排序方式: 共有41条查询结果,搜索用时 265 毫秒
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采用共缩聚法,成功地原位合成了碘改性的阶层多孔氧化硅纳米球(SiO2-I),研究了其基于卤键作用对典型有机氯污染物六六六的吸附性能,并考察了改性剂I-硅烷含量和pH值对吸附效果的影响.实验结果表明,该纳米材料对六六六表现出优异的吸附富集性能,吸附速率快,60 min内对六六六的去除率为71.6%,240 min内达到吸附平衡,去除率可达98.3%,最大吸附量为178.6 mg·g-1;吸附动力学符合拟二级动力学模型;碘物种的加入提高了阶层多孔氧化硅的吸附速率和吸附效率.另外,为了便于纳米吸附材料的分离,本研究对SiO2-I纳米球进行了磁性化.研究发现,磁性化修饰后,SiO2-I纳米材料仍然保留对六六六优异的吸附富集性能,240 min时的吸附去除率达90.3%. 相似文献
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我国现阶段生产、生活中触电事故增加,采用故障树的分析方法,对用电设备触电事故进行危险因素分析,得出保护接地在供配电系统中的重要作用。简要介绍保护接地,并指出目前我国用电设备保护接地中存在的问题及接地故障的防范措施。 相似文献
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《Journal of Manufacturing Processes》2014,16(4):518-526
There has been a growing demand in the fabrication of dissimilar metal parts for application in the automotive, aerospace, defense, chemical and nuclear industries. Welding of dissimilar materials can be accomplished via impact welding, which can minimize the formation of a continuous inter-metallic phase, while chemically bonding dissimilar metals. This paper discusses an innovative technique for bonding dissimilar metals by chemically produced hydrogen energy by reacting aluminum powder and water. Experiments were carried out to study impact bond characteristics using copper and stainless steel cylindrical billets. The influence of nosed flyer billet angle and billet mass on bonding characteristics were studied. The test results have demonstrated that the nosed flyer billet angle has significant influence on wavy bond patterns at the interface. Among the three flyer billet nose angles of 9°, 12° and 15°, the billets with a flyer angle of 15° resulted in a complete wave morphological pattern along the whole sample cross-section. This study shows the potential of developing a cost effective system/machinery where discrete metal parts can be bonded at near net shape. 相似文献
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载钯螯合树脂的制备、表征及其降解多溴联苯醚的初步研究 总被引:1,自引:0,他引:1
以聚丙烯醛-异烟酰腙螯合树脂为高分子载体, 利用其活性基团对钯的选择性富集分离性能, 将金属元素钯键合到高分子载体上, 制备一种含钯树脂材料(树脂1), 并进一步原位还原得到还原态的载钯树脂(树脂2)。利用红外光谱、扫描电镜和X射线衍射等对以上2种含钯树脂材料进行了分析表征,并考察了它们对持久性有机污染物(POPs)多溴联苯醚(PBDEs)的脱溴降解性能。结果表明,2种树脂对BDE209均有降解活性, 其中树脂1的降解性能比树脂2的降解性能要高, 树脂中钯的氧化形态可能对BDE209的催化降解起主要作用。 相似文献
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Z.A. Khan B.M. Misra K. Raghu 《Journal of environmental science and health. Part. B》2013,48(5):1015-1027
Abstract Interaction of lindane with silty loam and silty clay loam soils was studied in batch tests at 23, 30 and 37° C. Sorption experiments were carried out at four concentrations and for varying time of contact upto 72 hours. This was followed by desorption studies. No desorption was observed. The sorption data was analysed using sorption equations and evaluating the thermodynamic parameters. The sorption was found to be predominantly entropic in nature and a combined effect of adsorption and chemisorption. The effect of organic matter and other chemical and mineralogical constituents of soils has also been discussed. The sorption with single application of lindane with the two soil types indicates that the insecticide is less likely to reach groundwater. 相似文献
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A supportive attitude of residents towards protected areas is crucial for successful implementation and management, particularly in densely populated regions such as Central Europe. While previous studies have revealed that emotional and cultural drivers, as well as information level and group membership, can influence attitudes towards protected areas, the effect of place-attachment dimensions remains unclear. A postal survey among local residents (N = 460) explored factors influencing attitudes towards the Lungau (-Nockberge) Biosphere Reserve in Austria before its official recognition. Results indicated societal support throughout all socio-demographic strata. A logistic regression showed that, besides socio-demographics and information level, place attachment had a significant influence on the acceptance of the biosphere reserve. Supporters and opponents showed both high place identity and dependence, while waverers scored low on these dimensions. Results indicate that place attachment is relevant for the design of participatory processes as well as for developing management policies for biosphere reserves. 相似文献
7.
利谷隆在土壤中的吸附过程与机理 总被引:10,自引:0,他引:10
利谷隆是一种广泛应用的除草剂。本文研究了它在4种不同理化特性土壤中的吸附过程(平衡吸附所需的时间,土壤pH的影响及吸附等温线)和在单离子饱和粘土矿物上的吸附机理,结果表明:利谷隆在土壤的吸附强度大(Kt值在3.88-93.84);达到吸附平衡的短(5h);pH值降低,有利于吸附,pH在4-6范围内变化较明显;另外,利谷隆在土壤中形成氢键、配位键及离子键是可能的。 相似文献
8.
对5座高山电视塔在自然环境下金属腐蚀与防护进行了调查和分析研究,寻求其规律性,以便在今后建设中有针对性地改进抗蚀措施,提高并延长其结构使用寿命,更好地为广播电视宣传服务。 相似文献
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A novel inorganic–organic composite membrane,namely poly(vinylidene fluoride) PVDF-glass fiber(PGF) composite membrane,was prepared and reinforced by interfacial ultraviolet(UV)-grafting copolymerization to improve the interfacial bonding strength between the membrane layer and the glass fiber.The interfacial polymerization between inorganic–organic interfaces is a chemical cross-linking reaction that depends on the functionalized glass fiber with silane coupling(KH570) as the initiator and the polymer solution with acrylamide monomer(AM) as the grafting block.The Fourier transform infrared spectrometer-attenuated total reflectance(FTIR-ATR) spectra and the energy dispersive X-ray(EDX) pictures of the interface between the glass fiber and polymer matrix confirmed that the AM was grafted to the surface of the glass fiber fabric and that the grafting polymer was successfully embedded in the membrane matrix.The formation mechanisms,permeation,and anti-fouling performance of the PGF composite membrane were measured with different amounts of AM in the doping solutions.The results showed that the grafting composite membrane improved the interfacial bonding strength and permeability,and the peeling strength was improved by 32.6% for PGF composite membranes with an AM concentration at 2 wt.%. 相似文献