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排序方式: 共有1001条查询结果,搜索用时 15 毫秒
1.
为研究加氢站用高压储氢容器在火灾下的安全性能,采用计算流体力学(CFD)方法对45 MPa高压储氢瓶式容器火烧试验过程进行模拟研究,结合气瓶火烧试验,分析高压储氢容器火灾下的热响应过程,研究不同因素对储氢容器压力泄放装置动作时间的影响。结果表明:613 s以内试验压力与模拟数据的最大相对误差为3.9%,模型误差在可接受范围;不同充装介质对安全泄放装置动作时间影响不大;不同充装压力对容器内介质压升速率影响较大,充装水平较高时压力泄放装置更快动作,较低的充装压力下容器内介质温升较快;不同环境温度对介质温升影响较小。  相似文献   
2.
魏宁  刘胜男  魏凤  李小春 《环境科学》2023,44(12):6621-6629
中国水泥行业面临巨大的碳达峰与碳中和压力.CO2捕集利用与封存(CCUS)技术是能够实现化石资源低碳利用的碳减排技术.在中国水泥企业数据基础上,采用全流程CCUS系统模型(ITEAM-CCUS)评估CCUS的碳减排潜力对水泥企业碳中和非常重要.模型从源汇匹配距离、捕集率、CCUS技术和技术水平这4个方面设置了10种情景,完成了水泥行业的企业筛选、场地筛选、CCUS技术经济评估和源汇匹配,初步回答了水泥企业结合CCUS的封存场地、减排规模、成本范围和优先项目分布等关键问题.在250 km匹配距离、85%净捕集率、CO2-EWR技术和当前技术水平情景,44%的水泥企业可以利用CO2强化地下水开采(CO2-EWR)技术开展碳减排,累计年碳减排量为6.25亿t,平准化成本为290~1838元·t-1;具有全流程CO2-EWR早期示范优势的地区为新疆、内蒙古、宁夏、河南和河北等.水泥企业开展全流程CCUS项目技术可行,可以实现大规模CO2减排,低成本项目具有早期示范机会.研究结果可为水泥行业低碳发展和CCUS商业化部署提供定量参考.  相似文献   
3.
为做好梵净山国家级自然保护区森林植被保护,摸清自然保护区森林植被资源家底,采用2016年第四次森林资源规划设计调查数据及变更至2019年的森林资源数据,计算和分析保护区内森林植被生物量、净生产量、碳储量。梵净山8种森林类型的总生物量为443.72×104t,总碳储量为219.80×104t,总生长量为29.75×104t·a?1,总凋落量为18.65×104t·a?1,总净生产量为48.40×104t·a?1,总生物量、总碳储量较大的是栎林,较小的是铁杉林,桦木林、阔叶混交林、马尾松林、软阔林、杉木林和硬阔林居中;平均碳密度为48.86 t·hm?2,依次为:桦木林>阔叶混交林>栎林>硬阔林>软阔林>马尾松林>杉木林>铁杉林;总生长量、年凋落量、净生产量较高的是栎林、硬阔林,较低的是马尾松林、阔叶混交林和铁杉林,3种森林类型合计比例不到10%;在龄组中的分配依次为:中龄林>近熟林>成熟林>幼龄林>过熟林。在不同海拔中,梵净山森林植被生物量、碳储量、生长量、凋落量和净生产量主要分布在海拔1201—1800 m,其分布比例分别为50.39%、50.38%、49.21%、50.08%和49.54%;在不同坡向中,梵净山森林植被生物量、碳储量、生长量、凋落量和净生产量主要分布在南坡和北坡,二者合计比例大于60%。  相似文献   
4.
为了降低火灾环境下储罐内部介质热响应及储罐失效试验研究的成本和风险,更好地为储罐事故的预测预防提供模拟依据,利用Fluent 12.0软件对密闭容器内部介质的传热传质过程进行模拟,给出了内部介质在受热和冷却条件下相变的控制方程;通过考虑内部介质气化热随温度的变化及饱和温度与区域单元压力之间的关系,编写了内部介质在受热和冷却条件下质量和能量源项的用户自定义函数(UDF);通过对部分参数进行简化,分别给出了喷射火和池火条件下丙烷储罐热响应模拟的结果,并与试验结果进行了对比.结果表明:储罐热响应各主要参数(内部介质温度、壁面温度,储罐内部压力)的误差在喷射火条件下低于15%,在池火条件下低于12.4%.这表明模拟所需源项UDF正确,可以用于现实储罐热响应的模拟.  相似文献   
5.
Portable Fuel Containers (PFCs) made for consumer use can, under unusual circumstances, develop a flammable atmosphere in the container headspace. In order to prevent an inadvertent ignition from causing flame propagation into this headspace and a subsequent explosion or flame jetting, PFC manufacturers are developing prototype Flame Mitigation Devices (FMDs) for installation in the PFC. A test method is described in this paper to determine if the installed FMD will indeed prevent flame entry into the PFC in a high-challenge flame propagation scenario. The method entails the use of a butane-air mixture ignited in a 5 cm diameter, 12 cm long tube attached to either the container neck or a spout on the container neck. Two concept FMD designs have successfully prevented repeated attempts at flame propagation into the PFC and have also produced encouraging results in tests for fuel flow restriction, duel dispensing nozzle friction, and prolonged fuel exposure. Versions of these tests are currently being promulgated in a draft ASTM standard on PFC FMDs.  相似文献   
6.
龚政  崔宇晗 《化工环保》2019,39(3):289-295
采用共沉淀法合成了三元类水滑石Mg_3Mn_xAl_(1-x)CO_3,通过高温煅烧得到其衍生氧化物Mg_3Mn_xAl_(1-x)O_m,再经浸渍负载Pt或BaO后制得新型NO_x存储/再还原(NSR)催化剂。XRD及SEM表征结果显示,当Mn与Al的摩尔比(Mn/Al)大于1时所制备的Mg_3Mn_xAl_(1-x)O_m有杂晶相出现且发生团聚,结合NO_x存储性能评价结果,确定最优Mn/Al为1。BaO负载不利于NO_x的存储,而当Pt负载量为1%(w)时NO_x存储性能最优,250℃条件下的存储量由负载前的0.52 mmol/g提升至0.61 mmol/g。CO_2与NO_x之间存在较强的竞争吸附。负载1%Pt催化剂的NSR性能评价结果表明,8个稀燃-富燃循环后NO_x的去除率为68%,表明催化剂的还原性能仍需加强。  相似文献   
7.
• The rice growth was promoted by nano-TiO2 of 0.1–100 mg/L. • Nano-TiO2 enhanced the energy storage in photosynthesis. • Nano-TiO2 reduced energy consumption in carbohydrate metabolism and TCA cycle. Titanium dioxide nanoparticle (nano-TiO2), as an excellent UV absorbent and photo-catalyst, has been widely applied in modern industry, thus inevitably discharged into environment. We proposed that nano-TiO2 in soil can promote crop yield through photosynthetic and metabolic disturbance, therefore, we investigated the effects of nano-TiO2 exposure on related physiologic-biochemical properties of rice (Oryza sativa L.). Results showed that rice biomass was increased >30% at every applied dosage (0.1–100 mg/L) of nano-TiO2. The actual photosynthetic rate (Y(II)) significantly increased by 10.0% and 17.2% in the treatments of 10 and 100 mg/L respectively, indicating an increased energy production from photosynthesis. Besides, non-photochemical quenching (Y(NPQ)) significantly decreased by 19.8%–26.0% of the control in all treatments respectively, representing a decline in heat dissipation. Detailed metabolism fingerprinting further revealed that a fortified transformation of monosaccharides (D-fructose, D-galactose, and D-talose) to disaccharides (D-cellobiose, and D-lactose) was accompanied with a weakened citric acid cycle, confirming the decrease of energy consumption in metabolism. All these results elucidated that nano-TiO2 promoted rice growth through the upregulation of energy storage in photosynthesis and the downregulation of energy consumption in metabolism. This study provides a mechanistic understanding of the stress-response hormesis of rice after exposure to nano-TiO2, and provides worthy information on the potential application and risk of nanomaterials in agricultural production.  相似文献   
8.
Steel tanks are widely used in the storage of various chemical liquids, and the blast resistance of the tanks is very important because of the explosiveness of these liquids. To explore a feasible method to improve the blast resistance of steel tanks, the effect of polyurea coating on the blast resistance of steel storage tank is investigated in this paper. The responses of monolithic steel tanks and polyurea coated tanks under blast loads are studied by field blast experiments using TNT explosive, and the results shows that the polyurea layers are effective in reducing the maximum and residual displacements of the tank. Numerical simulations are performed and validated, and the deformation process and stress and strain distribution of the tanks are analyzed accordingly. The increase on the bending moment of the plastic hinge lines of the tanks and the increase of the area density of the cylindrical shell induced by the polyurea layers are believed to be the two main factors contributing to the displacement reduction effect of polyurea in this paper. The validated numerical model is used to study the influence of polyurea layer's thickness on the deflection of the tank, and a nearly inversely proportional relationship between the thickness and the maximum displacement is found. Three deformation modes of the tanks are identified when subjected to blast load with varying intensity and it is found that the displacement reduction effect of polyurea varies in different deformation modes.  相似文献   
9.
Hydrogen is considered an excellent clean fuel with potential applications in several fields. There are serious safety concerns associated with the hydrogen process. These concerns need to be thoroughly understood and addressed to ensure its safe operation. To better understand the safety challenges of hydrogen use, application, and process, it is essential to undertake a detailed risk analysis. This can be achieved by performing detailed consequence modellings and assessing risk using the computational fluid dynamics (CFD) approach. This study comprehensively reviews and analyses safety challenges related to hydrogen, focusing on hydrogen storage, transmission, and application processes. Range of release and dispersion scenarios are investigated to analyse associated hazards. Approaches to quantitative risk assessment are also briefly discussed.  相似文献   
10.
In many industrial installations, particulate solids (cereals, agri-food products, coal, plants, etc.) are stored or processed. Self-heating of these products, which can lead to fires and explosions, can occur in a variety of situations. Examples include large storage at room temperature, formation of a layer on a hot surface, layer deposited on a surface – insulating or conductive – in a hot environment or even storage of product exposed to heating on one side.The main parameters that determine the occurrence of self-heating are the size of the container, the temperature, the residence time and the characteristics of the product. Depending on the type of situation encountered and these implementation conditions, the analysis of self-heating risks must be based on specific models and/or parameters.This paper presents the different variants and combinations of the theoretical model from the theory of thermal runaway to represent self-heating, taking into account in particular the symmetry or asymmetry of heating, reagent consumption and boundary conditions. It also discusses their adaptation to the previous identified industrial situations.Nine products were chosen to be representative of those used in the different considered industrial situations. They were subjected to self-heating basket tests in isothermal ovens in order to determine the parameters for applying the described theoretical models. These results were compared with the results of self-heating tests in layers of different thicknesses in a hot environment, on an insulating or conductive plate, using a specially developed test protocol, as well as with the results of standardized tests of minimum ignition temperature in 5 mm layers.This led to the proposal of the most appropriate theoretical model to represent the self-heating phenomenon for each of the four identified industrial situations.This analysis can promote better design of industrial equipment and production conditions (temperatures, volumes or product flows …) in order to prevent fires and explosions.  相似文献   
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