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Pyridine, an important chemical raw material, is widely used in industry, for example in textiles,leather, printing, dyeing, etc. In this research, a dielectric barrier discharge(DBD) system was developed to remove pyridine, as a representative type of nitrogen heterocyclic compound in drinking water. First, the influence of the active species inhibitors tertiary butanol alcohol(TBA),HCO_3~-, and CO_3~(2-)on the degradation rate of pyridine was investigated to verify the existence of active species produced by the strong ionization discharge in the system. The intermediate and final products generated in the degradation process of pyridine were confirmed and analyzed through a series of analytical techniques, including liquid chromatography–mass spectrometry(LC–MS), high performance liquid chromatography(HPLC), ion chromatography(IC), total organic carbon(TOC) analysis, ultraviolet(UV) spectroscopy, etc. The results showed that the degradation of pyridine was mainly due to the strong oxidizing power of ozone and hydroxyl radical produced by the DBD system. Several intermediate products including 3-hydroxyl pyridine, fumaric acid, 2, 3-dihydroxypyridine, and oxalic acid were detected. Nitrogen was removed from the pyridine molecule to form nitrate. Through analysis of the degradation mechanism of pyridine, the oxidation pathway was deduced. The study provided a theoretical and experimental basis for the application of DBD strong ionization discharge in treatment of nitrogen heterocyclic compounds in drinking water. 相似文献
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吹扫捕集—气相色谱法能很好地满足地表水、废水中吡啶的分析要求,具有前处理简单、对设备要求低、抗干扰能力强的优点,且有良好的线性关系,相关系数达到0.999以上,相对标准偏差为1.3%~4.1%,加标回收率为80.1%~99.7%,方法检出限为0.015 mg/L。 相似文献
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顶空气相色谱法测定地表水中吡啶 总被引:2,自引:0,他引:2
采用顶空进样、毛细管柱HP -INNOWAX分离、GC -FID测定地表水中吡啶。水样顶空时通过加碳酸钠盐大幅度降低了检出限 ,最低检出浓度达到 0 0 2mg/L。本法加标回收率为 96 5 %~ 10 1% ,变异系数为 7 8%~ 9 8%。 相似文献
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通过对毒死蜱生产技术的国内外发展研究,说明山东谦诚公司发明的吡啶双定向氯化合成三氯吡啶酚钠工艺,具有技术先进性、经济合理性、环境可达性,是我国独创的,是毒死蜱生产技术的重大突破。环境保护综合名录认为吡啶双定向氯化合成三氧吡啶酚钠工艺是重大突破,具有技术先进性、经济合理性、环境可达性;通过对产品的全过程控制,分析毒死蜱对人体、作物土壤均有影响但是利大于弊。是可以接受的,被列入环境友好工艺。 相似文献
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以活性炭吸附大气中的吡啶,用二硫化碳解析、毛细管柱分离、FID检测器分析,采用保留时间定性、峰面积外标曲线法定量。方法在0~367mg/L范围内线性关系良好,当采样体积为20L时,最低检出质量浓度为0.007mg/m3,标准溶液平行测定的RSD≤2.0%,加标回收率为97.9%~104%。 相似文献
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含氮杂环化合物吡啶缺氧降解过程中硝酸还原酶活性研究 总被引:4,自引:0,他引:4
在实验室中,采用摇床试验,在保证缺氧的条件下。研究了含氮杂环化合物吡啶缺氧反硝化降解过程中,硝酸还原酶的适宜作用条件、吡啶降解过程中硝酸还原酶活性变化情况及吡啶和硝态氮等的降解情况。结果表明,C/N对吡啶缺氧反硝化降解具有重要意义,pH和温度均对硝黧还原酶活性具有一定影响。硝酸还原酶的适宜作用条件为:温度25—30℃,pH7.5。吡啶降解过程中,硝酸还原酶活性由低到高逐渐提高,最后达到一个相对稳定的数值。在适宜的碳氮比条件下,吡啶起始浓度越高,硝酸还原酶最后稳定活性越高。 相似文献
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缺氧反硝化去除难降解杂环化合物吡啶研究 总被引:6,自引:2,他引:6
在实验室中,采用好氧、厌氧和缺氧间歇试验,研究焦化废水中一种难降解有机物--吡啶的生物降解性能。试验主要研究了在缺氧状态下吡啶的生物降解性能、适宜的N/C比、N源的变化情况等。研究结果表明,缺氧反硝化状态下吡啶的生物降解性能有显著的提高。 相似文献