Transparent exopolymer particles (TEPs)-associated protobiofilm: A neglected contributor to biofouling during membrane filtration

• Bacteria could easily and quickly attached onto TEP to form protobiofilms. • TEP-protobiofilm facilitate the transport of bacteria to membrane surface. • More significant flux decline was observed in the presence of TEP-protobiofilms. • Membrane fouling shows higher sensitivity to protobiofilm not to bacteria level. Transparent exopolymer particles (TEPs) are a class of transparent gel-like polysaccharides, which have been widely detected in almost every kind of feed water to membrane systems, including freshwater, seawater and wastewater. Although TEP have been thought to be related to the membrane fouling, little information is currently available for their influential mechanisms and the pertinence to biofouling development. The present study, thus, aims to explore the impact of TEPs on biofouling development during ultrafiltration. TEP samples were inoculated with bacteria for several hours before filtration and the formation of “protobiofilm” (pre-colonized TEP by bacteria) was examined and its influence on biofouling was determined. It was observed that the bacteria can easily and quickly attach onto TEPs and form protobiofilms. Ultrafiltration experiments further revealed that TEP-protobiofilms served as carriers which facilitated and accelerated transport of bacteria to membrane surface, leading to rapid development of biofouling on the ultrafiltration membrane surfaces. Moreover, compared to the feed water containing independent bacteria and TEPs, more flux decline was observed with TEP-protobiofilms. Consequently, it appeared from this study that TEP-protobiofilms play a vital role in the development of membrane biofouling, but unfortunately, this phenomenon has been often overlooked in the literature. Obviously, these findings in turn may also challenge the current understanding of organic fouling and biofouling as membrane fouling caused by TEP-protobiofilm is a combination of both. It is expected that this study might promote further research in general membrane fouling mechanisms and the development of an effective mitigation strategy.     

Remediation of arsenic contaminated soil by sulfidated zero-valent iron

• Sulfidation significantly enhanced As(V) immobilization in soil by zerovalent iron. • S-ZVI promoted the conversion of exchangeable As to less mobile Fe-Mn bound As. • Column test further confirmed the feasibility of sulfidated ZVI on As retention. • S-ZVI amendment and magnetic separation markedly reduced TCLP leachability of As. In this study, the influences of sulfidation on zero-valent iron (ZVI) performance toward As(V) immobilization in soil were systemically investigated. It was found that, compared to unamended ZVI, sulfidated ZVI (S-ZVI) is more favorable to immobilize As(V) in soil and promote the conversion of water soluble As to less mobile Fe-Mn bound As. Specifically, under the optimal S/Fe molar ratio of 0.05, almost all of the leached As could be sequestrated by>0.5 wt.% S-ZVI within 3 h. Although the presence of HA could decrease the desorption of As from soil, HA inhibited the reactivity of S-ZVI to a greater extent. Column experiments further proved the feasibility of applying S-ZVI on soil As(V) immobilization. More importantly, to achieve a good As retention performance, S-ZVI should be fully mixed with soil or located on the downstream side of As migration. The test simulating the flooding conditions in rice culture revealed there was also a good long-term stability of soil As(V) after S-ZVI remediation, where only 0.7% of As was desorbed after 30 days of incubation. Magnetic separation was employed to separate the immobilized As(V) from soil after S-ZVI amendment, where the separation efficiency was found to be dependent of the iron dosage, liquid to soil ratio, and reaction time. Toxicity characteristic leaching procedure (TCLP) tests revealed that the leachability of As from soil was significantly reduced after the S-ZVI amendment and magnetic separation treatment. All these findings provided some insights into the remediation of As(V)-polluted soil by ZVI.     

The performance of nitrate-reducing Fe(II) oxidation processes under variable initial Fe/N ratios: The fate of nitrogen and iron species

•Bacterially-mediated coupled N and Fe processes examined in incubation experiments. •NO₃⁻ reduction was considerably inhibited as initial Fe/N ratio increased. •The maximum production of N₂ occurred at an initial Fe/N molar ratio of 6. •Fe minerals produced at Fe/N ratios of 1–2 were mainly easily reducible oxides. The Fe/N ratio is an important control on nitrate-reducing Fe(II) oxidation processes that occur both in the aquatic environment and in wastewater treatment systems. The response of nitrate reduction, Fe oxidation, and mineral production to different initial Fe/N molar ratios in the presence of Paracoccus denitrificans was investigated in 132 h incubation experiments. A decrease in the nitrate reduction rate at 12 h occurred as the Fe/N ratio increased. Accumulated nitrite concentration at Fe/N ratios of 2–10 peaked at 12–84 h, and then decreased continuously to less than 0.1 mmol/L at the end of incubation. N₂O emission was promoted by high Fe/N ratios. Maximum production of N₂ occurred at a Fe/N ratio of 6, in parallel with the highest mole proportion of N₂ resulting from the reduction of nitrate (81.2%). XRD analysis and sequential extraction demonstrated that the main Fe minerals obtained from Fe(II) oxidation were easily reducible oxides such as ferrihydrite (at Fe/N ratios of 1–2), and easily reducible oxides and reducible oxides (at Fe/N ratios of 3–10). The results suggest that Fe/N ratio potentially plays a critical role in regulating N₂, N₂O emissions and Fe mineral formation in nitrate-reducing Fe(II) oxidation processes.     

南京市典型地区大气多环芳烃污染特征及健康风险评价

采用气相色谱-质谱法,于2016年9月和12月对南京市2个典型地区大气中16种多环芳烃(PAHs)的质量浓度进行分析,并开展了PAHs组成特征、来源解析及人体健康风险评价研究。结果表明,工业区(六合区)和生活区(江宁区)大气(气态和可吸入颗粒态)中16种PAHs的质量浓度分别为914.82和712.27 ng/m~3,苯并[a]芘毒性等效浓度分别为274.1和309.84 ng/m~3,且呈现冬季高、秋季低的特征。比值法源解析结果表明,燃煤污染是六合区PAHs污染主要来源,而江宁区主要表现为交通污染。人体健康风险评价结果表明,六合区和江宁区人群通过大气吸入PAHs的超额致癌风险分别为5.17×10~(-5)和5.85×10~(-5),均略高于可接受水平10~(-6)。     

海洋风电场水下噪声评估与管理研究

总结了海洋风电场建设中水下噪声的主要类型与声学特性,基于国内外水下噪声对海洋生物影响的最新研究成果,分析了海洋风电场噪声对生态环境的可能影响,尤其是近岸海域海洋风电施工期冲击式打桩噪声对海洋生物的影响。在此基础上,参考《海上风电工程环境影响评价技术规范》的相关内容,提出了海洋风电场水下噪声测量与评估方法,以及控制与降低噪声的措施建议。     

Spatial analysis of resources and environmental carrying capacity in Iran

Urbanization and mass movement of the population from rural areas and small cities to megacities have led to environmental, economic, and social problems in Iran. In dealing with these challenges, assessing resource and environmental carrying capacity (RECC) is considered an effective method to leverage space and capital to achieve sustainable development. This study aimed to rank the provincial RECC in Iran. Toward this purpose, environmental indices were generated from remotely sensed and statistical census data. Then, the provinces were scored in terms of environmental, economic, and infrastructural carrying capacities, and RECC using the mean variance analysis method. Results demonstrated that in most areas, there is no relationship between economic and infrastructural capacities and development. Statistically, a correlation coefficient of −0.53 between economic and environmental carrying capacities indicated excessive use of environmental capacities. Moreover, the spatial distribution pattern of environmental, economic, and infrastructural carrying capacity was entirely heterogeneous between the provinces; there was a northeast–southwest pattern in terms of infrastructural capacity and an economic pattern from north to south. The distribution pattern of RECC is most consistent with the environmental capacity, pointing at the high weight of the indicators of the RECC model. In conclusion, this research offers a new vision for policymakers and provides a theoretical and applicable framework for implementing sustainable strategies in land-use planning. It is recommended that the RECC concept and tools can be used not only for planning but also for measuring the efficiency of spatial development programs and establishing land balances in the region.     

Efficient removal of Cr(VI) by a 3D Z-scheme TiO2-ZnxCd1-xS graphene aerogel via synergy of adsorption and photocatalysis under visible light

Efficient and robust photocatalysts for environmental pollutants removal with outstanding stability have great significance. Herein, we report a kind of three dimensional (3D) photocatalyst presented as Z-scheme heterojunction, which combining TiO 2 and Zn x Cd 1- x S with graphene aerogel to contrast TiO 2 -Zn x Cd 1- x S graphene aerogel (TSGA, x = 0.5) through a moderate hydrothermal process. The as-prepared Z-scheme TSGA was used to remove aqueous Cr(VI) via a synergistic effect of adsorption and visible light photocatalysis. The adsorption equilibrium can be reached about 40 min, then after about 30 min irradiation under visible light (wavelength ( λ) > 420 nm) the removal rate of Cr(VI) almost reached 100%, which is much better than the performance of pristine TiO 2 and Zn 0.5 Cd 0.5 S, as well as TiO 2 graphene aerogel (TGA) and Zn 0.5 Cd 0.5 S graphene aerogel (SGA). The virulent Cr(VI) was reduced to Cr(III) with hypotoxicity after photocatalysis on TSGA, meanwhile the as-synthesized TSGA presented a good stability and reusability. The reduced graphene oxide (rGO) sheets between TiO 2 and Zn 0.5 Cd 0.5 S played a role as charge transfer mediator, promoting the photoinduced electrons transfer and photocatalysis ability of TSGA was enhanced significantly. Hence,such photocatalyst exhibits a potential application on removing heavy metals with high efficiency and stability from polluted aqueous environment.     

内陆核设施废液零排放方式探讨

液态放射性流出物是核设施运行的必然产物,滨海核设施向大海进行稀释排放处置,内陆核设施缺少稀释载体,采用自然蒸发空气载带方式将液体流出物通过气态途径向大气稀释排放是可行的替代方案,可以实现液态流出物的零排放。自然蒸发空气载带排放方案描述了工艺原理,提出了空气流速、空气温度、环境相对湿度、废水温度等与蒸发强度的关系,给出了一套自然蒸发载带排放装置的概念设计,分析了液态流出物转为气态途径排放对环境的影响,论证了采用自然蒸发空气载带方式实现内陆核设施液态流出物零排放目标的可行性。     

Characteristics of animal-related motor vehicle crashes in select National Park Service units—United States, 1990–2013

Objectives: Nationally, animal–motor vehicle crashes (AVCs) account for 4.4% of all types of motor vehicle crashes (MVCs). AVCs are a safety risk for drivers and animals and many National Park Service (NPS) units (e.g., national park, national monument, or national parkway) have known AVC risk factors, including rural locations and substantial animal densities. We sought to describe conditions and circumstances involving AVCs to guide traffic and wildlife management for prevention of AVCs in select NPS units.

Methods: We conducted an analysis using NPS law enforcement MVC data. An MVC is a collision involving an in-transit motor vehicle that occurred or began on a public roadway. An AVC is characterized as a collision between a motor vehicle and an animal. A non-AVC is a crash between a motor vehicle and any object other than an animal or noncollision event (e.g., rollover crash). The final data for analysis included 54,068 records from 51 NPS units during 1990–2013. Counts and proportions were calculated for categorical variables and medians and ranges were calculated for continuous variables. We used Pearson’s chi-square to compare circumstances of AVCs and non-AVCs. Data were compiled at the park regional level; NPS parks are assigned to 1 of 7 regions based on the park’s location.

Results: AVCs accounted for 10.4% (5,643 of 54,068) of all MVCs from 51 NPS units. The Northeast (2,021 of 5,643; 35.8%) and Intermountain (1,180 of 5,643; 20.9%) regions had the largest percentage of the total AVC burden. November was the peak month for AVCs across all regions (881 of 5,643; 15.6%); however, seasonality varied by park geographic regions. The highest counts of AVCs were reported during fall for the National Capital, Northeast/Southeast, and Northeast regions; winter for the Southeast region; and summer for Intermountain and Pacific West regions.

Conclusions: AVCs represent a public health and wildlife safety concern for NPS units. AVCs in select NPS units were approximately 2-fold higher than the national percentage for AVCs. The peak season for AVCs varied by NPS region. Knowledge of region-specific seasonality patterns for AVCs can help NPS staff develop mitigation strategies for use primarily during peak AVC months. Improving AVC data collection might provide NPS with a more complete understanding of risk factors and seasonal trends for specific NPS units. By collecting information concerning the animal species hit, park managers can better understand the impacts of AVC to wildlife population health.     

报废汽车拆解工艺的比对与研究

报废汽车具有良好的资源属性,处理企业选取合理的处理工艺对其进行处置,不仅能够提高经济效益,也可以有效保护生态环境。通过对当前报废汽车处理工艺技术进行分析比对,针对不同拆解企业提出相应的工艺选取建议,为产业发展提供帮助。