碱激发胶凝材料及其固化Pb^2＋的试验研究

对碱激胶凝材料（碱-偏高岭土、碱-矿渣和碱-粉煤灰）与水-水泥体系固化Ph^2＋进行了试验研究,其中水-水泥体系为对比样。结果表明：对于相同稠度的碱激发胶凝材料,即使Pb^2＋含量达到2．4％,除了碱-粉煤灰的抗压强度略低外,其他都达到30MPa以上,满足填埋或做建筑基材的使用要求;与水泥相比,碱激发胶凝材料能显著降低重金属离子（Ph^2＋）浸出浓度,其规律性与其NH4交换容量大小的规律性一致,与其固化体的抗压强度的大小没有相关性。     

Element Removal in Harvested Tree Biomass: Scenarios for Critical Loads in Wallonia,South Belgium

The critical load concept is nowwidely used as a tool for developing emissioncontrol policies in Europe. As a signatorycountry of the Convention of Long-RangeTransboundary Air Pollution, critical loads foracidity, nutrient nitrogen, nitrogen and sulphurhave been calculated for the Flemish and Walloonregions in Belgium. This paper describes themethodology used for estimating critical loadsfor forest soils in the Walloon region accordingto the Steady-State Mass Balance equations. As anexample the methodology was applied to thecatchment `Waroneu', situated in a sensitive areaof the Haute Ardenne. Main input parameters tothe equations were derived from precipitation andrunoff data of the catchment study. Improvedestimates of nitrogen uptake (Nu) and base cationuptake (BCu) were obtained by intensive samplingof Picea abies and Quercus roburtrees. Nutrient contents (Ca, Mg, K, N) andnutrient to nitrogen ratios of Picea abiesreflected the poor soil quality at a site withhigh N deposition. Quercus robur nutrientcontents increased from stem to higher orderbranches with a high proportion of nutrientslocated in the bark. However the simulation ofstem only harvesting had a minor effect oncritical loads. Measured wood densities werelower than reported literature values with a maineffect on Nu and BCu estimates. The use ofrecommended default values and/or data derivedfrom the experimental site resulted in a widerange of critical loads, some of which werelargely overestimated. Results demonstrated theimportance of site specific data for criticalload calculations.     

Biodegradability of Quaternized, Crosslinked Sugarcane Bagasse

Quaternized, crosslinked sugarcane bagasse can adsorb anionic dyes from textile wastewater. Disposal of dye-saturated adsorbent by composting or land application would require that modifications made to the bagasse do not interfere with its decomposition. The impact of quaternization and crosslinking on bagasse biodegradability was examined. Bagasse in varying states of modification was mixed with soil and monitored for carbon dioxide evolution for four weeks at 27°C. After subtracting the amount of carbon evolved from control soil samples, the net carbon evolved from the bagasse samples was determined and used as a measure of their extent of biodegradation. Biodegradability decreased in the order: bagasse (approx. 60% degraded after four weeks) > quaternized bagasse > quaternized, epichlorohydrin-crosslinked bagasse > quaternized, methylene-bis-acrylamide-crosslinked bagasse > epichlorohydrin-crosslinked bagasse (less than 5% degraded). Crosslinking severely impacted biodegration, probably by preventing the penetration of (hemi)cellulytic and lignolytic enzymes into the interior of the modified bagasse particles. It is concluded that the biodegradability of quaternized, crosslinked bagasse is too low for composting or land application.     

树脂固载纳米铁对偶氮染料直接湖蓝5B的脱色性能研究

以FeSO4和NaBH4水溶液为前驱溶剂,以聚苯乙烯型阳离子交换树脂为载体,制备了树脂固载的纳米铁,室温下用于对偶氮染料直接湖蓝5B水溶液进行脱色研究。研究结果发现,脱色反应遵循准一级反应动力学,在初始pH为3~10的范围内,反应进行14 m in时,50 mg/L的染料溶液脱色率均能达到83%以上。固载的纳米铁材料可多次重复利用,溶液中释放的铁离子浓度不超过0.1 mg/L。     

C9-AA水溶性石油树脂的制备及其阻垢性能

以乙烯生产过程中的副产物C9馏分和丙烯酸为原料,采用自由基溶液聚合,合成具有阻垢性能的C9-AA水溶性石油树脂。考察了引发剂AIBN和溶剂的加入量、C9-AA加入量、Ca^2＋浓度、循环冷却水pH和养护时间对C9-AA水溶性石油树脂阻垢性能的影响,并对其阻垢效果进行了评价。在Ca^2＋质量浓度小于或等于600mg／L、循环冷却水pH小于或等于9．3、C9-AA水溶性石油树脂加入量大于或等于15mg／L的条件下,C9—AA水溶性石油树脂对循环冷却水的阻垢率达到90％以上,其有效作用时间为60h。     

膜电解技术处理含氯及重金属的废酸

采用离子交换膜电解技术处理铜冶炼过程产生的含氯及重金属的废酸。考察了废酸处理工艺、电解温度、电解时间、电流密度和催化剂的添加等条件对处理效果的影响。实验结果表明：采用先沉淀重金属后脱氯的废酸处理工艺,氯离子和铜离子的去除效果均较好;当以钛盐为催化剂时,在电解温度为40 ℃、电解时间为2.0 h、电流密度为825 A/m²的最佳工艺条件下,处理后废酸中的氯离子质量浓度为0.22 g/L,氯离子去除率为98.59%,铜离子质量浓度为0.45 g/L,铜离子去除率为95.08%,其他重金属大部分也得到有效去除。净化后的废酸可回用至铜冶炼的生产过程中。     

用离子交换法从β盐母液中分离1-萘磺酸钠的研究

比较了Ｄ２９０、Ｄ２９６、Ｄ３０１、Ｄ３７０、Ｄ３７２、Ｄ３８０ ６种树脂对β盐母液中１－萘磺酸的静态交换性能,筛选出Ｄ２９６用以回收β盐母液中的１－萘磺酸钠,进行了ＰＨ、接触时间、交换温度等影响因素的条件试验及树脂再生试验,得到１－萘磺酸钠收率８０％以上。     

苯基周位酸生产废水处理试验研究

采用CHA－111大孔吸附树脂对苯基周位酸生产过程排放的汽提苯胺盐析废水和苯基周位酸酸析母液进行处理试验,效果良好。汽提苯胺盐析废水苯胺质量浓度＞1600mg／L,经树脂吸附处理后苯胺质量浓度＜2mg／L,苯胺去除率＞99．9％,COD去除率＞97％,树脂工作吸附量达120g／L,脱附率＞98％;苯基周位酸酸析母液经树脂吸附、混凝沉淀处理后,苯基周位酸质量浓度＜190mg／L,苯基周位酸去除率为94．8％,COD去除率为94．3％,氨基值去除率为80％,脱附率＞99％。     

基于热湿交换理论的巷道风流温、湿度影响因素研究

为了研究巷道风流参数的影响因素、预测风流温湿度的变化规律,结合热湿交换理论,建立了风流与围岩壁面之间热湿交换的数学模型,以及贴体坐标系下围岩内部温度场的导热微分方程;利用数值方法,将围岩内部的导热问题与影响风流参数变化的热湿交换问题耦合起来,并以大柳塔煤矿52505综采工作面为例进行计算,得到了与实测参数较为一致的模拟结果,验证了该数值方法的有效性。研究结果表明:风流温度受原始岩温、入风流温度、局部热源强度等因素的影响,风流相对湿度与入风流温、湿度以及井下湿源的数量和强度有关;巷道壁温作为将围岩温度场与风流参数之间关联起来的主要因素,对模拟结果影响较大,其数值取决于壁面与风流之间热湿交换以及围岩原始岩温。