater than those in the completely stratified model. The unstratified model yielded travel times that were between 3 and 5 times greater than the completely stratified model. The stochastic mean travel times were comparable to those of the two strata model.  相似文献   
8.
As zinc (Zn) is both an essential trace element and potential toxicant, the effects of Zn fixation in soil are of practical significance. Soil samples from four field sites amended with ZnSO4 were used to investigate ageing of soluble Zn under field conditions over a 2-year period. Lability of Zn measured using 65Zn radioisotope dilution showed a significant decrease over time and hence evidence of Zn fixation in three of the four soils. However, 0.01 M CaCl2 extractions and toxicity measurements using a genetically modified lux-marked bacterial biosensor did not indicate a decrease in soluble/bioavailable Zn over time. This was attributed to the strong regulatory effect of abiotic properties such as pH on these latter measurements. These results also showed that Zn ageing occurred immediately after Zn spiking, emphasising the need to incubate freshly spiked soils before ecotoxicity assessments.  相似文献   
9.
本文介绍了关于护听器实际防护值的研究数据,和用于护听器个人防护效果验证的方法,以及3ME-A-RfitTM听力防护验证系统。研究表明,护听器的标称降噪值对其实际防护值的指示性非常差,目前也还没有一个可靠的方法来使用护听器的标称值。3ME-A-RfitTM听力防护验证系统是使用实地真耳内置麦克风(F-MIRE)方法,在实际工作现场中快速、定量地测定护听器在具体使用者身上取得的个人声衰减值(PAR),让安全管理人员对员工实际获得的防护水平有清晰的了解。  相似文献   
10.
Sorption of 3,4-dichloroaniline (3,4-DCA) on four typical Greek agricultural soils, with distinct texture, organic matter content and cation exchange capacities, was compared by using sorption isotherms and the parameters calculated from the fitted Freundlich equations. The sorption process of 3,4-DCA to the soil was completed within 48–72 h. The 3,4-DCA sorption on all soils was well described by the Freundlich equation and all sorption isotherms were of the L-type. The sandy clay loam soil with the highest organic matter content and a slightly acidic pH was the most sorptive, whereas the two other soil types, a high organic matter and neutral pH clay and a low organic matter and acidic loam, had an intermediate sorption capacity. A typical calcareous soil with low organic matter had the lowest sorption capacity which was only slightly higher than that of river sand. The 3,4-DCA sorption correlated best to soil organic matter content and not to clay content or cation exchange capacity, indicating the primary role of organic matter. The distribution coefficient (K d) decreased with increasing initial 3,4-DCA concentration and the reduction was most pronounced with the highly sorptive sandy clay loam soil, suggesting that the available sorption sites of the soils are not unlimited. Liming of the two acidic soils (the sandy clay loam and the loam) raised their pH (from 6.2 and 5.3, respectively) to 7.8 and reduced their sorption capacity by about 50 %, indicating that soil pH may be the second in importance factor (after organic matter) determining 3,4-DCA sorption.  相似文献   
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