排序方式: 共有44条查询结果,搜索用时 78 毫秒
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多氯酚QSAR数值模型比较研究 总被引:6,自引:0,他引:6
应用多元线性回归分析和新近发展起来的人工神经网络方法进行了一类重要环境污染物多氯酚的定量构效关系研究,并用所建立的模型进行毒性预报,计算值与实验值的比较表明,前的相关系数约为0.92,后的相关系数约为0.99.后的百分误差地明显小于前,后的预报能力略好于前,中还讨论了后优于前的的原因。 相似文献
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氯酚与富里酸的缔合作用 总被引:1,自引:0,他引:1
本文用超滤膜方法证实氯酚与富里酸之间存在缔合作用,并计算出表观缔合常数在2.7*10^3--121*10^3ml.g^-1范围内。实验结果表明”PH、富里酸含量,氯酚取代氯原子个数都能够影响K值的大小。 相似文献
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Rong CHENG Jianlong WANG Weixian ZHANG 《Frontiers of Environmental Science & Engineering in China》2008,2(1):103-108
Chlorophenols (CPs), as important contaminants in groundwater, are toxic and difficult to biodegrade. Recently nanoscale zero-valent
iron received a great deal of attention because of its excellent performance in treating recalcitrant compounds. In this study,
nanoscale zero-valent iron particles were prepared using chemical reduction, and the reductive transformations of three kinds
of chlorinated phenols (2-CP, 3-CP, and 4-CP) by nanoscale zero-valent iron under different conditions were investigated.
The transformation process of the CPs was shown to be dechlorination first, then cleavage of the benzene ring. The removal
efficiency of the CPs varied as follows: 2-CP > 3-CP > 4-CP. The reactivity of CPs was associated with their energy of lowest
unoccupied molecular orbit (E
LUMO). With the increase in initial concentrations of CPs, removal efficiency decreased a little. But the quantities of CPs reduced
increased evidently. Temperature had influence on not only the removal efficiency, but also the transformation pathway. At
higher temperatures, dechlorination occurred prior to benzene ring cleavage. At lower temperatures, however, the oxidation
product was formed more easily.
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Translated from China Environmental Science, 2006, 26(6): 698–702 [译自: 中国环境科学] 相似文献
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以片状甲壳素(聚氨基葡萄糖)为研究对象,探讨了不同温度(5,15,25℃)下五氯酚(PCP)的吸附动力学;考察了温度(5,15和25℃)、盐度(w(NaCl)为0~7%)、pH值(pH5~8)、氯原子取代等对氯酚吸附的影响;比较了5℃时7种氯酚(PCP,三氯酚(2,4,6-TCP),4种二氯酚(2,5-DCP,3,4-DCP,2,3-DCP,2,6-DCP)和单氯酚(3-MCP))的吸附容量。结果表明,低温使五氯酚在片状甲壳素上的吸附速率显著降低,但同时增加甲壳素的吸附容量;5℃条件下,pH>6 5时,PCP吸附量降低一半后趋于稳定;w(NaCl)高于1%时,几乎完全抑制了PCP的吸附。7种氯酚在片状甲壳素上的吸附量大小顺序为PCP>TCP>DCP>MCP,其中4种DCP具有相似的吸附性能。 相似文献
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氯酚的生物降解特性及其微生物的16SrRNA基因序列分析 总被引:4,自引:0,他引:4
从受氯代有机物污染的土壤中富集分离到对2、4-二氯酚具有高效降解能力的微生物混合菌群。实验表明,降解1mol二氯酚可以定量释放出2mol的氯离子,在生物流化床反应器中,以聚胺酯泡沫块为固定化载体吸附固定化微生物,进行了连续降解氯酚的实验研究,当水力停留时间为24h,二氯酚的初始浓度为30μmol/L时,二氯酚的去除率均在90%以上,利用平板划线法从混合微生物菌群中分离到可以利用二氯酚为唯一碳源和能源的纯种微生物,16SrRNA基因序列分析结果表明,该微生物为Rhodococcus属。 相似文献
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