土壤污染物的生态毒理效应和风险评估研究进展

环境生态风险评估（ERA）流程已经被纳入全球环境政策中，既用于规范新化学物质的授权和营销（前瞻性环境生态风险评估），也用于评估潜在的污染场地（回顾性环境生态风险评估）。将土壤生态毒理学应用于风险评估，能阐明有毒物质对土壤生态系统中生命有机体的危害程度与范围。笔者主要介绍了应用评估因子法和物种敏感度分布法对基于效应数据进行的外推与估算，并综述了欧美等主要国家和地区的土壤生态风险评估框架、相关法律法规及其实施情况等，为中国开展土壤污染物生态毒理效应和风险评估等相关研究提供参考。     

射阳湖浮游动物群落结构特征及其与环境因子相关性研究

2016—2017年对射阳湖开展浮游动物群落结构和水质指标逐月监测。结果表明,射阳湖共鉴定出浮游动物61种,其中原生动物、轮虫、枝角类和桡足类分别为25种、24种、7种和5种。浮游动物种类数呈现春夏季多于秋冬季的变化趋势。浮游动物优势种数量较多、分布广,群落结构相对复杂且稳定。运用Shannon-Wiener指数、均匀度指数和B/T指数对射阳湖水质作评价,结果表明,该湖处于轻度—中度污染状态,生物学指标评价法与常规水质评价结果一致。浮游动物群落结构与水质指标相关性分析表明,水温、透明度、Chl-a和DO是影响射阳湖浮游动物群落结构的主要水质指标。     

Effect of pyrolysis and oxidation characteristics on lauric acid and stearic acid dust explosion hazards

The effect of pyrolysis and oxidation characteristics on the explosion sensitivity and severity parameters, including the minimum ignition energy MIE, minimum ignition temperature MIT, minimum explosion concentration MEC, maximum explosion pressure P_max, maximum rate of pressure rise (dP/dt)_max and deflagration index K_st, of lauric acid and stearic acid dust clouds was experimentally investigated. A synchronous thermal analyser was used to test the particle thermal characteristics. The functional test apparatuses including the 1.2 L Hartmann-tube apparatus, modified Godbert-Greenwald furnace, and 20 L explosion apparatus were used to test the explosion parameters. The results indicated that the rapid and slow weight loss processes of lauric acid dust followed a one-dimensional diffusion model (D1 model) and a 1.5 order chemical reaction model (F1.5 model), respectively. In addition, the rapid and slow weight loss processes of stearic acid followed a 1.5 order chemical reaction model (F1.5 model) and a three-dimensional diffusion model (D3 model), respectively, and the corresponding average apparent activation energy E and pre-exponential factor A were larger than those of lauric acid. The stearic acid dust explosion had higher values of MIE and MIT, which were mainly dependent on the higher pyrolysis and oxidation temperatures and the larger apparent activation energy E determining the slower rate of chemical bond breakage during pyrolysis and oxidation. In contrast, the lauric acid dust explosion had a higher MEC related to a smaller pre-exponential factor A with a lower amount of released reaction heat and a lower heat release rate during pyrolysis and oxidation. Additionally, due to the competition regime of the higher oxidation reaction heat release and greater consumption of oxygen during explosion, the explosion pressure P_m of the stearic acid dust was larger in low concentration ranges and decayed to an even smaller pressure than with lauric acid when the concentration exceeded 500 g/m³. The rate of explosion pressure rise (dP/dt)_m of the stearic acid dust was always larger in the experimental concentration range. The stearic acid dust explosion possessed a higher P_max, (dP/dt)_max and K_st mainly because of a larger pre-exponential factor A related to more active sites participating in the pyrolysis and oxidation reaction. Consequently, the active chemical reaction occurred more violently, and the temperature and overpressure rose faster, indicating a higher explosion hazard class for stearic acid dust.     

重大基坑坍塌事故虚拟仿真系统研究

为预防基坑坍塌事故发生、进行重大事故警示教育，以杭州地铁湘湖站北2基坑坍塌事故为素材，研究构建重大基坑坍塌事故虚拟仿真培训系统。对案例事故涉及的设计、施工、环境三大因素的技术问题进行总结，研究了事故链各致险因素及对推动事故发生所起作用，完成仿真系统平台设计和开发工作。系统应用多种制作技术创建工程场景模型，展示深基坑工程复杂的施工工序和空间关系，再现基坑坍塌事故发生发展过程和贴近实际的灾难场景。研究结果表明:仿真系统成果可丰富地下工程教学、施工现场安全教育和安全监察培训的内容和形式。     

磺胺氯哒嗪在海水中的间接光降解

以有色溶解有机物(CDOM)作为主要光敏剂研究磺胺氯哒嗪(SCP)间接光降解行为和机理,分析CDOM组成、盐度和pH值对SCP间接光降解的影响.SCP间接光降解速率随CDOM浓度升高而逐渐加快.CDOM产生的光化学反应活性中间体对SCP间接光降解的贡献率不同,其中³CDOM^*起主要作用,对SCP间接光降解的贡献率高达77.94%.所用CDOM由4种荧光组分组成,包含3种外源腐殖质(C1,C2,C3)和1种内源腐殖质(C4), SCP间接光降解去除率和³CDOM^*浓度分别与荧光组分的相关性大小顺序均为C3>C2>C4>C1.其中C3和C2与[³CDOM^*]具有较高线性相关性(R²>0.97),是³CDOM^*的主要贡献者.盐度和pH值对SCP间接光降解的影响作用显著.在盐度为15‰时,SCP的间接光降解速率最大.在低盐度范围(0~15‰)内,离子强度效应对间接光降解的促进作用大于无机阴离子带来的抑制作用,使得间接光降解速率随着盐度的升高而加快.溶液pH=(5.00±0.10)时,SCP的间接光降解速率最大.SCP的间接光降解速率随着溶液pH值的升高而减慢,中性和碱性环境不利于SCP的间接光降解.     

北京市典型废弃物焚烧源2010—2017年二NFDA1英排放特征和减排效果分析

分析2010—2017年北京市三类典型废弃物焚烧源的废气二NFDA1英排放监测数据,计算排放因子和排放量,评估减排政策成效,并分析不同排放源达标排放时同类物分布特征异同和变化规律,探讨影响排放的重要因素。结果表明: 5家焚烧源平均排放浓度为 0.008～0.069 ng/m³(以TEQ计,下同),废气二NFDA1英排放因子为 0.027～1.7 μg/t,2016年向空气中排放的二NFDA1英量为 0.002 5～0.058 g；生活垃圾、危险废物和医疗废物焚烧源的低、高氯代同类物质量分数比的平均值分别为接近于 0.5、大于0.5和小于0.5,危险废物焚烧源的 ∑PCDFs、∑PCDDs质量分数比的平均值大于2； 123478-HxCDF和123678-HxCDF质量浓度接近且线性相关,具有相近的生成机理和去除效率； I-TEQ变化趋势与∑PCDFs质量分数的变化趋势基本一致,活性炭喷射和布袋除尘的去除效率是影响二NFDA1英排放的重要因素之一；危险废物焚烧源HWI1随运行时间增加排放浓度增加,而及时更换烟道管壁有助于消除“记忆效应”的不良影响。     

嘉善前体物与气象因子对臭氧生成的影响及臭氧潜在源区分析

利用2017年嘉善善西超级站臭氧（O₃）及其前体物（NO_x和VOCs）以及气象因子（温度、湿度、风速）逐小时数据，分析了2017年全年NO_x和O₃的变化特征以及春季（4—5月）、夏季（7—8月）NO_x和气象因子对O₃生成的影响，利用O₃生成潜势（OFP）评估了VOCs大气化学反应活性，并通过潜在源区贡献（PSCF）和浓度权重轨迹（CWT）方法分析了嘉善春、夏季O₃潜在源区贡献特征。研究发现：O₃日变化特征为单峰结构，NO_x为弱双峰结构。O₃浓度在3—9月较高，春、夏季O₃浓度峰值分别出现在15：00和14：00，春、夏季的NO_x、O₃日变化与2017年全年日变化趋势基本一致。NO_x对O₃存在滴定作用，且低湿高温有利于O₃浓度的升高。春、夏季O₃生成潜势贡献均表现为烯烃 > 芳香烃 > 烷烃，由于烯烃光化学活性较高，夏季烯烃浓度升高导致其贡献较春季增长约18.1个百分点，且夏季VOCs平均最大O₃增量反应活性高于春季。PSCF和CWT分析结果表明，嘉善春季的潜在源区主要为本地、西南方向和东南方向，夏季的潜在源区主要为本地、西北方向、西南方向以及东南方向。     

基于SVM的矿井通风阻力系数影响因素分析与预测

矿井通风阻力系数是通风安全最重要的基础参数之一，为了实现矿井通风阻力系数简单准确地预测，提出了利用支持向量机（SVM）来预测矿井通风阻力系数的方法。通过分析影响因子与矿井通风阻力系数的相关性关系，并利用MATLAB逐步建立单影响因素与矿井通风阻力系数、多影响因素与矿井通风阻力系数之间的SVM预测模型，对比分析各预测模型的相对误差，确定最佳矿井通风阻力系数预测模型，即当输入模型影响因素为巷道断面积、周长和支护方式时，预测相对误差小于10%的样本数占测试样本的76%，相对误差小于20%的样本数占测试样本的90%。结果表明:该预测方法在矿井通风阻力系数预测中是可行的，并具较高的准确性。     

阿什河底栖动物群落特征及影响因子

阿什河作为松花江的一级支流,全境包含了从Ⅰ类到劣Ⅴ类的各种类型水质。通过对阿什河沿线底栖动物群落构成进行调查,结合典范对应性分析(CCA)对底栖动物群落与环境因子进行相关性分析得出结论,溶解氧和高锰酸盐指数为研究区域内底栖动物群落构成的主要限制因子。为分析不同水质条件下底栖动物种群变化成因和从生物学角度提出阿什河治理方法提供技术依据。     

Technological innovation paths toward green industry in China

With the environmental carrying capacity reaching its limits and the decreasing margin benefits of traditional production factors, the green transformation and green development through technological innovations has been a major direction for the future development of Chinese industries. However, the characteristics and heterogeneities of various types of industries call for different approaches regarding technological innovations. How to choose the most effective mode of technological innovation according to the characteristics of a certain industry has been a key issue. This paper measures the green total factor productivity of 32 industrial trades using the Slacks Based Measure(SBM)-DDF method. The effects of three innovation modes in the green transformation of industrial industry, including the independent innovation(Ⅱ), the technology introduction(TI), and the government support(GS), are empirically analyzed based on industry heterogeneity. Results indicate that the green total factor productivities of different industries show significant differences if taking into account the energy input and the undesirable output of pollutant emissions. The green total factor productivities of traditional high input,high pollution, and high energy consumption industrial trades were significantly lower than those with obvious green features. The year of 2009 is a leap year for the industrial green transformation in China. For resource-intensive industries, the II and the GS are the important ways to achieve green transformation. For labor-intensive industries, the TI is the best path to achieve green transformation, while for technology-intensive industries, the II is the primary driving force for the promotion of green developments. In addition, the innovation-compensating effect of the current Chinese environmental regulations to the resource-intensive industries has been revealed. Improving the overall scale and the industrial concentration of the industries is also beneficial for the green transformation of the industries.