绿色化工环保技术与环境治理的关系

我国化工产业的不断发展,带动了我国经济的飞速发展,给人们的生活带来了许多便利条件,但是与此同时也对我国的环境造成了严重的破坏,化工生产用到许多化学材料,在生产过程中会产生大量的化学废弃物,对环境的污染造成很严重的影响。我国对化工生产给环境保护造成的影响高度重视,随着绿色化工环保技术的出现,有效解决了化工产业造成的环境污染问题,对我国的环境问题进行了有效的改善,对我国工业的发展具有重要意义。本文针对绿色化工环保技术进行分析,探讨绿色化工环保技术在环境治理中的有效应用。     

Review: recent advances in biogas purifying technologies

Biomethane production through biogas upgrading is a promising renewable energy for some industries which could be part of the equilibrium needed with fossil fuels consumption to achieve a sustainable society. This paper presents a comprehensive list of biogas upgrading technologies focused on carbon dioxide removal as well as recent advances reported by researcher with wide expertise in this topic. Additionally, an extensive costs–performance comparison among the technologies studied is discussed. Among the different alternatives, chemical scrubbing stood out to achieve high biomethane purities while cryogenic technologies proved to be effective against methane losses. Regarding the different costs, water scrubbing and membrane separation seem to be the most affordable techniques.     

2010—2019年台州市市区降水化学组成特征及变化趋势

为了解台州市市区大气降水化学成分组成特征及变化规律,对2010—2019年台州市市区降水监测数据进行了统计分析。结果表明:2010—2019年降水样品pH为4.20～4.84夏高冬低,强酸性降水频率下降显著,电导率平均值为3.16 mS/cm。SO_4~(2-)和NO_3~-是降水中最主要的阴离子,NH_4~+和Ca~(2+)是降水中最主要的阳离子。Ca~(2+)浓度在2018年开始有所抬升,SO_4~(2-)和NO_3~-浓度整体呈波动下降趋势。SO_4~(2-)与NO_3~-浓度比均值为1.50,呈下降趋势,同大气中SO_2与NO_2的质量浓度比变化趋势基本一致。SO_4~(2-)和NO_3~-相关性显著,Cl~-、Na~+及Mg~(2+)三者之间具有较好相关性。降水与气态污染物相关性不大,对颗粒物有明显冲刷去除作用。SO_2和NO_x的排放量显著下降,酸雨污染呈现改善过程。     

2016—2020年全国化工和危险化学品事故分析研究*

为分析“十三五”期间（2016—2020年）我国化工和危险化学品事故发生情况，统计“十三五”期间化工和危险化学品事故数量及死亡人数，从发生月份、发生区域、行业分布等方面分析事故特征，从事故类别、事故环节、关键作业等方面分析事故原因，总结2011—2020年我国化工和危险化学品事故发展趋势，按照全国4大经济区域研究2013—2020年事故特征。结果表明:“十三五”期间我国化工和危险化学品事故数量呈下降趋势，死亡人数出现波动，总体形势较为平稳。2011—2020年化工和危险化学品事故风险向中西部转移趋势明显，东北、西部地区事故死亡率普遍高于东部地区。研究结果可为相关行业从业者及监管部门提供决策参考。     

Safety assessment of the film boiling chemical vapor infiltration (FB-CVI) process through a system-theoretic accident model and process (STAMP)

Film boiling chemical vapor infiltration (FB-CVI) is considered as one of the fastest process methodologies for manufacturing carbon-carbon (C–C) composite products and possesses various advantages compared to conventional methodologies. However, there are safety concerns associated with this process for large-scale manufacturing, mainly owing to the intrinsic nature of the precursor and the process conditions. Considering the multifunctional interactions of the various systems during the process, a system-theoretic process analysis (STPA)/system theoretic accident model and process (STAMP) model is used to perform a safety analysis of the hazardous states of the FB-CVI process at the system level. As a case study, the FB-CVI process equipment employed for the manufacturing of C–C composites is considered. The safety constraints present in the system are assessed for adequacy through a hazard analysis by STPA/STAMP. The analysis through STPA/STAMP demonstrated the capability to create proactive strategies for the design and realization of process equipment that can be employed to manufacture C–C composite products through the FB-CVI process.     

Application of environmentally conscious manufacturing strategies for an automotive component

Application of appropriate environmentally conscious manufacturing strategies enables the sustainable development of products and processes. Automotive component manufacturers recognise the potential of applying appropriate strategies for attaining Triple Bottom Line benefits. In this context, three strategies such as eco-efficiency, waste minimisation and material efficiency are being applied to minimise environmental impacts associated with the manufacture of automotive products and its associated processes. A case study of an automotive component manufacturing firm has been exemplified. After conducting the study, the potential environmental impact was reduced by 20% and eco-efficiency was improved by 13%. Further, improvements have been observed in terms of overall resource consumption and material efficiency. The overall power consumption was reduced by 18% and weight of the component was reduced by 11%. The study aimed at improving the sustainable performance of product by incorporating green and environmentally friendlier manufacturing practices.

Abbreviations: USEPA: United Nations Environmental Protection Agency; OECD: Organisation for Economic Co-operation and Development; WBCSD: World Business Council for Sustainable Development; Eco-QFD: Environmental Quality Function Deployment; WCED: World Commission on Environment and Development; LCA: Life Cycle Assessment     

基于GM-SVR的小样本条件下化工设备可靠性预测

为了准确预测化工设备可靠性趋势，针对化工设备失效寿命数据为小样本的情形，基于灰色估计法与支持向量回归机在小样本数据处理中的优势，建立了失效寿命时间服从三参数威布尔分布的化工设备可靠性模型；结合GM（1，1）和SVR对模型进行参数估计，在压缩机可靠性分析中进行了实例应用，对比分析了最小二乘法、灰色估计法和GM-SVR的估计效果。研究结果表明:GM-SVR对威布尔分布参数的估计精度明显优于最小二乘法和灰色估计法，可以有效地应用于化工设备失效数据为小样本时的可靠性预测。     

基于模糊推理的FRAM事故定量分析方法研究

为有效克服FRAM事故分析中无法进行定量分析的缺陷，提出结合模糊推理技术的Fuzzy FRAM模型。此改进模型基于FRAM识别系统运行状态；依据功能输出要素的时间/精度属性利用Matlab构建2阶模糊推理系统量化功能输出质量；根据通用性能条件(CPC)及功能输入耦合端口构建功能评价体系，针对评价体系中存在的不确定性信息融合及建模问题，采用模糊证据推理技术，通过模糊信度结构建立、数据处理、信息融合测度后获得功能的风险指数;以既有铁路危险品运输事故为例，验证方法的可行性。结果表明:Fuzzy FRAM模型的评估结果较为精确，是FRAM分析方法的有效补充。     

典型电脱盐废水预处理技术及其应用

针对原油电脱盐废水处理形势日益严峻的问题,介绍了电脱盐废水预处理技术的研究及应用进展,分析了电脱盐废水预处理技术的原理、特点及应用效果,总结了影响电脱盐废水特点的主要因素,指出改进原油开采技术、提高电脱盐装置的运行和管理水平可从源头上改善电脱盐废水水质,进一步开发和应用先进技术对控制电脱盐废水污染具有积极意义。     

基于ALOHA软件的某化工厂选址合理性评估

为了研究化工厂选址的合理性,以山东省某化工厂为例,采用ALOHA(有害大气空中定位软件)模拟软件定量确定厂区内环氧乙烷毒气扩散事故的影响区域和敏感点毒气浓度,结合GoogleEarth地图对影响范围进行实地拟合。结果表明化工厂的环氧乙烷储罐泄漏后,毒气扩散到厂区范围之外,毒气浓度在50~500ppm之间的重伤区(ERPG-2)扩散距离可达1.7km,对周围居民的人身安全构成严重威胁;厂区应根据拟合结果重新规划工厂中环氧乙烷储罐的位置;ALOHA软件对化工厂选址评价提供了新的手段。