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1.
Water quality index (WQI) models are generally used in hydrochemical studies to simplify complex data into single values to reflect the overall quality. In this study, deep groundwater quality in the Chittur and Palakkad Taluks of the Bharathapuzha river basin of Kerala, India, was assessed by employing the WQI method developed by the Canadian Council of Ministers of the Environment (CCME). The assessment of overall water quality is indispensable due to the specific characteristics of the study area, such as geography, climate, over-drafting, and prevalent agricultural practices. Forty representative samples were collected from the study area for monsoon (MON) and pre-monsoon (PRM) seasons. The results showed a general increase of contents from MON to PRM. The major cations were spread in the order Ca2+>Na+>Mg2+>K+ and the anions HCO3>Cl>CO32− based on their relative abundance. Among various parameters analysed, alkalinity and bicarbonate levels during MON were comparatively high, which is indicative of carbonate weathering, and 90% of the samples failed to meet the World Health Organization (WHO, 2017)/Bureau of Indian Standards (BIS, 2012) drinking water guidelines. The CCME WQI analysis revealed that nearly 50% of the samples during each season represented good and excellent categories. The samples in the poor category comprised 10% in MON and 15% in PRM. The overall WQI exhibited 15% of poor category samples as well. The spatial depiction of CCME WQI classes helped to expose zones of degraded quality in the centre to eastward parts. The spatial and temporal variations of CCME WQI classes and different physicochemical attributes indicated the influence of common factors attributing to the deep groundwater quality. The study also revealed inland salinity at Kolluparamba and Peruvamba stations, where agricultural activities were rampant with poor surface water irrigation.  相似文献   
2.
The High Plains aquifer (HPA) is the primary water source for agricultural irrigation in the US Great Plains. The water levels in many locations of the aquifer have declined steadily over the past several decades because the rate of water withdrawals exceeds recharge, which has been a serious concern to the water resources management in the region. We evaluated temporal trends and variations in agricultural water use and hydroclimatic variables including precipitation, air temperature, reference evapotranspiration, runoff, groundwater level, and terrestrial water storage across the HPA region for different periods from 1985 to 2020 at the grid, county, or region scale. The results showed that water withdrawals decreased from 21.3 km3/year in 1985 to 18.2 km3/year in 2015, while irrigated croplands increased from 71,928 km2 in 1985 to 78,464 km2 in 2015 in the entire HPA. The hydroclimatic time-series showed wetting trends in most of the northern HPA, but drying and warming trends in the southern region from 1985 to 2020. The groundwater level time-series indicated flat trends in the north, but significant declining in the central and southern HPA. Trends in irrigation water withdrawals and irrigation area across the HPA were controlled by the advancement of irrigation systems and technologies and the management of sustainable water use, but also were affected by dynamical changes in the hydroclimatic conditions.  相似文献   
3.
刘钰  曾妍妍  周金龙  闫志雲  白凡 《环境科学》2023,44(12):6778-6789
开展地下水污染风险评价研究是地下水污染防控的重要环节.以巴里坤-伊吾盆地平原区地下水为研究对象,构建DRSTIW模型进行地下水脆弱性评价;根据污染场地调查资料和土地利用类型划分点源和面源污染,进行地下水污染荷载评价;考虑地下水的原生价值、经济价值和生态价值进行地下水功能价值评价;利用ArcGIS的地图代数功能生成地下水污染风险评价图,采用ROC曲线验证地下水污染风险评价结果,通过计算G指数得到地下水污染风险空间冷热点分布,结合重心和标准差椭圆对热点变动情况进行定量分析.结果表明,研究区地下水污染风险整体较低,高污染风险区和较高污染风险区仅占研究区总面积的6.8%,主要位于伊吾县的淖毛湖镇、盐池镇,巴里坤县的奎苏镇、石人子乡、花园乡和兵团红山农场,该区域内地下水埋深较浅,土壤表层和包气带介质透水性能较强,吸附能力较差,加之污染源分布较集中,使得污染物易于迁移富集,在地下水高脆弱性和高污染荷载的双重作用下导致局部区域地下水污染风险升高.受人类活动影响,地下水污染风险在空间上存在一定的集聚现象,整体表现为由西北向东南演变的趋势.地下水污染风险评价结果为划分地下水污染防治区提供重要参考.  相似文献   
4.
刘海  康博  管政亭  宋阳  柴义伦 《环境科学》2023,44(11):6038-6049
为厘清淮南矿区地表水和地下水水化学特征和控制因素,采集115组地下水和30组地表水样品,基于数理统计、 Piper三线图、 Gibbs图、矿物稳定场图和离子比例系数等方法,分析了淮南煤矿区地表水和地下水的水文地球化学特征,研究了其水化学特征演变规律.结果表明,淮南煤矿区地下水和地表水呈弱碱性,地表水和地下水中优势阴阳离子为HCO-3、 Ca+和Na+.HCO3-Ca型和HCO3-Ca·Na·Mg型为地表水和地下水的主要水化学类型.地下水和地表水的水化学特征主要受岩石风化作用控制,阳离子交替吸附和蒸发对其有一定的促进作用.水岩作用以硅酸盐和碳酸盐矿物的溶解为主,碳酸盐岩的溶解制约Ca2+、 Mg2+和HCO-3等离子的变化.地表水和地下水中Cl-、 SO42-、 NO-3  相似文献   
5.
明确硝酸盐的主要来源及转化过程对地下水氮污染防治和水资源开发利用具有重要意义.为了探明滇池周边浅层地下水中硝酸盐污染现状及来源,于2020年雨季(10月)和2021年旱季(4月)在滇池周边共采集73个浅层地下水样,运用水化学和氮氧同位素(δ15N-NO3-δ18O-NO3-)识别浅层地下水中硝酸盐的空间分布、来源及转化过程,并结合同位素混合模型(SIAR)定量评价不同来源氮对浅层地下水硝酸盐的贡献.结果表明,旱季浅层地下水中有40.5%的采样点ρ(NO3--N)超过地下水质量标准(GB/T 14848)Ⅲ类水质规定的20 mg·L-1,雨季超过47.2%的采样点ρ(NO3--N)超过20 mg·L-1.氮氧同位素和SIAR模型分析结果证明了土壤有机氮、化肥氮、粪肥和污水氮是浅层地下水硝酸盐的主要来源,以上氮源对旱季浅层地下水中硝酸盐的贡献率分别为13.9%、11.8%和66.5%,对雨季的贡献率分别为33.7%、31.1%和25.9%,而大气氮沉降贡献率仅为8.5%,对该区浅层地下水中硝酸盐来源贡献较小.硝化作用是旱季浅层地下水中硝态氮转化的主导过程,雨季以反硝化作用为主,且反硝化作用雨季比旱季明显.  相似文献   
6.
地下水砷污染是全球化环境问题.本文基于阿克苏地区平原区2017年75个地下水砷实测含量进行分析.结果表明,研究区地下水砷含量变化范围为ND—98.70μg·L-1,平均值为9.42μg·L-1,超标率达26.7%.水平方向上,高砷地下水主要集中在研究区的中部偏南一带;垂直方向上,山麓斜坡冲洪积砾质平原潜水区地下水砷含量平均值表现为深层潜水>浅层潜水,中下游河流冲积平原区承压水区地下水砷含量平均值表现为深层承压水>浅层承压水>潜水.采用绘制Piper三线图、Gibbs图、离子比例图等方法对研究区地下水砷的富集因素进行研究.结果表明,研究区地下水砷主要为自然来源;封闭的地质构造和造山带与河流等沉积环境相结合的水文地质条件有利于研究区地下水砷的富集;研究区高砷地下水水化学类型主要为HCO3·SO4-Na,还原性-弱碱性环境利于地下水砷富集;研究区地下水砷受强烈的蒸发浓缩作用进一步浓缩,同时地下水阴离子浓度增大加剧了地下水中阴离子与砷酸根、亚砷酸根之间的竞争吸附,利于地下水砷的富集.  相似文献   
7.
Subgrade biogeochemical reactors (SBGRs) are an in situ remediation technology shown to be effective in treating contaminant source areas and groundwater hot spots, while being sustainable and economical. This technology has been applied for over a decade to treat chlorinated volatile organic compound source areas where groundwater is shallow (e.g., less than approximately 30 feet below ground surface [ft bgs]). However, this article provides three case studies describing innovative SBGR configurations recently developed and tested that are outside of this norm, which enable use of this technology under more challenging site conditions or for treatment of alternative contaminant classes. The first SBGR case study addresses a site with groundwater deeper than 30 ft bgs and limited space for construction, where an SBGR column configuration reduced the maximum trichloroethene (TCE) groundwater concentration from 9,900 micrograms per liter (μg/L) to <1 μg/L (nondetect) within approximately 15 months. The second SBGR is a recirculating trench configuration that is supporting remediation of a 5.7‐acre TCE plume, which has significant surface footprint constraints due to the presence of endangered species habitat. The third SBGR was constructed with a new amendment mixture and reduced groundwater contaminant concentrations in a petroleum hydrocarbon source area by over 97% within approximately 1 year. Additionally, a summary is provided for new SBGR configurations that are planned for treatment of additional classes of contaminants (e.g., hexavalent chromium, 1,4‐dioxane, dissolved explosives constituents, etc.). A discussion is also provided describing research being conducted to further understand and optimize treatment mechanisms within SBGRs, including a recently developed sampling approach called the aquifer matrix probe.  相似文献   
8.
The present study investigated the fate and transport of two significant anions through soil to explore their potential as groundwater contaminants. The retention properties of chloride and sulfate in soils having several significantly different characteristics (soil‐1 and soil‐2) were determined using adsorption test and adsorption‐diffusion column experiments. The maximum adsorption capacity of chloride was 3.7 and 1.16 mg/g, respectively, in soil‐1 and soil‐2, with organic matter (OM) content of 3.92% and 4.69%, respectively. The sulfate adsorption obtained was 24.09% and 13.83%, respectively, in the two soils. The anions exhibited monolayer adsorption in the soils with replacement of hydroxyl ions from soils as the major mechanism of adsorption. On the other hand, the adsorption capacities obtained from the adsorption‐diffusion column experiment were about 100 times lower compared to that of the column tests of both of the soils. The maximum adsorption capacity of chloride was 0.03 mg/g and 0.01 mg/g, respectively, in soil‐1 and soil‐2, whereas that of sulfate was 0.04 mg/g and 0.03 mg/g. The empirical relation for depth of penetration (d) from a known spillage onto the soil surface was determined as a function of sorption capacity (S) and initial anion concentration (C) as = 0.0073e(?57S)C and = 0.0038e(?35S)C for chloride and sulfate, respectively.  相似文献   
9.
This study focuses on investigating the quality of groundwater for irrigation and drinking water purposes. Spatial distribution of physicochemical and microbiological parameters was assessed from samples collected from springs, hand‐dug wells, and boreholes found the Guna Tana landscape. A total of 70 samples were considered for physical, chemical, and bacteriological water quality determination. The results revealed that most of the groundwater quality index (WQI) values lie between good and excellent. The maximum, minimum, mean, and standard deviation of each water quality parameter were prepared for evaluating groundwater quality. According to the WQI values, more than 83% of the water samples were classified as excellent water for drinking. More than 92% of the water samples showed low sodium hazards for irrigation and about 48% and 46% of the water samples were classified as within the excellent and good water classes for irrigation based on their electrical conductance levels. Therefore, the groundwater that is found in the Guna Tana landscape could be used for drinking and irrigation purposes without any advanced treatment.  相似文献   
10.
Ephemeral and intermittent streams are abundant in the arid and semiarid landscapes of the Western and Southwestern United States (U.S.). Connectivity of ephemeral and intermittent streams to the relatively few perennial reaches through runoff is a major driver of the ecohydrology of the region. These streams supply water, sediment, nutrients, and biota to downstream reaches and rivers. In addition, they provide runoff to recharge alluvial and regional groundwater aquifers that support baseflow in perennial mainstem stream reaches over extended periods when little or no precipitation occurs. Episodic runoff, as well as groundwater inflow to surface water in streams support limited naturally occurring riparian communities. This paper provides an overview and comprehensive examination of factors affecting the hydrologic, chemical, and ecological connectivity of ephemeral and intermittent streams on perennial or intermittent rivers in the arid and semiarid Southwestern U.S. Connectivity as influenced and moderated through the physical landscape, climate, and human impacts to downstream waters or rivers is presented first at the broader Southwestern scale, and secondly drawing on a specific and more detailed example of the San Pedro Basin due to its history of extensive observations and research in the basin. A wide array of evidence clearly illustrates hydrologic, chemical, and ecological connectivity of ephemeral and intermittent streams throughout stream networks.  相似文献   
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