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排序方式: 共有451条查询结果,搜索用时 15 毫秒
1.
Puteri Nur Syazwani Mohd Kopli Mimi H. Hassim Umi Aisah Asli Firdaus Abdul Wahab 《环境质量管理》2023,33(1):95-106
Biohythane production via single-stage anaerobic digestion (AD) is an effective way for sustainable energy recovery from lignocellulosic biomass. In this paper, biohythane was produced through the AD process from pineapple peel waste substrate using purely cultured Methanosarcina mazei with the enhancement of palm oil mill effluent (POME) sludge as the inoculum. This study focuses on the effects of the lignocellulosic pre-treatment method, the addition of POME sludge into M. mazei culture medium as inoculum, and various operational conditions (food to microorganisms (F/M) ratios, temperature, pH) on gas production performances. The experimental results indicate that these parameters influenced the efficiency of biohythane production by producing the peak maximum biohythane production rate values (HPRmax) and (MPRmax), H2:CH4 = 1.93:0.67 L/L-d, and biohythane yield (HY) and (MY), H2:CH4 = 1.18:0.55 mL/L-substrate. This study demonstrates that biohythane gas (H2 + CH4 + CO2) production from pineapple waste can be accelerated by M. mazei only with the enhancement of POME sludge through single-stage AD system under mesophilic batch process conditions. 相似文献
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表面活性剂改性4A分子筛对Cr(VI)的吸附行为 总被引:1,自引:0,他引:1
采用浸渍法对4A分子筛进行表面改性,通过引入阳离子表面活性剂,使4A分子筛表面附着季铵型阳离子,并与反离子Br-形成"阴离子交换膜",从而促使更多的Cr(VI)阴离子通过离子交换吸附到改性4A分子筛上,通过X-射线衍射(XRD)和傅里叶变换红外光谱(FTIR)对样品的物相结构和组成进行表征分析。研究表明,表面活性剂的类型和疏水碳氢链结构会影响4A分子筛的吸附能力,十八烷基三甲基溴化铵(OTAB)碳氢链长,在分子筛表面形成的双分子层密,对Cr(VI)的吸附量最大。采用准一级、准二级、Elovich和Bangham动力学模型对六价铬的吸附数据进行拟合,其中准一级动力学方程最符合十八烷基三甲基溴化铵改性分子筛的吸附行为。同时,分别从Langmuir和Redlich-Peterson等温吸附模型获得六价铬的最大吸附量为13.98 mg/g,且改性分子筛以均一表面吸附为主。 相似文献
5.
好氧颗粒污泥对酸性红B的生物吸附模型研究 总被引:1,自引:0,他引:1
考察了灭活好氧颗粒污泥吸附酸性红B的吸附等温线、吸附动力学和热力学.结果表明,Langmuir和Redlich-Peterson比Freudlich吸附等温线更符合试验数据,20 ℃时Langmuir最大单分子层吸附量为123.46 mg/g.吸附动力学符合准2级动力学模型.灭活AGS内部扩散过程用Webber-Morris模型拟合,结果表明颗粒内部扩散过程是限速步骤,但边界层扩散和动力学阻力亦不能忽略.热力学分析表明,吸附过程是吸热且自发的过程. 相似文献
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Oxidation of aniline by persulfate in aqueous solutions was investigated and the reaction kinetic rates under different temperature, persulfate concentration and pH conditions were examined in batch experiments. The results showed that, the aniline degradation followed pseudo first-order reaction model. Aniline degradation rate increased with increasing temperature or persulfate concentration. In the pH range of 3 to 11, a low aniline degradation rate was obtained at strong acid system (pH 3), while a high degradation rate was achieved at strong alkalinity (pH 11). Maximum aniline degradation occurred at pH 7 when the solution was in a weak level of acid and alkalinity (pH 5, 7 and 9). Produced intermediates during the oxidation process were identified using liquid chromatography-mass spectrometry technology. And nitrobenzene, 4-4’-diaminodiphenyl and 1-hydroxy-1,2-diphenylhydrazine have been identified as the major intermediates of aniline oxidation by persulfate and the degradation mechanism of aniline was also tentatively proposed. 相似文献
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Amina Chnirhe Mourad Harir Basem Kanawati Mohammed El Azzouzi Istvan Gebefgi Philippe Schmitt-Kopplin 《环境科学学报(英文版)》2012,24(9):1686-1693
The photodegradation of mefenpyrdiethyl (MFD), an herbicide safener, was investigated in aqueous suspensions by using Degussa P-25 and Hombikat UV100 titanium oxide under simulated sunlight irradiation. The effects of initial concentration of the herbicide, pH, catalysts and hydrogen peroxide doses as well as their combinations were studied and optimized. Accordingly, the kinetic parameters were determined and the effectiveness of the processes was assessed by calculating the rate constants. A pseudo first-order kinetics was observed. Under experimental conditions, the degradation rate constants were strongly influenced using P-25 and no noticeable effect was observed for Hombikat UV100. DFT calculations with B3LYP/6-311+G(2d,p)//B3LYP/6-31+G(d,p) level of theory were performed to check whether significant conformational changes occur when the charge state of the MFD substrate changes and whether these changes could play a role in the dependency of photodegradation rate constant on the studied pH. High resolution mass spectrometry (FT-ICR/MS) was implemented to identify the main degradation products. 相似文献
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Removal of arsenic from wastewater using iron compound: Comparing two different types of adsorbents in the context of LCA 总被引:1,自引:0,他引:1
Gjergj Dodbiba Teiji Nukaya Yousuke Kamioka Yuji Tanimura Toyohisa Fujita 《Resources, Conservation and Recycling》2009,53(12):688-697
A study was carried out in order to compare the environmental performance of two different types of adsorbents in removing arsenic (As) from wastewater. A FeCl3-based adsorbent and a poly-Fe-based adsorbent were first synthesized and their abilities in adsorbing As from wastewater were investigated in terms of the adsorption density and the rate of adsorption. Here, it should be noted that the main material being used in the synthesis of the poly-Fe-based adsorbent was a waste product, known as polyferric sulfate or poly-Fe in short, which exits the manufacturing process of titanium dioxide.Both adsorbents were then compared in the context of life-cycle assessment (LCA). In other words, the experimental results (i.e. the value of the adsorption density and the rate of adsorption) were input into the LCA model in order to assess the environmental performance of each adsorbent in removing arsenic. An estimate for the environmental burden of each option was finally calculated as the sum of the depletion of abiotic resources (ADP), the global warming potential (GWP), the acidification potential (AP), the photo-oxidant formation potential (POCP), the eutrophication potential (EP), and the human toxicity potential (HTP). The main finding of this study was that the adsorption of arsenic by using the poly-Fe-based adsorbent is more attractive treatment option in the environmental protection point of view than the adsorption by using the FeCl3-based adsorbent, which generates a relatively larger environmental burden. 相似文献
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基于典型的希瓦氏金属还原菌(Shewanella decolorationis S12)和针铁矿相互作用的现象,探讨了电子供体、针铁矿浓度及氧化还原中介体2-磺酸钠蒽醌(AQS)对其相互作用的影响.结果表明, AQS加入使针铁矿的微生物还原程度得到加强,在添加AQS的0.5mmol/L针铁矿体系中,厌氧培养38天后,被还原解离出的Fe(ΙΙ)浓度是未添加AQS的394%.针铁矿的归一化还原速率表明,当电子供体浓度一定时,随着针铁矿浓度增加,针铁矿的还原酶促反应显著减弱.米氏拟合方程表明,以不同浓度的针铁矿为底物时, S12菌-针铁矿相互作用过程的拟合相关系数R2分别为0.843(添加AQS)和0.998(未添加AQS),电子转移载体的存在以及底物类型的不同均对Vmax和Km值均有一定程度的影响.在微生物在还原针铁矿过程中,其还原速率越大,用于ATP合成所需能量 值也随之升高,S12菌和针铁矿的还原反应达到平衡时, Gibbs自由能变化(DGr)达最大值. 相似文献
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