高氯酸铁可见分光光度法测定水中叠氮化物研究

基于Fe~(3+)显色技术,建立了测定地表水、地下水、生活污水和工业废水中叠氮化物的高氯酸铁分光光度法。研究结果表明:N_3~-与Fe~(3+)反应生成的棕红色络合物的特征吸收峰为454 nm;氨基磺酸铵可有效掩蔽NO_2~-的干扰,蒸馏能消除色度、CN~-、SCN~-硫化物等对测定的影响;当取样体积为150 mL、蒸馏定容体积为100 mL、使用10 mm比色皿时,方法检出限为0.08 mg/L(以N_3~-计),测定下限为0.32 mg/L;平均回收率为88.0%~104%,相对标准偏差(n=6)为0.3%～5.6%。对实际工业废水样品进行了测定,结果为1.37 mg/L。该方法准确度高、精密度好、操作简单,能够满足水污染物排放标准中叠氮化物的测定要求。     

Animal agency in wildlife conservation and management

Wildlife conservation and management (WCM) practices have been historically drawn from a wide variety of academic fields, yet practitioners have been slow to engage with emerging conversations about animals as complex beings, whose individuality and sociality influence their relationships with humans. We propose an explicit acknowledgement of wild, nonhuman animals as active participants in WCM. We examined 190 studies of WCM interventions and outcomes to highlight 3 common assumptions that underpin many present approaches to WCM: animal behaviors are rigid and homogeneous; wildlife exhibit idealized wild behavior and prefer pristine habitats; and human–wildlife relationships are of marginal or secondary importance relative to nonhuman interactions. We found that these management interventions insufficiently considered animal learning, decision-making, individuality, sociality, and relationships with humans and led to unanticipated detrimental outcomes. To address these shortcomings, we synthesized theoretical advances in animal behavioral sciences, animal geographies, and animal legal theory that may help conservation professionals reconceptualize animals and their relationships with humans. Based on advances in these fields, we constructed the concept of animal agency, which we define as the ability of animals to actively influence conservation and management outcomes through their adaptive, context-specific, and complex behaviors that are predicated on their sentience, individuality, lived experiences, cognition, sociality, and cultures in ways that shape and reshape shared human–wildlife cultures, spaces, and histories. Conservation practices, such as compassionate conservation, convivial conservation, and ecological justice, incorporate facets of animal agency. Animal agency can be incorporated in conservation problem-solving by assessing the ways in which agency contributes to species’ survival and by encouraging more adaptive and collaborative decision-making among human and nonhuman stakeholders.     

Investigation of long-term river water quality variations using different urbanization indices and assessment of common scientific perspectives of urbanization on water quality

This study investigated the water quality variation spanning 30 years (1986–2017) in 16 catchments of Hong Kong against different urbanization indices, namely, built area fraction; population; and product of population and built area fraction. Pearson correlations of three different periods of time (1988–1990, 1998–2000, and 2015–2017) indicated that water quality trends were dependent on the urbanization index. Total solids, nitrite-nitrogen, total phosphorus, electrical conductivity, dissolved oxygen, and flow rate had significant deteriorative trends (Pearson r > 0.5 and p < 0.05) with population and product of built area and population. Results also interpreted that built area fraction and product of built area and population were the worst and best indices that represented urbanization and/or its impacts, respectively. Mann-Kendall test for the entire 30 year period showed that water quality had improved with time with respect to certain water quality parameters (e.g., dissolved oxygen, ammoniacal nitrogen and total suspended solids). The results portrayed that although the urbanization of catchments had increased with time, the river water quality with respect to many parameters showed signs of improvement and the legislative measures implemented seemed to be effective in controlling pollution.     

Temporal trends in agricultural water use and the relationships to hydroclimatic factors in the High Plains aquifer region

The High Plains aquifer (HPA) is the primary water source for agricultural irrigation in the US Great Plains. The water levels in many locations of the aquifer have declined steadily over the past several decades because the rate of water withdrawals exceeds recharge, which has been a serious concern to the water resources management in the region. We evaluated temporal trends and variations in agricultural water use and hydroclimatic variables including precipitation, air temperature, reference evapotranspiration, runoff, groundwater level, and terrestrial water storage across the HPA region for different periods from 1985 to 2020 at the grid, county, or region scale. The results showed that water withdrawals decreased from 21.3 km³/year in 1985 to 18.2 km³/year in 2015, while irrigated croplands increased from 71,928 km² in 1985 to 78,464 km² in 2015 in the entire HPA. The hydroclimatic time-series showed wetting trends in most of the northern HPA, but drying and warming trends in the southern region from 1985 to 2020. The groundwater level time-series indicated flat trends in the north, but significant declining in the central and southern HPA. Trends in irrigation water withdrawals and irrigation area across the HPA were controlled by the advancement of irrigation systems and technologies and the management of sustainable water use, but also were affected by dynamical changes in the hydroclimatic conditions.     

地表水环境遥感监测关键技术与系统

介绍了地表水环境遥感监测的关键技术与系统及其典型应用,其代表性机理模型和应用示范成果主要来自于中国科学院遥感与数字地球研究所的高光谱遥感团队在最近几年中取得的一些研究进展,主要包括建立了基于改进双峰法的水体分布自动化遥感提取方法,实现了简单、高效和高精度的水体提取；提出了大型湖泊长时序水量估算方法,并以青藏高原湖区为例,重建了典型湖泊面积、水位和水量序列；发展了基于“软分类”的典型内陆水体叶绿素a浓度反演方法,构建了基于生物光学模型的高度浑浊水体悬浮物浓度遥感反演半解析方法,提高了反演方法的区域和季节适用性；构建了基于水色指数的大范围湖库营养状态和透明度遥感监测方法,实现了全球大型湖库营养状态遥感监测,以及全国大型湖库透明度遥感监测；在此基础上,开发了地表水环境遥感监测系统,提高了水环境遥感监测效率,促进了卫星遥感在水环境监测中的高精度业务化应用。     

Effects of T-2 toxin on histopathology,fatty acid and water distribution of shrimp (Litopenaeus vannamei) muscle

T-2 toxin (T-2), one of the naturally occurring mycotoxins, often accumulates in aquatic animals from contaminated feed. Shrimp (n?=?30 per group) were fed with different concentrations (0, 0.5, 1.5, 4.5 and 13.5?mg kg^?1) of T-2 for 20?days. Changes in histopathology, fatty acid and water distribution of shrimp muscle were analyzed. Histopathology of shrimp muscle showed dose-dependent marked degenerative and necrotic changes on exposure to dietary T-2. The T-2 significantly (P?<?0.05) affected the muscle fatty acid composition. ∑SFA, ∑MUFA and ∑PUFA initially decreased and then increased slowly in the high-dosed groups. C16:0, C18:1n-9 and C18:2n-6 were the main saturated fatty acid (SFA), monounsaturated fatty acid (MUFA) and polyunsaturated fatty acid (PUFA), respectively. Also, T-2 significantly affected water distribution in shrimp muscle. High doses of T-2 reduced free water content, resulting in a reduction in the water holding capacity and hence changes to the shrimp muscle quality. Collectively, these results illustrated that T-2 significantly affects the fatty acid and water distribution, and also muscle histopathology, all of which would result in a reduction in the quality and nutritional value of shrimp.     

汶川县生态保护红线人类活动本底调查评估

生态保护红线是国家和区域生态安全的底线,以阿坝州汶川县划定的生态保护红线区为研究区域,利用GIS软件对研究区域内人类活动遥感影像进行遥感解译,并对研究区生态保护红线内的人类活动进行本底实地调查,结合遥感解译和实地调查结果,对红线内人类活动强度进行了评价。结果表明:红线内人类活动面积共计142.04hm²,人类活动斑块数量共计281个;红线内的人类活动影响指数为0.019,人类活动影响强度弱;红线内人类活动影响类型主要为旅游活动和耕地、道路及居民点等。     

The deflectors influence on flow complexity,bed morphology,sediment transport and water quality of urban lotic waters - A laboratory study

In this laboratory study different combinations of bed (sand, pebble gravel [gravel], and a mix of sand and gravel) and flow (typical and overtopping) were experimented with to investigate the impact of porous deflectors in flow diversity, water quality, and fish performance in prismatic open channels. Deflectors changed the gradually varied flow to a rapidly varied flow, as a sudden change in the water depth was observed at the deflectors, and this change was large for smooth beds. With the presence of gravel, the scouring near the downstream deflector was almost twice that of the sand bed, and with the scouring at its own upstream deflector, irrespective of whether the flow was typical or overtopping. This behavior was a result of sand mobilization due to shear stress and sand mobilization aided gravel transport. The mixed bed showed less gravel movement compared to the gravel-only bed. The percentage of sediment washed out was minor for all bed scenarios, indicating that sediment transport was local. Relative to the sand bed without deflectors (representing a typical urban canal), deflectors resulted in reduced and improved water quality (in terms of sediment load) for sand, and mixed bed, respectively. The fishes found refuge and were comfortable in the pool areas created by deflectors unlike in channels without deflectors where they showed exhaustion.