有机化学品不同温度下(过冷)液体蒸气压预测模型的建立与评价

(过冷)液体蒸气压(PL)是评价化学品在环境中分配、迁移和归趋行为的重要参数。PL具有较强的温度依附性。发展一种能够精确预测不同环境温度下化学品PL的方法,有助于填补化学品生态风险评估的大量数据缺失。本研究收集整理了661种有机化合物在不同温度下(200~830 K)共计10 478个log PL值。在此基础上,采用偏最小二乘(PLS)回归和支持向量机(SVM)方法,构建了PL的线性和非线性预测模型。结果表明:2种模型均具有良好的拟合度、稳健性及预测能力,SVM模型的预测性能略高于PLS模型(PLS:R2adj.tra=0.912,RMSEtra=0.477,Q2ext=0.910;SVM:R2adj.tra=0.997,RMSEtra=0.092,Q2ext=0.967)。机理分析表明,温度是影响PL的主要因素,温度越高,蒸气压越大;其次,X1sol也影响PL大小,X1sol用来描述分子间的色散作用,分子间色散力越小,蒸气压越大;此外,化合物的氢键个数、极性和分子构型等因素也影响PL大小。采用Wiliams plot方法表征了PLS模型应用域。所建立的模型可用来预测烷烃、烯烃、醇、酮、羧酸、苯、酚、联苯、卤代芳香烃、含N化合物及含S化合物在不同温度下的PL数据。     

基于FTA-SVM的车辆发动机故障识别方法

发动机结构日益复杂,其故障具有多样性和频发性的特点,收集大量故障样本存在很多实施障碍。为了提高车辆发动机的故障识别的效率和准确性,提出了一种新的结合故障树(FTA)和支持向量机(SVM)各自特点,从故障模式分析到故障类型识别的FTA-SVM故障识别方法。首先利用故障树在复杂系统故障模式分析中的优势,找出系统的故障模式,建立故障树模型,通过对故障树模型中各故障事件的分析,采集与故障事件状态相关的数据,建立数据与故障树底事件的映射模型,最后利用支持向量机在小样本数据处理中的优势,进行故障类型的识别。以发动机的失火故障为例建立了发动机失火故障树模型及故障数据与故障模式映射模型,验证了FTA-SVM方法的有效性和适用性。     

岩溶塌陷倾向性等级的KPCA-SVM预测模型

为了快速、有效地预测岩溶塌陷倾向性等级,在统计分析大量观测实例的基础上,选取岩性系数、岩体结构系数、地下水系数、覆盖层系数、地形地貌系数和环境条件系数作为特征指标。利用核主成分分析(KPCA)方法在高维空间提取岩溶塌陷影响因子的主成分,将获取的主成分作为支持向量机(SVM)的特征向量,建立基于KPCA的岩溶塌陷倾向性等级的SVM预测模型。将12组观测数据作为学习样本对模型进行训练。采用回代估计法进行回检,误判率为0。利用训练好的模型对2组待判样本进行预测。结果表明:经KPCA后指标个数减少,相关性降低,SVM运算的复杂度降低。用该模型所得预测结果的准确率为100%。     

基于MDE和分形优化SVM的周期来压预测

为了解决周期来压的预测问题,首先对已知支架周期来压荷载曲线使用多重差异进化算法(MDE)进行拟合,将每重拟合形成的单一正弦曲线与上次差余曲线(Ei)再作差余曲线(Ei+1)。将这些Ei图通过分形几何的盒子法计算维度和相关系数(r)。将每条Ei的维度、r和支架相对距离(L)作为输入值,对应的Ei的周期Ti、缩放系数Si和纵移系数Di作为目标值,使用支持向量机(SVM)进行训练。通过对维度和r规律的研究得到拟设置支架处荷载各Ei的维度和r,带入训练后的SVM模拟得到Ei的Ti、Si和Di,进而得到Ei的表达式。将上述Ei求和即为所求拟设置支架处的周期来压荷载。实例分析说明,该种方法预测结果可以大体反映支架周期来压的基本形式和变化规律。     

Modelling and Prediction of Diesel Engine Performance using Relevance Vector Machine

Diesel engines are being increasingly adopted by many car manufacturers today, yet no exact mathematical diesel engine model exists due to its highly nonlinear nature. In the current literature, black-box identification has been widely used for diesel engine modelling and many artificial neural network (ANN) based models have been developed. However, ANN has many drawbacks such as multiple local minima, user burden on selection of optimal network structure, large training data size, and over-fitting risk. To overcome these drawbacks, this article proposes to apply an emerging machine learning technique, relevance vector machine (RVM), to model and predict the diesel engine performance. The property of global optimal solution of RVM allows the model to be trained using only a few experimental data sets. In this study, the inputs of the model are engine speed, load, and cooling water temperature, while the output parameters are the brake-specific fuel consumption and the amount of exhaust emissions like nitrogen oxides and carbon dioxide. Experimental results show that the model accuracy is satisfactory even the training data is scarce. Moreover, the model accuracy is compared with that using typical ANN. Evaluation results also show that RVM is superior to typical ANN approach.     

Prediction of effluent concentration in a wastewater treatment plant using machine learning models

Of growing amount of food waste, the integrated food waste and waste water treatment was regarded as one of the efficient modeling method. However, the load of food waste to the conventional waste treatment process might lead to the high concentration of total nitrogen(T-N) impact on the effluent water quality. The objective of this study is to establish two machine learning models—artificial neural networks(ANNs) and support vector machines(SVMs), in order to predict 1-day interval T-N concentration of effluent from a wastewater treatment plant in Ulsan, Korea. Daily water quality data and meteorological data were used and the performance of both models was evaluated in terms of the coefficient of determination(R~2), Nash–Sutcliff efficiency(NSE), relative efficiency criteria(d rel). Additionally, Latin-Hypercube one-factor-at-a-time(LH-OAT) and a pattern search algorithm were applied to sensitivity analysis and model parameter optimization, respectively. Results showed that both models could be effectively applied to the 1-day interval prediction of T-N concentration of effluent. SVM model showed a higher prediction accuracy in the training stage and similar result in the validation stage.However, the sensitivity analysis demonstrated that the ANN model was a superior model for 1-day interval T-N concentration prediction in terms of the cause-and-effect relationship between T-N concentration and modeling input values to integrated food waste and waste water treatment. This study suggested the efficient and robust nonlinear time-series modeling method for an early prediction of the water quality of integrated food waste and waste water treatment process.     

基于SVM的矿井通风阻力系数影响因素分析与预测

矿井通风阻力系数是通风安全最重要的基础参数之一，为了实现矿井通风阻力系数简单准确地预测，提出了利用支持向量机（SVM）来预测矿井通风阻力系数的方法。通过分析影响因子与矿井通风阻力系数的相关性关系，并利用MATLAB逐步建立单影响因素与矿井通风阻力系数、多影响因素与矿井通风阻力系数之间的SVM预测模型，对比分析各预测模型的相对误差，确定最佳矿井通风阻力系数预测模型，即当输入模型影响因素为巷道断面积、周长和支护方式时，预测相对误差小于10%的样本数占测试样本的76%，相对误差小于20%的样本数占测试样本的90%。结果表明:该预测方法在矿井通风阻力系数预测中是可行的，并具较高的准确性。     

基于文本挖掘的煤矿安全隐患管理研究

为探寻安全隐患的内在特征，加深安全管理人员对安全隐患的理解，提升安全管理效率。以潞安集团司马煤业有限公司2009—2015年安全隐患记录为数据源，利用Word2Vec模型构建安全隐患词向量模型，从模型中获取各类安全隐患主要相关词，利用桑基图解释安全隐患在不同隐患地点、生产作业单位的特征分布，并进一步揭示相关安全隐患的细节特征。结果表明:词向量模型能有效发掘安全隐患特征，桑基图能突出呈现安全隐患的关键信息流动。上述措施有助于管理人员深刻理解安全隐患数据中蕴含的潜在规律，为煤矿安全隐患排查治理工作提供依据，指导安全管理实践。     

土地城镇化与人口城镇化的非协调性和互动关系

土地城镇化与人口城镇化失调是我国目前城镇化进程中的一个突出问题。但对各地区土地城镇化与人口城镇化的非协调性进行全面系统分析的研究相对较少。此外,鲜有研究对土地城镇化与人口城镇化之间的互动关系进行实证检验。本研究利用我国2005—2013年间的省级面板数据考察各省级行政区土地城镇化与人口城镇化的非协调性,并通过构建和估计面板向量自回归模型探究土地城镇化与人口城镇化之间的互动关系。研究发现,土地城镇化与人口城镇化的非协调性存在着显著的时空差异。在样本期的后半段(2009—2013年),多个省级行政区人口城镇化滞后于土地城镇化的程度有所加深。根据全样本期内土地城镇化与人口城镇化非协调性的严重程度,可将各省级行政区划分为5个等级。城镇常住人口变化对建成区面积变化具有显著的正向影响;建成区面积变化对城镇常住人口变化的影响方向虽然为正,但该影响不具有统计显著性。从而表明人口城镇化对土地城镇化起到了推动作用,但土地城镇化却未能有效地带动和促进人口城镇化。此外,第二、三产业增加值变化对城镇常住人口变化具有显著的正向影响。研究从改革新增建设用地指标分配方式、抑制城市空间粗放扩张及推动户籍制度改革和基本公共服务均等化等方面提出了促进土地城镇化和人口城镇化协调发展的政策建议。     

Optimizing mixture properties of biodiesel production using genetic algorithm-based evolutionary support vector machine

Nowadays, biodiesel is used as one of the alternative renewable energy due to the increasing energy demand. However, optimum production of biodiesel still requires a huge number of expensive and time-consuming laboratory tests. To address the problem, this research develops a novel Genetic Algorithm-based Evolutionary Support Vector Machine (GA-ESIM). The GA-ESIM is an Artificial Intelligence (AI)-based tool that combines K-means Chaotic Genetic Algorithm (KCGA) and Evolutionary Support Vector Machine Inference Model (ESIM). The ESIM is utilized as a supervised learning technique to establish a highly accurate prediction model between the input--output of biodiesel mixture properties; and the KCGA is used to perform the simulation to obtain the optimum mixture properties based on the prediction model. A real biodiesel experimental data is provided to validate the GA-ESIM performance. Our simulation results demonstrate that the GA-ESIM establishes a prediction model with better accuracy than other AI-based tool and thus obtains the mixture properties with the biodiesel yield of 99.9%, higher than the best experimental data record, 97.4%.