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1.
Zhen Bi Deqing Wanyan Xiang Li Yong Huang 《Frontiers of Environmental Science & Engineering》2020,14(3):38
2.
The effect of pyrolysis and oxidation characteristics on the explosion sensitivity and severity parameters, including the minimum ignition energy MIE, minimum ignition temperature MIT, minimum explosion concentration MEC, maximum explosion pressure Pmax, maximum rate of pressure rise (dP/dt)max and deflagration index Kst, of lauric acid and stearic acid dust clouds was experimentally investigated. A synchronous thermal analyser was used to test the particle thermal characteristics. The functional test apparatuses including the 1.2 L Hartmann-tube apparatus, modified Godbert-Greenwald furnace, and 20 L explosion apparatus were used to test the explosion parameters. The results indicated that the rapid and slow weight loss processes of lauric acid dust followed a one-dimensional diffusion model (D1 model) and a 1.5 order chemical reaction model (F1.5 model), respectively. In addition, the rapid and slow weight loss processes of stearic acid followed a 1.5 order chemical reaction model (F1.5 model) and a three-dimensional diffusion model (D3 model), respectively, and the corresponding average apparent activation energy E and pre-exponential factor A were larger than those of lauric acid. The stearic acid dust explosion had higher values of MIE and MIT, which were mainly dependent on the higher pyrolysis and oxidation temperatures and the larger apparent activation energy E determining the slower rate of chemical bond breakage during pyrolysis and oxidation. In contrast, the lauric acid dust explosion had a higher MEC related to a smaller pre-exponential factor A with a lower amount of released reaction heat and a lower heat release rate during pyrolysis and oxidation. Additionally, due to the competition regime of the higher oxidation reaction heat release and greater consumption of oxygen during explosion, the explosion pressure Pm of the stearic acid dust was larger in low concentration ranges and decayed to an even smaller pressure than with lauric acid when the concentration exceeded 500 g/m3. The rate of explosion pressure rise (dP/dt)m of the stearic acid dust was always larger in the experimental concentration range. The stearic acid dust explosion possessed a higher Pmax, (dP/dt)max and Kst mainly because of a larger pre-exponential factor A related to more active sites participating in the pyrolysis and oxidation reaction. Consequently, the active chemical reaction occurred more violently, and the temperature and overpressure rose faster, indicating a higher explosion hazard class for stearic acid dust. 相似文献
3.
采用溶胶-凝胶法制备了Mn掺杂钙钛矿型催化剂LaFexMn1-xO3,并以其为催化剂催化湿式双氧水氧化处理煤气化废水纳滤浓缩液。采用XRD,SEM,FTIR技术对催化剂进行了表征。表征结果显示:制备的催化剂均具有标准的钙钛矿型结构,其中,LaFe0.9Mn0.1O3的结构稳定,比表面积大。实验结果表明:制备的催化剂中LaFe0.9Mn0.1O3的催化活性最高,且稳定性好,连续使用5次后催化活性未见明显减弱;在H2O2投加量3.0 g/L、n(H2O2)∶n(LaFe0.9Mn0.1O3)=12∶1、反应温度160 ℃、反应压力1 MPa、浓缩液pH 3、反应时间60 min的最优条件下,COD、UV254和TOC的去除率分别达到80.9%、95.2%和68.0%,BOD5/COD由0.02提升至0.40,可生化性大幅提高。 相似文献
4.
以颗粒活性炭(GAC)为载体、铜为活性组分、铈为助剂组分、草酸钠为沉淀剂,采用浸渍焙烧法制得CuO_x-CeO_2/GAC催化剂。以H_2O_2为氧化剂,微波强化催化湿式过氧化氢氧化(CWPO)处理二甲亚砜(DMSO)初始质量浓度为1 000 mg/L的废水,处理3 min后DMSO去除率达93.8%。催化剂第7次使用时DMSO去除率仍保持在75%以上。初始废水pH在3~9范围内,DMSO去除率均在85%以上。助剂Ce的加入提高了催化剂表面活性组分的分散性和稳定性,使催化剂的活性稳定性和使用寿命显著提高。 相似文献
5.
采用臭氧氧化—湿式钙法吸收工艺对模拟烟气进行同时脱硫脱硝处理。O3于150 ℃下具有较高的热稳定性,可将NO氧化为高价态氮氧化物,且NO氧化率随n(O3)∶n(NO)的增大而逐渐提高。烟气中SO2和H2O的存在对NO氧化率的影响不大。O3对SO2的氧化率较低,约为5%。3%(w)石灰石浆液对SO2的吸收率接近100%,NOx吸收率随n(O3)∶n(NO)的增大而逐渐提高,当n(O3)∶n(NO)为1.6时NOx吸收率可达约65%。SO2能促进吸收液对NOx的脱除。石灰石浆液中加入0.2%(w)的(NH4)2SO3或Na2SO3后NOx吸收率可达约85%或82%,且吸收率随添加剂加入量的增加而提高,添加(NH4)2SO3的NOx吸收率略高于添加Na2SO3。 相似文献
6.
采用三维电极电Fenton氧化法处理实际染料废水,探究了染料废水处理效果的影响因素。实验结果表明:以钌铱镀层钛电极为阳极、不锈钢板为阴极、粉末活性炭为颗粒电极,在粉末活性炭投加量为2.0 g/L、电流密度为0.5 mA/mm2、极板间距为3 cm、pH为2.0、硫酸亚铁投加量为0.50 g/L的最优工艺条件下,反应2 h后COD、TOC、氨氮、色度的去除率达到最大,分别为62.80%、41.15%、42.48%和95.00%;粉末活性炭作为颗粒电极可使染料废水COD去除率提高18个百分点;重复使用10次的处理效果与第2次基本持平。 相似文献
7.
Secondary containment (bunds, drip trays, interceptors/sumps) is an integral part of many chemical, petrochemical, as well as agricultural, food and pharmaceutical facilities. Bunds are the built-in cases for accidental liquid substance spillage where there is a hazard that a substance could leak into the surroundings and the potential of health or environmental damage. The authors focus on the cases installed in large-volume atmospheric tanks storing hazardous chemicals in liquid form, where the bund failure occurred. In the first part of the study, a database of these accidents was created, numbering a total of 15 items. Attention was paid to the course of the accident, its causes and consequences. Several basic representative scenarios of bund failure have also been developed. The second part of the study is devoted mainly to the measures against the bund failure, such as risk assessment, technical and organizational measures. The aim of this study is to provide readers (including experts in the field of safety engineering, maintenance experts and building designers) with the information that can subsequently be used in the risk assessment of bund failure, possibly also for planning the construction of new bunds, or revitalization and maintenance of the existing ones. 相似文献
8.
Yapeng Song Hui Gong Jianbing Wang Fengmin Chang Kaijun Wang 《Frontiers of Environmental Science & Engineering》2020,14(4):64
9.
基于平衡计分卡原理,结合网站特点,建立了大气环境监测数据共享网站绩效评估模型。以共享网站的战略愿景为模型框架的中心,以财务、顾客、内部程序、学习与成长等4个基本维度为一级指标,构建了绩效评估指标体系,并采用层次分析法确定了各指标的权重。利用该模型对长三角区域空气质量预测预报系统和宁波市空气质量预报预警平台的大气数据共享模块进行实证研究,绩效评估结果均为良好。 相似文献
10.
通过分析降水化学成分,探讨黄山景观区域降雨的微量元素化学组成特征及其来源。结果表明,降雨中微量元素含量呈现明显的季节性变化,主要受到降雨量、pH值、风向及溶解有机质等因素影响。来源分析和贡献估算结果表明,降雨中Mn、Cu、Pb、Cd、Ni、Co等元素受燃煤和交通污染排放的影响显著,贡献率均在98%以上;土壤源和人为源对Fe的贡献率分别为76. 9%、23. 1%,对Ti的贡献率为22. 8%、77. 2%; Sr主要受海洋源(28. 3%)和人为源(70. 5%)双重影响。 相似文献