絮凝沉淀法测定地表水中氨氮的方法改进

本文通过比较监测黑臭河流氨氮时人员比对的结果,对絮凝沉淀预处理过程的关键因素进行了改进。结果表明,直接在离心管中絮凝沉淀、离心、取样分析,精密度和准确度更好,而且方便快捷,值得推广。     

Dissolved organic matter in pore water of freshwater sediments: effects of separation procedure on quantity, quality and functionality

Pore water was separated either with or without water extraction prior to centrifugation (7600 or 20 000 × g) in order to investigate the effects of separation procedure on the amount and properties of dissolved organic matter (DOM i.e. the material passing through a 0.45-μm filter) in three freshwater sediments. On the basis of solubility in alkaline, organic matter was concluded to compose of humic substances in two (S1 and S3) and of humin (S2) in one of the sediments. DOM in the samples was quantified by total organic carbon measurement. Specific UV-absorption (SUVA) and high performance size exclusion chromatography (HPSEC) analyses were used to characterize DOM. Sorption of pyrene was used as a measure for functionality of DOM. Both water extraction and centrifugation speed were shown to affect the properties of DOM; however, the effects were sediment dependent. Water extraction increased the amount of DOM separated from the two sediments that had humic character (S1 and S3). In most cases water extraction increased SUVA and shifted the molecular size distribution of DOM towards larger sizes. The separation procedure had also an effect on the functionality of DOM. In water extracted samples of S2 and S3 the sorption of pyrene was higher than in the corresponding samples separated without water extraction, whereas in S1 similar effect was not found. Generally, centrifugation speed had smaller effects on the properties of DOM than water extraction. The fact that the effects of separation procedure on DOM depend on the sediment characteristics complicates the comparison between samples and evaluation of functionality in field conditions.     

Priority and emerging pollutants in sewage sludge and fate during sludge treatment

This paper aims at characterizing the quality of different treated sludges from Paris conurbation in terms of micropollutants and assessing their fate during different sludge treatment processes (STP). To achieve this, a large panel of priority and emerging pollutants (n = 117) have been monitored in different STPs from Parisian wastewater treatment plants including anaerobic digestion, thermal drying, centrifugation and a sludge cake production unit. Considering the quality of treated sludges, comparable micropollutant patterns are found for the different sludges investigated (in mg/kg DM – dry matter). 35 compounds were detected in treated sludges. Some compounds (metals, organotins, alkylphenols, DEHP) are found in every kinds of sludge while pesticides or VOCs are never detected. Sludge cake is the most contaminated sludge, resulting from concentration phenomenon during different treatments. As regards treatments, both centrifugation and thermal drying have broadly no important impact on sludge contamination for metals and organic compounds, even if a slight removal seems to be possible with thermal drying for several compounds by abiotic transfers. Three different behaviors can be highlighted in anaerobic digestion: (i) no removal (metals), (ii) removal following dry matter (DM) elimination (organotins and NP) and iii) removal higher than DM (alkylphenols – except NP – BDE 209 and DEHP). Thus, this process allows a clear removal of biodegradable micropollutants which could be potentially significantly improved by increasing DM removal through operational parameters modifications (retention time, temperature, pre-treatment, etc.).     

离心法在土壤颗粒分级技术中的应用

用离心法进行土壤颗粒分级,优化了离心时间和转速,并对河北保定,浙江嘉兴,磐安、永康和温州五地典型土壤样品进行了土壤颗粒粒径分布的初步研究,探讨了土壤颗粒直径和土壤有机质.土壤pH值之间的相关关系.结果显示:离心法土壤分级技术的回收率为96.73%～99.74%,实验按照粒径尺寸将土壤样品分成四级,分别是砂粒(>20 μm),粗粉砂(5～20μm),细粉砂(2～5μm)和粘粒(<2 μm).保定土壤的砂粒含量最高,达92.68%,磐安土样的粗粉砂含量最高,达4.12%,各样品细粉砂颗粒含量相当,均值为1.73%,粘粒含量很少,均值为0.44%.土壤有机质含量以磐安土壤最高,达9.15%,而土壤pH值则是保定土壤最高,为8.14.     

制浆,黑液碱回收试验研究

本文对造纸工业制浆黑液中的碱回收问题进行了探讨,在实验的基础上,提出了一种切实可行而且比传统的燃烧法投资更省的碱回收工艺,即将多效蒸发后的浓缩黑液经等离子处理后得到的黑粉,稀释后用离心过滤脱水的办法再进行碱回收。