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1.
《Chemistry and Ecology》2007,23(5):409-425
The use of a new sorbent developed from the husk of pomegranate, a famous fruit in Egypt, for the removal of toxic chromium from aqueous solution has been investigated. The batch experiment was conducted to determine the adsorption capacity of the pomegranate husk. The effects of initial metal concentration (25 and 50 mg l-1), pH, contact time, and sorbent concentration (2-6 g l-1) have been studied at room temperature. A strong dependence of the adsorption capacity on pH was observed, the capacity increased as the pH decreased, and the optimum pH value was pH 1.0. Adsorption equilibrium and kinetics were studied with different sorbent and metal concentrations. The adsorption process was fast, and equilibrium was reached within 3 h. The maximum removal was 100% for 25 mg l-1 of Cr6+ concentration on 5 g l-1 pomegranate husk concentration, and the maximum adsorption capacity was 10.59 mg g-1. The kinetic data were analysed using various kinetic models—pseudo-first-order, pseudo-second-order, Elovich, and intraparticle diffusion equations—and the equilibrium data were tested using several isotherm models, Langmuir, Freundlich, Tempkin, Dubinin-Radushkevich, and Generalized isotherm equations. The Elovich and pseudo-second-order equations provided the greatest accuracy for the kinetic data, while Langmuir and Generalized isotherm models were the closest fit for the equilibrium data. The activation energy of sorption has also been evaluated as 0.236 and 0.707 kJ mol-1 for 25 and 50 mg l-1 chromium concentration, respectively. 相似文献
2.
Caroline Michel Marie-Thérèse Giudici-Orticoni Frauke Baymann Mireille Bruschi 《Water, Air, & Soil Pollution: Focus》2003,3(3):161-169
The treatment of soils and ground waters polluted by heavy metals is of economical and environmental interest. Reduction of Cr(VI) to the less toxic Cr(III) associated to its precipitation is a potentially useful process for bioremediation. In order to develop ecological processes using micro-organisms, we have compared various sulfate-reducing bacteria for enzymatic reduction of chromate. The best Cr(VI) reductase activity was obtained with Desulfomicrobium norvegicum. Despite morphological changes induced by the presence of chromate, this strain can grow in the presence of up to 500 M Cr(VI) and can decontaminate waters polluted by Cr(VI) when seeded in bioreactors. We have demonstrated the ability of several metalloenzymes (cytochromes c
3 and hydrogenases) to reduce chromate. Biophysical investigations of the chromate/protein interaction in order to get further informations on the mechanism of metal reduction by cytochromes c
3 are under the way. 相似文献
3.
化学还原法在受铬污染土壤地下水系统修复过程中应用广泛。化学还原固定化方法通过将溶解度大、迁移性强的六价铬(Cr(VI))还原转化为稳定的三价铬(Cr(III))氢氧化物,从而实现铬污染控制与修复的目的。常用的还原剂包括:含铁类还原剂(零价铁、纳米零价铁和亚铁类还原剂)、还原性硫化物(H2S、FeSx、硫代硫酸盐和多硫化合物等)及一些具有还原活性的有机物。本文系统地综述了不同还原剂对六价铬还原固定化的机理、影响因素、修复效果及适用范围;重点对常用还原剂的优缺点进行了比较,并提出了存在的问题和今后的发展方向。 相似文献
4.
实验探究了常温还原铁氧体法处理含铬废水的最优工艺条件,研究了不同亚铁盐及氨氮和COD对处理效果的影响,对沉淀进行了化学分析与材料表征。实验表明,在n(Fe2+):n(Cr6+)=6,共沉淀pH=10.0,还原时间为2 min,共沉淀时间为15 min条件下,处理含铬废水可达最好效果,总铬浓度从1 600 mg/L降至1.5 mg/L以下,符合国家《污水综合排放标准》(GB 8978-1996)的要求,实现了常温条件下铁氧体法对含铬废水的处理。对于不同亚铁盐,氯化亚铁处理废水的性能要强于硫酸亚铁,沉降速率快且沉淀致密。一般浓度的氨氮(50 mg/L)与COD(500 mg/L)对处理效果没有明显影响。对沉淀进行酸稳定性分析和XRD表征,确定生成了稳定的含铬复合铁氧体。 相似文献
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6.
研究了未处理的腐殖酸(HA)和不溶性腐殖酸(IHA)对Cr(Ⅵ)的吸附作用.进行了反应时间、pH值、IHA投加量、温度等对去除效率的影响研究,确定了两种吸附剂最佳反应条件,并通过对比实验,分析了两种吸附剂吸附Cr(Ⅵ)的特点.实验表明,HA达到最大吸附量时所需要的反应时间(180 min左右)远远高于IHiA的反应时间... 相似文献
7.
Simultaneous photocatalytic reduction of poisonous Cr(VI) and Ni(II) ions, coupled with photocatalytic oxidation of sodium dodecyl benzene sulfonate (SDBS) were studied with a trace amount of commercial titania nanoparticles and by means of a direct-photo-irradiation reactor. The co-presence of metal ions and SDBS causes metal ions reduction as well as SDBS oxidation to enhance and energy efficiency to improve. XRD, XPS and FTIR analysis were used to characterize TiO2 particles before and after usage with the aim of evaluating the mechanism of reactions. The effect of major operating parameters, pH and temperature, was investigated. Under conditions of [Cr(VI)]0 = [Ni(II)]0 = 5 mg/L, [SDBS]0 = 10 mg/L, [TiO2] = 40 mg/L, pH 6 and T = 35 °C; the removal efficiencies of 55.4%, 71.2% and 57.2% were obtained, respectively, for Cr(VI) and Ni(II) reduction, as well as for SDBS oxidation, after 110 min operation. The relevant kinetic model jointed with the Arrhenius equation was introduced. Pseudo-first-order reactions are relevant. Energy consumption (electrical and thermal) evaluations revealed that operations at higher temperatures provide significant cost reduction. Meantime, a criterion was proposed for a consistent assessment of this kind of processes. 相似文献
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