典型装饰织物在不同氧浓度下热分析研究

人民生活水平的提高使人民对室内环境的舒适程度提出了更高要求,室内装饰织物的用量迅速增加,室内装饰织物在燃烧时会释放出大量有毒物质和热量,对人及环境构成了巨大危害.因此,研究装饰织物的燃烧特性非常重要.笔者利用热重-差热(TG-DTA)分析仪对纯棉、棉麻和腈纶这几种典型的装饰织物在不同的氧气浓度(10%,15%,21%)和升温速率(10K/min,30K/min)条件下进行了热重分析(TG)和差热分析(DTA)实验,研究了它们的燃烧特性,并着重进行了不同氧浓度下的对比研究,发现试样的燃烧分为两个阶段.建立了以一级反应模型为主的动力学方程,并得出了各阶段的动力学参数、表观活化能和频率因子.     

Treatment of digestate from a co-digestion biogas plant by means of vacuum evaporation: Tests for process optimization and environmental sustainability

Vacuum evaporation consists in the boiling of a liquid substrate at negative pressure, at a temperature lower than typical boiling temperature at atmospheric conditions. Condensed vapor represents the so called condensate, while the remaining substrate represents the concentrate.This technology is derived from other sectors and is mainly dedicated to the recovery of chemicals from industrial by-products, while it has not been widely implemented yet in the field of agricultural digestate treatment. The present paper relates on experimental tests performed in pilot-scale vacuum evaporation plants (0.100 and 0.025 m³), treating filtered digestate (liquid fraction of digestate filtered by a screw-press separator). Digestate was produced by a 1 MW_e anaerobic digestion plant fed with swine manure, corn silage and other biomasses. Different system and process configurations were tested (single-stage and two-stage, with and without acidification) with the main objectives of assessing the technical feasibility and of optimizing process parameters for an eventual technology transfer to full scale systems.The inputs and outputs of the process were subject to characterization and mass and nutrients balances were determined.The vacuum evaporation process determined a relevant mass reduction of digestate.The single stage configuration determined the production of a concentrate, still in liquid phase, with a total solid (TS) mean concentration of 15.0%, representing, in terms of mass, 20.2% of the input; the remaining 79.8% was represented by condensate. The introduction of the second stage allowed to obtain a solid concentrate, characterized by a content of TS of 59.0% and representing 5.6% of initial mass.Nitrogen balance was influenced by digestate pH: in order to limit the stripping of ammonia and its transfer to condensate it was necessary to reduce the pH. At pH 5, 97.5% of total nitrogen remained in the concentrate. This product was characterized by very high concentrations of total Kjeldhal nitrogen (TKN), 55,000 mg/kg as average.Condensate, instead, represented 94.4% of input mass, containing 2.5% of TKN. This fraction could be discharged into surface water, after purification to meet the criteria imposed by Italian regulation. Most likely, condensate could be used as dilution water for digestion input, for cleaning floor and surfaces of animal housings or for crop irrigation.The research showed the great effectiveness of the vacuum evaporation process, especially in the two stage configuration with acidification. In fact, the concentration of nutrients in a small volume determines easier transportation and reduction of related management costs. In full scale plants energy consumption is estimated to be 5–8 kWh_e/m³ of digestate and 350 kWh_t/m³ of evaporated water.     

不同类型喷头灭火有效性研究

通过实验研究了不同类型喷头对灭木垛火的影响。实验采用了ZSTX和ZSTP两种类型喷头,在不同的水压力下灭木垛火,通过实验现场观测和测得的烟气温度,烟气组分变化来分析对比灭火的效果和对烟气的影响。通过对比分析实验数据,可知ZSTX喷头在0.2MPa的水压力下可以实现灭火,ZSTP喷头在0.4MPa才可以实现灭火。喷淋实现灭火时产生的CO比只能实现控火产生的CO少。     

压缩空气泡沫在长距离管路输送中压降的数值模拟

基于Fluent对压缩空气泡沫在长距离管道中的流动特性进行了数值模拟研究,将压缩空气泡沫近似为弥散流,采用Saplart-Allmaras模型模拟了不同管径下压缩空气泡沫以及不同泡沫原液浓度的AFFF泡沫在长距离管道内的流动及压降变化。模拟结果表明,随着距离变化,各管径管道内压降均呈现线性变化,且随着压缩空气泡沫的流动,压降线性增大。管道管径对管内压降变化具有显著影响,管道直径越小,管道内压降越大;泡沫原液浓度对压降的影响较小,且压缩空气泡沫在长距离输送中的压力随距离线性衰减。将模拟结果与长距离输送的试验结果进行了对比,误差在10%以内。     

基于BP神经网络的儿童卧室内灰尘PAEs浓度预测

在实测数据的基础上,以邻苯二甲酸酯(PAEs)的各类影响因素为自变量,PAEs浓度为因变量,采用Back-propagation(BP)神经网络建立儿童卧室内PAEs浓度预测模型.结果表明,该模型的预测效果较理想,其中,STD比值均＞0.5,NMB均接近0,EMR均＜19％.以室内环境与儿童健康(CCHH)课题组天津地...     

高温热表面油液蒸发的时变性热质传递模型与实验研究

针对高温热表面油液蒸发热质传递过程的时变性,考虑这一过程中的对流传质传热,建立了热环境作用下油液蒸发的热质传递模型方程,通过无量纲变换,求得空间浓度分布和温度场随时间的变化规律。以庚烷为试验对象,对高温热表面油液蒸发过程进行了实验研究。理论分析与实验表明:庚烷蒸发过程中,刘易斯数大于1,传热速率大于传质速率;蒸发导致的质量损失与时间平方根的成正比,与液面的面积成正比,且与质量扩散系数的平方根成正比,饱和蒸气浓度越大,蒸发速率也越大。油液蒸发计算结果与试验结果基本一致,表明了模型的有效性。     

药厂、啤酒厂等有机废水厌氧处理试验研究

针对几种高浓度有机废水进行厌氧处理试验,取得参数,为生产性试验提供有价值的参数。     

An optimal level of dust explosion risk management: Framework and application

The current research provides guidance on the prevention and mitigation of dust explosion using a Quantitative Risk Management Framework (QRMF). Using concepts drawn from previous studies, the framework consists of three main steps: (i) a new combined safety management protocol, (ii) the use of DESC (Dust Explosion Simulation Code) and FTA (Fault Tree Analysis) to assess explosion consequences and likelihood, respectively, and (iii) application of the hierarchy of controls (inherent, engineered and procedural safety). QRMF assessment of an industrial case study showed that the original process was at high risk. DESC simulations and Probit equations determined the destructive percentages. FTAs revealed high probabilities of explosion occurrence; in addition, detailed individual and societal risks calculations were made, before and after the framework was applied. Based on the hierarchy of controls technique, the framework showed significant risk reduction to the point where the residual risk was acceptable for the process.     

计算机辅助确定外因火灾位置方法

系统介绍用计算机辅助确定矿井外因火灾位置方法的原理,给出该方法的具体步骤,剖析其定性分析、定量分析和定量分析结果评价三大步骤中的各技术关键,并借助一个实例验证了该方法实用的可行性