g-C_3N_4/C@Bi_2MoO_6复合光催化剂的制备及其光催化活性

通过水热合成法和液相沉积法制备g-C_3N_4/C@Bi_2MoO_6复合光催化剂,并采用X射线衍射、扫描电子显微镜、氮气吸脱附、紫外-可见漫反射等技术对其进行表征。研究了可见光下g-C_3N_4/C@Bi_2MoO_6催化降解罗丹明B(Rh B)的影响因素,并对其光催化反应机理进行初步探讨。实验结果表明:g-C_3N_4掺杂量为60%(w)时g-C_3N_4/C@Bi_2MoO_6的光催化活性最高;在60%g-C_3N_4/C@Bi_2MoO_6的投加量为1.00 g/L、初始Rh B质量浓度为2.50 mg/L、可见光照射150 min的条件下,Rh B的降解率达到97.90%;在g-C_3N_4/C@Bi_2MoO_6光催化降解体系中,h~+和·O_2~-是主要活性物种。     

预氧化聚丙烯腈/g-C3N4光催化降解罗丹明B

以聚丙烯腈(PAN)和g-C_3N_4为原料,采用超声波辅助分散的溶液浸渍法及煅烧法制备了具有共轭结构的预氧化聚丙烯腈/g-C_3N_4复合光催化剂(CPAN/g-C_3N_4),采用XRD、SEM、FTIR、UV-Vis DRS、EIS等技术对光催化剂进行了表征,考察了CPAN/g-C_3N_4对罗丹明B(Rh B)的可见光催化降解性能。结果表明:CPAN与g-C_3N_4具有良好的协同作用,使g-C_3N_4片状结构堆叠体颗粒显著减小,明显增强了光催化剂在全部光谱范围内的光吸收,有效提高了光生电子-空穴分离效率;在PAN与g-C_3N_4质量比为1∶200、煅烧温度250 ℃、煅烧时间1 h条件下所制备的CPAN/g-C_3N_4光催化活性最高,且具有良好的光催化活性稳定性。超氧自由基和光生空穴为CPAN/g-C_3N_4复合光催化剂光降解罗丹明B的主要活性物种。     

焦化行业苯并芘排放量与厂界达标预测分析

论文以某100万吨/年焦化项目为例,分析其在不同地形和风速参数条件下苯并芘排放量,预测不同条件下距离焦炉炉体中心-1000～1000米范围内各网格点的苯并芘超标概率,最终得出风速、地形参数对苯并芘浓度超标概率的影响.     

IKK inhibition prevents PM2.5-exacerbated cardiac injury in mice with type 2 diabetes

Epidemiological studies have found that individuals with diabetes mellitus(DM) display an increased susceptibility for adverse cardiovascular outcomes when exposed to air pollution.This study was conducted to explore the potential mechanism linking ambient fine particles(PM2.5) and heart injury in a Type 2 DM(T2DM) animal model. The KKay mouse, an animal model of T2DM, was exposed to concentrated ambient PM2.5 or filtered air for 8 weeks via a versatile aerosol exposure and concentrator system. Simultaneously, an inhibitor of IκB kinase-2(IKK-a)(IMD-0354), which is a blocker of nuclear factor κB(NF-κB)nuclear translocation, was administrated by intracerebroventricular injection(ICV) to regulate the NF-êB pathway. The results showed that ambient PM2.5 induced the increase of, NF-êB, cyclooxygenase-2(COX-2) and mitogen activated protein kinase(MAPK) expression in cardiac tissue, and that IMD-0354 could alleviate the inflammatory injury. The results suggested that the NF-êB pathway plays an important role in mediating the PM2.5-induced cardiovascular injury in the T2DM model. Inhibiting NFκB may be a therapeutic option in air-pollution-exacerbated cardiovascular injury in diabetes mellitus.     

四氨基酞菁钯/γ-Al_2O_3可见光催化降解罗丹明B

采用浸渍法制备了四氨基酞菁钯(PdTAPc)/γ-Al_2O_3负载型光催化剂,采用UV-Vis,FTIR,XRD,SEM技术对其进行了表征,并将其用于罗丹明B的可见光催化降解,考察了光催化剂加入量、溶液pH、H_2O_2加入量、反应温度对罗丹明B降解效果的影响,并对光催化剂的稳定性进行了测试。表征结果显示,PdTAPc以圆片状负载于γ-Al_2O_3上,二者的结构均未发生明显变化。实验结果表明:在光催化剂加入量1.6 g/L、溶液pH 7.0、H_2O_2加入量12 mmol/L、反应温度20℃的优化条件下反应120 min,罗丹明B(质量浓度0.05 g/L)的降解率高达95%;光催化剂具有较高的稳定性,使用4次后罗丹明B的降解率仍高于85%。     

粉煤灰基层状金属氧化物对水中活性红X-3B的吸附

以粉煤灰(FA)为原料,采用共沉淀法制备了层状双金属氢氧化物(LDH)和层状金属氧化物(LMO,也称LDO),并采用XRD和BET技术进行了表征。比较了FA、LDH、LMO对活性红X-3B染料(X-3B)的吸附效果;考察了LMO吸附X-3B的影响因素,并探讨了吸附机理。XRD表征结果表明,LMO在吸附X-3B后重新恢复LDH层状结构。BET表征结果表明,LMO的比表面积大于LDH。吸附实验结果表明,3种吸附剂对X-3B吸附效果的优劣顺序为:LMOLDHFA;在初始X-3B质量浓度为50 mg/L、LMO投加量为2.0 g/L、吸附温度为25℃、吸附pH为7、吸附时间为30 min的条件下,X-3B去除率可达98.1%;LMO对X-3B的吸附符合Langmuir等温吸附方程,饱和吸附量为129.53 mg/g,且吸附过程可用准二级动力学方程描述。     

纳米TiO2-石墨烯光催化剂的水热合成及其光催化性能

以钛酸四正丁酯和石墨为原料，通过水热法制备了锐钛矿型为主的纳米TiO2复合光催化剂（纳米TiO2-石墨烯），并采用XRD，FTIR，FESEM，TEM技术对其进行了表征。通过紫外光照射降解溶液中的罗丹明B（RhB）研究了TiO2-石墨烯的光催化活性，分析了初始罗丹明B质量浓度、催化剂加入量、溶液pH和催化剂使用次数等影响降解效果的因素。实验结果表明：在初始RhB质量浓度为20 mg/L、溶液pH为7.10、催化剂加入量为1.000 g/L的条件下，紫外光照射30 min时，纳米TiO2-石墨烯对RhB的降解率高达98.69%，明显高于纳米TiO2的44.69%;纳米TiO2-石墨烯稳定性较强，可多次重复使用。     

高压脉冲放电等离子体处理活性红X-3B染料废水

采用高压脉冲放电等离子体技术对活性红X-3B染料废水进行处理,考察了废水电导率、脉冲电压、脉冲频率、针板间距以及曝气量对处理效果的影响。实验结果表明,当废水电导率为200μS/cm、脉冲电压为34kV、脉冲频率为60Hz、针板间距为15mm、曝气量为12L/h、处理时间为60m in时,活性红X-3B染料废水脱色率能达到98.6%。     

Pd-MnO2 nanoparticles/TiO2 nanotube arrays (NTAs) photo-electrodes photo-catalytic properties and their ability of degrading Rhodamine B under visible light

Pd-MnO_2/TiO_2 nanotube arrays(NTAs) photo-electrodes were successfully fabricated via anodization and electro deposition subsequently; the obtained Pd-MnO_2/TiO_2 NTAs photo electrodes were analyzed by scanning electron microscopy(SEM), X-ray diffraction(XRD) and characterized accordingly. Moreover, the light harvesting and absorption properties were investigated via ultraviolet–visible diffuse reflectance spectrum(DRS); photo degradation efficiency was investigated via analyzing the photo catalytic degradation of Rhodamine B under visible illumination(xenon light). The performed analyses illustrated that Pd-MnO_2 codoped particles were successfully deposited onto the surface of the TiO_2 nanotube arrays;DRS results showed significant improvement in visible light absorption which was between400 and 700 nm. Finally, the photo catalytic degradation efficiency results of the designated organic pollutant(Rhodamine B) illustrated a superior photocatalytic(PC) efficiency of approximately 95% compared to the bare TiO_2 NTAs, which only exhibited a photo catalytic degradation efficiency of approximately 61%, thus it indicated the significant enhancement of the light absorption properties of fabricated photo electrodes and their yield of UOH radicals.     

湿地基质及阴极面积对人工湿地型微生物燃料电池去除偶氮染料同步产电的影响

本研究采用人工湿地型微生物燃料电池处理偶氮染料X-3B,实现降解偶氮染料同步产电的效果.为了构建性能最优的人工湿地型微生物燃料电池(CW-MFC)系统,本研究主要从湿地基质和阴极面积两个方面研究系统构型对去除X-3B同步产电的影响,提高系统性能.研究表明以粒径10 mm、孔隙率30%的小石子作为湿地基质构造的CW-MFC系统微生物生物量最大,去除X-3B效果最好,脱色率高达92.70%,但其产电性能最差.较小的粒径和孔隙率使底层微生物生物量增加,促进X-3B的去除,但随着湿地基质粒径和孔隙率的减小,导致阴阳极营养物质不足,系统传质阻力增加,抑制了系统产电性能.X-3B的去除效果随着阴极面积的增加而提高直到阴极面积为594 cm~2时取得最大脱色率99.41%.当阴极面积继续增加时,CW-MFC系统产电性能上升趋势趋于平缓,X-3B去除效果呈现下降趋势,这是因为阴极反应过快导致更多的阳极电子输送到阴极用于产生电流,与X-3B发生反应的电子减少,阳极成为提高CW-MFC系统性能的限制因素.