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Natural muds used as or in cosmetics may expose consumers to toxic metals and elements via absorption through the skin, inhalation
of the dried product, or ingestion (by children). Despite the extensive therapeutic and cosmetic use of the Dead Sea muds,
there apparently has been no assessment of the levels of such toxic elements as Pb, As, or Cd in the mud and mud-based products.
Inductively coupled plasma mass spectrometry analysis of eight toxic elements in samples collected from three black mud deposits
(Lisan Marl, Pleistocene age) on the eastern shore of the Dead Sea in Jordan revealed no special enrichment of toxic elements
in the mud. A similar analysis of 16 different commercial Dead Sea mud cosmetics, including packaged mud, likewise revealed
no toxic elements at elevated levels of concern. From a toxic element standpoint, the Dead Sea black muds and derivative products
appear to be safe for the consumer. Whatever the therapeutic benefits of the mud, our comparison of the elemental fingerprints
of the consumer products with those of the field samples revealed one disturbing aspect: Dead Sea black mud should not be
a significant component of such items as hand creams, body lotions, shampoo, and moisturizer. 相似文献
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Benn TM Westerhoff P Herckes P 《Environmental pollution (Barking, Essex : 1987)》2011,159(5):1334-1342
Detection methods are necessary to quantify fullerenes in commercial applications to provide potential exposure levels for future risk assessments of fullerene technologies. The fullerene concentrations of five cosmetic products were evaluated using liquid chromatography with mass spectrometry to separate and specifically detect C60 and C70 from interfering cosmetic substances (e.g., castor oil). A cosmetic formulation was characterized with transmission electron microscopy, which confirmed that polyvinylpyrrolidone encapsulated C60. Liquid-liquid extraction of fullerenes from control samples approached 100% while solid-phase and sonication in toluene extractions yielded recoveries of 27-42%. C60 was detected in four commercial cosmetics ranging from 0.04 to 1.1 μg/g, and C70 was qualitatively detected in two samples. A single-use quantity of cosmetic (0.5 g) may contain up to 0.6 μg of C60, demonstrating a pathway for human exposure. Steady-state modeling of fullerene adsorption to biosolids is used to discuss potential environmental releases from wastewater treatment systems. 相似文献
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采用高效液相色谱二极管阵列检测器同时测定化妆品中二苯酮-2、二苯酮-3与甲氧基肉桂酸乙基己酯,以乙腈和水为流动相梯度洗脱,335 nm为检测波长,以保留时间和紫外光谱特征定性,外标法定量。3种化合物在1.00 mg/L~150 mg/L范围内线性良好,最低检出质量分数均为0.015%,基质加标平均回收率为96.2%~117%,RSD为0.2%~1.0%。 相似文献
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Perfluorinated carboxylic acids (PFCAs), including perfluorooctanoic acid (PFOA), are persistent organic pollutants that pose human health risks. However, sources of contamination and exposure pathways of PFCAs have not been explored. In this study, PFCA concentrations were quantified in personal care products. Among 24 samples that listed fluorinated compounds, such as polyfluoroalkyl phosphate esters (PAPs), in their international nomenclature of cosmetic ingredients (INCI) labels, 21contained PFCAs (13 of 15 cosmetic samples, and 8 of 9 sunscreen samples). The concentrations of total PFCAs ranged from not detected to 5.9 μg g−1 for cosmetics and from not detected to 19 μg g−1 for sunscreens. We also investigated components of PFCAs in cosmetics and sunscreens. Commercially available compounding agents, mica and talc, which were treated with PAPs were analyzed and high concentrations of PFCAs were detected (total PFCAs 2.5 μg g−1 for talc treated with PAPs, 35.0 μg g−1 for mica treated with PAPs). To the best of our knowledge, this is the first report on contamination of end consumer products containing PAPs with high concentrations of PFCAs. 相似文献
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