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1.
Yang Li Yixin Zhang Guangshen Xia Juhong Zhan Gang Yu Yujue Wang 《Frontiers of Environmental Science & Engineering》2021,15(1):1
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The present study investigated the fate and transport of two significant anions through soil to explore their potential as groundwater contaminants. The retention properties of chloride and sulfate in soils having several significantly different characteristics (soil‐1 and soil‐2) were determined using adsorption test and adsorption‐diffusion column experiments. The maximum adsorption capacity of chloride was 3.7 and 1.16 mg/g, respectively, in soil‐1 and soil‐2, with organic matter (OM) content of 3.92% and 4.69%, respectively. The sulfate adsorption obtained was 24.09% and 13.83%, respectively, in the two soils. The anions exhibited monolayer adsorption in the soils with replacement of hydroxyl ions from soils as the major mechanism of adsorption. On the other hand, the adsorption capacities obtained from the adsorption‐diffusion column experiment were about 100 times lower compared to that of the column tests of both of the soils. The maximum adsorption capacity of chloride was 0.03 mg/g and 0.01 mg/g, respectively, in soil‐1 and soil‐2, whereas that of sulfate was 0.04 mg/g and 0.03 mg/g. The empirical relation for depth of penetration (d) from a known spillage onto the soil surface was determined as a function of sorption capacity (S) and initial anion concentration (C) as d = 0.0073e(?57S)C and d = 0.0038e(?35S)C for chloride and sulfate, respectively. 相似文献
3.
José Ignacio Nazif-Muñoz 《Traffic injury prevention》2015,16(7):S32-S40
Objective: The objective of the current study is to determine what factors have been associated with the global adoption of mandatory child restraint laws (ChRLs) since 1975.Methods: In order to determine what factors explained the global adoption of mandatory ChRLs, Weibull models were analyzed. To carry out this analysis, 170 countries were considered and the time risk corresponded to 5,146 observations for the period 1957–2013. The dependent variable was first time to adopt a ChRL. Independent variables representing global factors were the World Health Organization (WHO) and World Bank's (WB) road safety global campaign; the Geneva Convention on Road Traffic; and the United Nation's (UN) 1958 Vehicle Agreement. Independent variables representing regional factors were the creation of the European Transport Safety Council and being a Commonwealth country. Independent variables representing national factors were population; gross domestic product (GDP) per capita; political violence; existence of road safety nongovernmental organizations (NGOs); and existence of road safety agencies. Urbanization served as a control variable. To examine regional dynamics, Weibull models for Africa, Asia, Europe, North America, Latin America, the Caribbean, and the Commonwealth were also carried out.Results: Empirical estimates from full Weibull models suggest that 2 global factors and 2 national factors are significantly associated with the adoption of this measure. The global factors explaining adoption are the WHO and WB's road safety global campaign implemented after 2004 (P <.01), and the UN's 1958 Vehicle Agreement (P <.001). National factors were GDP (P <.01) and existence of road safety agencies (P <.05). The time parameter ρ for the full Weibull model was 1.425 (P <.001), suggesting that the likelihood of ChRL adoption increased over the observed period of time, confirming that the diffusion of this policy was global. Regional analysis showed that the UN's Convention on Road Traffic was significant in Asia, the creation of the European Transport Safety Council was significant in Europe and North America, and the global campaign was in Africa. In Commonwealth and European and North American countries, the existence of road safety agencies was also positively associated with ChRL adoption.Conclusions: Results of the world models suggest that the WHO and WB's global road safety campaign was effective in disseminating ChRLs after 2004. Furthermore, regions such as Asia and Europe and North America were early adopters since specific regional and national characteristics anticipated the introduction of this policy before 2004. In this particular case, the creation of the European Transport Safety Council was fundamental in promoting ChRLs. Thus, in order to introduce conditions to more rapidly diffuse road safety measures across lagging regions, the maintenance of global efforts and the creation of road safety regional organizations should be encouraged. Lastly, the case of ChRL convergence illustrates how mechanisms of global and regional diffusion need to be analytically differentiated in order better to assess the process of policy diffusion. 相似文献
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填埋场内渗滤液饱和带是物质交换和生化反应的活跃区域,也是含硫恶臭的主要发生源.本研究探究了填埋场内温度场下渗滤液饱和带内硫酸盐还原行为特征,结果表明,在25~55℃逐步升温的温度场下,渗滤液饱和带内的硫酸盐还原行为逐步增强且差异显著.渗滤液饱和带纵向SO42-和DOC迁移转化规律各异但趋势相同.硫酸盐还原行为主要发生在固液交界区和固相区,且固液交界区的电子供、受体呈特定化学计量关系.电子供体是引起硫酸盐还原行为差异的主要原因.本研究揭示的温度场下渗滤液饱和带内硫酸盐还原行为可为填埋场精准除臭提供重要依据. 相似文献
6.
庄贵阳 《中国人口.资源与环境》2020,(3):19-28
政策试点是中国国家治理策略体系的重要组成部分,是中国政府遵循“由点到面”逻辑以试验手段制定政策的一种常规性工作方法。低碳城市试点是中国应对气候变化战略的重要组成部分,通过选择不同类型、不同发展阶段、不同资源禀赋的地区开展试点,探索经济增长与碳排放脱钩的模式。现有文献侧重低碳城市建设的内涵、建设模式与路径、温室气体的核算方法、政策手段、峰值研究与达峰路径、效果评估等,有力地支持了低碳城市建设决策,但对于低碳城市试点的政策设计鲜有涉及。本文从政策过程理论、央地关系两个视角,结合府际学习与竞争关系,建构了中国低碳城市政策“试点–扩散”机制与政府行为的分析框架。中国的低碳城市试点具有探索型开拓性、综合型专业性、授权型自主性的特点,结合三批低碳城市试点的文件要求和实践进展,从政策试点的选点、设计、执行、监督和评估五个方面对于中国低碳城市试点进行了系统的梳理分析。相较于经济领域的其他政策试点,低碳城市政策试点具有弱激励弱约束的政策环境。地方政府基于自身的学习能力和领导力,在政策创新方面表现出争先、自主、效仿和守成四种行为特征,并以杭州、深圳、镇江、成都四个表率城市做了实证。政策“试点-扩散”的过程从本质上讲是中国政策创新与扩散的过程,可能在现实中需要往复多次进行,中国已陆续开展的三批低碳城市试点工作就遵循这样的政策逻辑。试点的意义是试出问题、解决问题、积累经验。从前三批试点城市评估结果来看,试点城市在低碳发展目标设定、转型路径探索和低碳发展动力转换等方面与社会的预期仍有差距,为此本文提出了推进低碳城市建设的四点建议:一是激发城市低碳发展的内生动力;二是完善低碳城市试点的科学论证机制;三是建立激励与约束并举的长效机制;四是强化市场公平竞争的政策导向。 相似文献
7.
为探究铁磁流体对煤体瓦斯解吸性能的影响,采用水浴恒温吸附解吸系统,开展0.44,0.65,1.14 MPa 3组不同平衡压力下加铁磁流体前后的瓦斯解吸对比实验,根据Langmuir方程经验公式计算瓦斯极限解吸量和初始扩散系数,分析铁磁流体对煤体瓦斯解吸影响的机理。结果表明:在3组不同平衡压力下加入铁磁流体后瓦斯极限解吸量由2.5,10,20 mL/g降低为2.22,3.33,10 mL/g,降低11.2%,66.7%,50%;初始扩散系数由0.997 1,1.629 9,3.888 3 μm2·s降低为0.685 5,0.997 1,2.933 5 μm2·s,降低31.25%,38.82%,24.56%。在铁磁流体的作用下,煤体瓦斯解吸性能得到大幅降低。 相似文献
8.
Chloride ingress and freeze-thaw cycles are the most important mechanisms for deterioration of concrete in cold areas. In this study, chloride ingress into concrete that has been exposed to freeze-thaw cycles was investigated. Data demonstrated that freeze-thaw cycles allow for a larger effective diffusion coefficient. Based on our findings, the concept of a developing coefficient was defined to obtain the evolution equation of the effective diffusion coefficient. Together with considering the effect of aging of concrete on the effective diffusion coefficient, the time-dependent diffusion coefficient was also obtained. Based on Fick's second law and time-dependent diffusion coefficient, chloride ingress model of concrete in cold regions was derived. Finally, the model was tested by comparing predicted results, lab results, and in situ inspection data. 相似文献
9.
以2种典型的污染排放源(点污染源和线污染源)为基础,提出排污窗口的概念,通过参数转换分解源强对污染扩散进行研究。首先在高斯污染扩散模型的基础上,对非持续性污染源强建模,然后以某烟囱的周期性排污分析,检验排污窗口设置的合理性。对于单双号限行的窗口性质的污染排放研究中,首先对交通流建立线污染扩散模型,然后融合元胞自动机(9元胞互影响)模拟区域多角度污染的扩散平衡,最后对"单双号限行"下北京市不同区域空气质量指标进行分析与仿真。分析结果表明,合理的排污窗口能够减轻污染程度及对人们日常生活的影响。 相似文献
10.