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Catalytic activity of V, Mn, Ni, Cu, Zn, Mo, Zr and Ce oxides over an -alumina support was evaluated for cyclohexane oxidation under oxygen deficient conditions in order to understand the relation between carbon deposition and catalytic activity/selectivity. Carbon formation over the catalysts during the oxidation reaction was measured by means of Fourier transformed infrared spectroscopy (FTIR). Catalysts Mn/Al2O3 and Ce/Al2O3, which are selective for deep oxidation of cyclohexane, possessed relatively carbon free surfaces. The catalysts with relatively high carbon deposition (V, Ni, Cu, Zn, Mo and Zr) produced CO in addition to CO2. Traces of formaldehyde were produced over the catalysts Mo and V.  相似文献   
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The Flixborough explosion was the largest-ever peacetime explosion in the UK. There were 28 fatalities as well as near-complete destruction on the 24 ha plant. An official Court of Inquiry was immediately established and charged with the responsibility of determining the cause(s) of the disaster and the lessons to be learnt. Reviews are made here of the evidence and arguments behind an alleged 8 in initiation to the event and briefly that of the Court's determination of failure—the simultaneous failure of two 28 in bellows attached to a temporary 20 in dog-leg pipe bridge. Both cases are seen as flawed. The only credible hypothesis appears to be one that involved the failure, most probably by fatigue, of only one of the two bellows attached to the dog-leg—this then buckled, sealing the lower reactor. The dog-leg later collapsed by the blast. This process resulted in a much smaller explosive release than either alternate hypothesis and thus may have consequences for reportable inventories and process safety. The investigation employs NIST FDS CFD analyses of the potential releases, fires and their influence.  相似文献   
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纳米二氧化钛的改性及光催化氧化烷烃研究   总被引:5,自引:0,他引:5  
催化剂的表面结构是影响催化反应的重要因素之一.利用原位红外(In-situ FT-IR)、X射线衍射(XRD)和紫外-可见漫反射(UV-Vis DRS)等现代物理技术考察了热处理改性对纳米 TiO2的表面结构、晶相结构、粒子大小、比表面积和吸光性能的影响,采用In-situ FT-IR光谱着重研究了纳米TiO2催化剂上环己烷光催化降解机制及催化剂的结构特性与催化反应之间的相关性.研究表明,400 ℃条件下热处理纳米TiO2具有最佳光催化活性,适宜的表面结构、晶相结构、吸光能力及晶化度是纳米TiO2光催化剂高催化活性的主要原因.借助In-situ FT-IR光谱,观察到环己烷氧化的主要产物是CO2和H2O,同时捕捉到了中间产物CO以及乙酸,提出了环己烷光催化降解的可能机理.  相似文献   
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