铜合金实验室试验与实海挂片结果的比较与分析

目的比较实验室试验结果与实海挂片结果对B10和H62两种铜合金腐蚀性能评价的异同之处。方法采用线性极化、电化学阻抗、显微形貌观察等,比较两种铜合金在实验室模拟海水中的的腐蚀速率、点蚀倾向,结合反应机理、腐蚀形貌、环境等外部因素,分析导致实验室与实海环境下出现差异的原因。结果除榆林海域外,实海挂片与实验室结果都表明,B10试样的平均腐蚀速率小于H62。B10和H62两种铜合金随温度升高腐蚀速率增大,在实验室和实海情况下表现出一致性,且平均腐蚀速率都随浸泡时间的延长而降低。结论在实海环境中,温度不是影响点蚀的主要因素,微生物等其他环境因素会对点蚀产生较大影响。     

云南白秧坪铜银矿床Cu、Ag迁移形式探讨

在野外地质研究的基础上,采用地球化学热力学方法研究了Cu、Ag的迁移形式。研究结果表明,铜在热液中主要以CuCl42-、Cu(H2O)42+、Cu(S2O3)46-、CuS46-、Cu(HS)42-、Cu(SbS3)410-形式迁移;银在热液中主要以AgCl2-、Ag(S2O3)23-、Ag(HS)2-、AgS23-、Ag(SbS3)25-形式迁移。铜银矿床是在含矿热液物理化学条件发生改变的情况下铜银化合物发生解析作用而成。     

深圳地铁罗湖车站深基坑位移监测结果分析

依据基坑监测的实际数据，通过分析桩锚支护结构的水平位移挠曲线，论述了锚索的锚固效果及相应的改进方法，总结桩背土体深层位移的特点和发展趋势，同时利用灰色模型对支护结构进行了位移预测、比较，说明了其准确性。     

用传递矩阵法计算消声器插入损失的理论探讨

采用声电类比的传递矩阵法，本文对消声器插入损失进行了理论探讨，所推导的理论公式准确地反映了整个内燃机排气系统对消声器插入损失的影响，克服了其它学者在研究此问题中的不足，考虑了声源声阻抗对传递损失的影响，对消声器的整体优化设计具有重要的指导意义。     

多热源分散程度的数学模拟及对置换通风影响

通过建立多污染热源置换通风的三维数学模型,根据数值解分析三热源位置变化对多污染源置换通风效果的影响,结果表明:热源的位置变化对多污染热源置换通风效果的影响是很大的,房间内热源应紧凑布置以利于提高通风效果和节能。     

Effect of Cross-Linking Waste Protein with Dialdehydes on Its Biodegradation Under Anaerobic Conditions

Most native polymers used in processing and application technologies are admittedly disposable from the environment in a biologic manner, but products possess low mechanical strength. One of the paths to increasing this attribute (if feasible) is their cross-linking, which may, however, affect their readiness to biodegradation. In the presented work this condition was observed on the example of waste protein (Hykol B) cross-linking by means of glutardialdehyde and glyoxal. Degree and course of cross-linking were determined through impedance spectroscopy. The objective of this work also was to obtain data for constructing a sensor capable of following the cross-linking course in real time, for potential industrial application of Hykol in continuous production. Impedance spectroscopy proved to be applicable even to this kind of material marked by considerable water content and exhibiting relatively high electric conductivity; so far it had been used only for materials of low conductivity. An aqueous environment inoculated with digested anaerobic sludge from a municipal wastewater treatment plant was selected for modeling anaerobic conditions. The relation was studied between cross-linking degree given by content of cross-linking agent (determined by impedance spectroscopy) and biodegradation degree under anaerobic conditions. It was confirmed that network density as given by quantity of added agent not only reduced breakdown degree but also slowed the course of the process. This fact is particularly obvious with cross-linking by means of glyoxal; network density is thus dependent on type of employed substance, which affect type and structure of created network. That not merely forms an obstacle during polymer swelling and dissolution but also prevents access of bacteria to source of metabolized organic carbon.     

旧路改造工程路堤稳定性安全监测方案设计

本文从旧路改造工程的特点出发,通过室内实验获取土力学参数并对沉降量进行预测计算.利用沉降仪、测斜管、孔隙水压力计、土压力盒等多种测试仪器,选取有代表性的观测断面,对经过土工格栅加筋处理的软土地基进行了高路堤施工期间的沉降与稳定观测,并提出适合工程特点的控制标准.从而达到控制路堤稳定、检验填筑质量、控制差异沉降、为路面施工提供技术支持的目的.     

Quantifying the squeezing or stretching of fisheries as they adapt to displacement by marine reserves

The designation of no‐take marine reserves involves social and economic concerns due to the resulting displacement of fishing effort, when fishing rights are removed from those who traditionally fished within an area. Displacement can influence the functioning of the fishery and success of the reserve, yet levels of displacement are seldom quantified after reserve implementation and very rarely before that. We devised a simple analytical framework based on set theory to facilitate reserve placement. Implementation of the framework requires maps of fishing grounds, fishing effort, or catch per unit effort for at least 2 years. The framework quantifies the level of conflict that a reserve designation might cause in the fishing sector due to displacement and the opportunities to offset the conflict through fisher spatial mobility (i.e., ability of fishers to fish elsewhere). We also considered how the outputs of the framework can be used to identify targeted management interventions for each fishery. We applied the method in Honduras, where the largest marine protected area in Central America is being placed, for which spatial data on fishing effort were available for 6 fisheries over 3 years. The proposed closure had a greater negative impact on the shrimp and lobster scuba fisheries, which concentrated respectively 28% and 18% of their effort inside the reserve. These fisheries could not accommodate the displacement within existing fishing grounds. Both would be forced to stretch into new fishing grounds, which are available but are of unknown quality. These stakeholders will likely require compensation to offset costly exploratory fishing or to travel to fishing grounds farther away from port.     

Investigation of titanium liquid/gas diffusion layers in proton exchange membrane electrolyzer cells

In a proton exchange membrane electrolyzer cell (PEMEC), liquid/gas diffusion layer (LGDL) is expected to transport electrons, heat, and reactants/products to and from the catalyst layer with minimum voltage, current, thermal, interfacial, and fluidic losses. In addition, carbon materials, which are typically used in PEM fuel cells (PEMFCs), are unsuitable in PEMECs due to the high ohmic potential and highly oxidative environment of the oxygen electrode. In this study, a set of titanium gas diffusion layers with different thicknesses and porosities are designed and examined coupled with the development of a robust titanium bipolar plate. It has been found that the performance of electrolyzer improves along with a decrease in thickness or porosity of the anode LGDL of titanium woven meshes. The ohmic resistance of anode LGDL and contact resistance between anode LGDL and the anode catalyst play dominant roles in electrolyzer performance, and better performance can be obtained by reducing ohmic resistance. Thin titanium LGDLs with straight-through pores and optimal pore morphologies are recommended for the future developments of low-cost LGDLs with minimum ohmic/transport losses.     

Attitudes towards relocation following Hurricane Sandy: should we stay or should we go?

This study explores the dilemma of whether to rebuild or relocate from the areas devastated by Hurricane Sandy in 2012. Since disasters represent the discernible manifestation of other complex coastal hazards, they offer a window of opportunity to engage residents in the dialogue on relocation as sometimes the most effective risk reduction strategy. The following research evaluates attitudes towards relocation and willingness to consider buyout among 46 surveyed households located in highly‐affected communities five months after Sandy. It also gauges perceptions of coastal risks and recovery concerns as drivers of relocation, the level of support for different adaptation strategies, and preferences related to the relocation process itself on how and where to relocate and with what type of assistance. Responses indicate that, even though residents prefer structural solutions to address coastal hazards, they are not fully opposed to the possibility of relocation mostly for personal health and safety reasons.