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蒽醌染料的电解处理研究 总被引:17,自引:0,他引:17
用复极性固定床电解槽(BPBC)对蒽醌染料进行电解处理研究.结果表明BPBC可以破坏染料分子结构中的发色共轭体系,色度和CODcr的去出率分别达到98%和85%以上,对总氮的去除率也达到60%以上 相似文献
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Zhenlian Qi Shijie You Ranbin Liu C. Joon Chuah 《Frontiers of Environmental Science & Engineering》2020,14(3):40
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NourElHouda Abdessamad Hanene Akrout Ghaith Hamdaoui Kais Elghniji Mohamed Ksibi Latifa Bousselmi 《Chemosphere》2013
The efficiency of the electrochemical degradation of synthetic wastewater containing an anthraquinone dye has been comparatively studied in two electrolytic cells with a synthetic boron-doped diamond (Si/BDD) as an anode. The first is an individual cell (Cell 1) with monopolar electrode BDD and the second (Cell 2) has two bipolar electrodes BDD self-polarized. The bulk electrolysis was performed at the same initial operating conditions in order to quantify the influence of the initial pH and current density on dye discoloration and global mineralization removal. The current efficiency and the consumption energy were also evaluated. When the same solutions have been comparatively treated with the two cells, a quite good mineralization is found in Cell 2. This result supposed more fraction of the applied current is used for the electrocombustion reaction on Cell 2 if compared to Cell 1 and small amount rest for the side reaction of oxygen evolution. The HPLC analyses confirmed this hypothesis and showed that the concentration trend of intermediates (sulfanilic acid, phthalate acid and salicylic acid) with electrolysis time was different on two cells. Phototoxicity tests show that the electrochemical oxidation with BDD electrodes could be useful as a pretreatment technique for reducing hazardous wastewater toxicity. 相似文献
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Huan He Qinjin Yu Chaochao Lai Chen Zhang Muhan Liu Bin Huang Hongping Pu Xuejun Pan 《Frontiers of Environmental Science & Engineering》2021,15(2):18
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The present study investigates the performance of the zero valent iron (ZVI, Fe0) packed bed bipolar electrolytic cell for nitrate removal. The packing mixture consists of ZVI as electronically conducting material and silica sand as non-conducting material between main cathode and anode electrodes. In the continuous column experiments for the simulated groundwater (initial nitrate and electrical conductivity of about 30 mg L−1 as N and 300 μS cm−1, respectively), above 99% of nitrate was removed at the applied potential of 600 V with the main anode placed on the bottom of reactor. The influx nitrate was converted to ammonia (20% to maximum 60%) and nitrite (always less than 0.5 mg L−1 as N in the effluent). The optimum packing ratio (v/v) of silica sand to ZVI was found to be 1:1-2:1. Magnetite was observed on the surface of the used ZVI as corrosion product. The reduction at the lower part of the reactor in acidic condition and adsorption at the upper part of the reactor in alkaline condition are the major mechanism of nitrate removal. 相似文献
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