2016—2017年武汉市城区大气PM2.5污染特征及来源解析

利用2016年1月至2017年9月湖北省环境监测中心站大气复合污染自动监测站的在线监测数据，对武汉市城区PM_2.5的污染特征及主要来源进行解析。结果表明，武汉市城区PM_2.5质量浓度呈现出明显的季节差异，季节变化规律为冬季>春季>秋季>夏季。水溶性离子的主要成分SO₄^2-、NO₃^-和NH₄⁺占总离子质量浓度的82.0%。PM_2.5中阴离子相对阳离子较为亏损，颗粒整体呈碱性。夏季气态污染物的氧化程度较高且SO₂较NO₂氧化程度高。后向轨迹分析结果表明，区域传输是武汉市PM_2.5的一个重要来源，在4个典型重污染阶段，武汉市分别受到局地、东北、西北及西南方向气团传输的影响。PMF模型解析出武汉市PM_2.5五大主要来源及平均贡献率：扬尘22.0%、机动车排放27.7%、二次气溶胶21.6%、重油燃烧14.9%和生物质燃烧13.8%。     

固定源排污许可证监测管理制度研究

依靠排污许可证管理,固定源执行由行业排放标准为主正逐步过渡到"国家行业排放标准——单一源排放标准"双层排放标准,并以执行更全面和精准的单一源排放标准为主,对应的监测要求及考核方式更加多样化。对监测管理制度进行设计,明确固定源制定自行监测方案和守法监测的主体责任,厘清许可证核发部门、属地监测、执法部门的监管职责。系统设计"固定源制定并提交自行监测方案-核发部门审核-方案纳入排污许可证中成为规定-依规定自行监测和记录-固定源提交执行报告-监管部门审计式审核-执法监测和执法检查"的全过程管理机制,设计标准化的监管计划程序落实证后监管与执法监测,明晰监管部门的有限责任。     

基于生态系统服务供需的雄安新区生态安全格局构建

生态安全格局构建是保障区域生态安全的关键。沿用“源地识别—阻力面构建—廊道提取”的生态安全格局构建模式，选取粮食供给、产水量、土壤保持、固碳释氧和生境维持5项生态系统服务供给指标，以及人口密度、地均GDP和土地利用程度3项生态系统服务需求指标，综合生态系统服务供需2方面识别重要生态源地，利用夜间灯光强度进行基本阻力面修正，采用最小累积阻力模型进行生态廊道提取，构建出雄安新区生态安全格局。研究表明:新区生态源地总面积约48433 km2，占新区土地总面积的313%，主要分布于新区西北部旱地和东南部水域；新区生态阻力系数空间分布较为破碎，大部分区域阻力值较低，间或分布高阻力值；新区生态廊道总长度18586 km，呈“Y”字型沿建设用地和水系分布，所处地类主要为旱地。基于生态系统服务供需的生态安全格局构建可为新区规划建设提供参考和借鉴。     

A new approach to spatial source apportionment of haze pollution in large scale and its application in China

Long-lasting expansion of haze pollution in China has already presented a stern challenge to regional joint prevention and control. There is an urgent need to enlarge and reconstruct the coverage of joint prevention and control of air pollution in key area. Air quality models can identify and quantify the regional contribution of haze pollution and its key components with the help of numerical simulation, but it is difficult to be applied to larger spatial scale due to the complexity of model parameters. The time series analysis can recognize the existence of spatial interaction of haze pollution between cities, but it has not yet been used to further identify the spatial sources of haze pollution in large scale. Using econometric framework of time series analysis, this paper developed a new approach to perform spatial source apportionment. We applied this approach to calculate the contribution from spatial sources of haze pollution in China, using the monitoring data of particulate matter (PM_2.5) across 161 Chinese cities. This approach overcame the limitation of numerical simulation that the model complexity increases at excess with the expansion of sample range, and could effectively deal with severe large-scale haze episodes.     

新形势下对环境统计工作的思考

分析了环境统计工作的定位和内容,以及第二次全国污染源普查、排污许可证与排污税制度、环境质量考核制度给环境统计工作带来的改革契机。针对固定源、城镇生活源与农业面源、移动源,提出了统计调查工作的设想。建议改变环境统计调查焦点,实现污染源统计空间格局"一张图";开拓环境统计分析品牌,推动环境统计方法研究;以政策管理需求为导向,完成环境统计工作体系的重构。     

Optimal Absorbent Evaluation for the CO2 Separating Process by Absorption Loading,Desorption Efficiency,Cost, and Environmental Tolerance

The CO₂ absorption capacities of potassium glycinate, potassium sarcosinate (choline, proline), mono-ethanolamine (MEA), and tri-ethanolamine were evaluated to find the optimal absorbent for separating CO₂ from gaseous products by a CO₂ purification process. The absorption loading, desorption efficiency, cost, and environmental tolerance were assessed to select the optimal absorbent. MEA was found to be the optimum absorbent for separating the CO₂ and H₂ mixture in gaseous product. The maximum absorption loading rate was 0.77 mol CO₂ per mol MEA at temperature of 20°C and absorbent concentration of 2.5 mol/L, whereas desorption efficiency was 90% by heating for 3 h at 130°C. MEA was found to be an optimal absorbent for the purification process of CO₂ during gaseous production.     

Feasibility of honeycomb monolith supported sugar catalyst to produce biodiesel from palm fatty acid distillate (PFAD)

Carbon coated monolith was prepared by sucrose solution 65 wt.% via dip-coating method. Sulfonation of incomplete carbonized carbon coated monolith was carried out in order to synthesize solid acid catalyst. The textural structure characteristics of the solid acid catalyst demonstrated a low surface area and pore volume. Palm fatty acid distillate (PFAD), a by-product of palm oil refineries, was utilized as oil source in biodiesel production. The esterification reaction subjected to different reaction conditions was performed by using the sulfonated carbon coated monolith as heterogeneous catalyst. The sulfonation process had been performed by using vapour of concentrated H₂SO₄ that was much easier and efficient than liquid phase sulfonation. Total acidity value of carbon coated monolith was measured for unsulfonated sample (0.5 mmol/g) and sulfonated sample (4.2 mmol/g). The effect of methanol/oil ratio, catalyst amount and reaction time were examined. The maximum methyl ester content was 89% at the optimum condition, i.e. methanol/oil molar ratio (15:1), catalyst amount (2.5 wt.% with respect to PFAD), reaction time (240 min) and temperature 80 °C. The sugar catalyst supported on the honeycomb monolith showed comparable reactivity compared with the sugar catalyst powder. However, the catalyst reusability studies showed decrease in FFA% conversion from 95.3% to 68.8% after four cycles as well as the total acidity of catalyst dropped from the value 4.2 to 3.1 mmol/g during these cycles. This might be likely due to the leaching out of SO₃H group from the sulfonated carbon coated monolith surface. The leaching of active species reached a plateau state after fourth cycle.     

大气细颗粒物在线源解析方法研究进展

基于对国内外关于PM2.5化学组分特征、二次气溶胶生成机理、源解析模型的研究综述,引入实现PM2.5在线源解析的2种可能方法,即气溶胶质谱+解析算法与3类化学组分组合观测+受体模型。重点阐述了气溶胶质谱及在线水溶性离子、EC/OC和金属元素仪器的应用研究现状,并分析了不同仪器测定结果的可靠性、优势及缺陷,在此基础上提出加强城市尺度的大气化学二次反应机理及关键技术参数研究、大气颗粒物化学组分连续观测应用于在线源解析的研究、基于多种信息来源和技术手段的在线源解析方法集成研究等建议。     

河流型饮用水水源保护区划分比较

比较分析了国内外河流型水源保护区划分的原则、方法和标准,例证了我国不同省份的划分实践。指出,我国各省多采用经验值划分水源保护区范围,部分省份划分方案久未更新,没有充分发挥保护区的作用。提出,应进一步细化水源保护区划分规范指导要求,及时修订省级水源保护区划分方案,并借鉴国外水源保护区划分经验,通过调整水质标准、重视公众参与、利用地理信息系统等方式划分水源保护区,从源头上预防水源污染,降低饮用水公共风险,保障饮用水安全。     

横通道通风对隧道火灾烟气蔓延影响的数值模拟研究*

为探究隧道横通道通风对隧道火灾烟气蔓延的影响规律,使用火灾动力学模拟软件FDS,对不同火源位置的横通道临界风速、主隧道温度分布以及烟气层高度进行研究。研究结果表明:在一定火源功率范围内,隧道横通道临界风速与火源功率的1/3次方成正比且火源距横通道越远,临界风速越小;当火源位于交叉口,横通道使用临界风速通风时,隧道内烟气温度明显降低,烟气迅速沉降到2 m以下;当火源距离交叉口10,20 m,横通道通风会加快火源下游烟气沉降,烟气沉降速度随横通道通风速率的增大而增大;当火源位于交叉口时,烟气沉降由横通道通风对烟气的降温作用和涡旋作用共同主导,当火源位于距离交叉口10,20 m时,烟气沉降主要由涡旋作用主导。