Greenhouse Gas Inventory for Land Use Change and Forestry in Finland Based on International Guidelines

Mitigation and Adaptation Strategies for Global Change - Guidelines of the Intergovernmental Panel on Climate Change (IPCC) were used to assess a greenhouse gas inventory for land use change and...     

Benefits of applying X-ray computed tomography in bentonite based material research focussed on geological disposal of radioactive waste

Environmental Science and Pollution Research - Bentonite-based geomaterials are included in the designs of geological repository planning in most countries, especially in high-level radioactive...     

Urban Geochemistry: A Multimedia and Multielement Survey of a Small Town in Northern Europe

The concentrations and distributions of chemical elements (Ag, Al, As, Au, Ba, Bi, Ca, Cd, Co, Cr, Cu, Fe, Ga, Hg, K, La, Mg, Mn, Mo, Na, Ni, P, Pb, S, Sb, Sc, Se, Sr, Te, Th, Ti, Tl, U, V, W and Zn) were studied in till, humus and urban soil in Jakobstad, a small town (20,000 inhabitants) in W. Finland. The analyses were performed with ICP-MS after aqua regia leaching of till (n = 37), urban topsoil (n = 32) and subsoil (n = 32), and HNO3 leaching of humus (n = 37). The till and humus samples, collected at the same sites, were divided into urban and rural samples. The urban till was not significantly enriched in metals. In contrast, a majority of the elements occurred in higher concentrations in the urban than the rural humus samples. Statistical and spatial interpretations of the humus data revealed that traffic (Pb, V and Ni), metal industry (Pb, Zn, Bi, Sb and Cr), an abandoned shooting range (Pb and Sb) and other sources contribute to higher metal levels in the urban humus. The urban soil samples were collected at parks, yards, abandoned industrial sites, roadsides, etc. The topsoil samples were enriched in most elements, also by elements not enriched in the urban humus (e.g. Cd). At several sites, the concentrations far exceeded the limit concentrations for contaminated soils in Finland. A large variety of sources were identified or indicated.     

Process chemicals – An ever present concern during plant shutdowns

Chemical accidents during process plant shutdowns may have severe consequences. In spite of this, the safety management systems in place in many companies still mainly cover the normal operations and little explicitly addresses the maintenance shutdown and plant start-up phases. A Finnish research project found that the level of safety during shutdowns is more closely related to the skills of key individuals at the plants and less due to the systematic safety management system of the companies. A guidebook on the topic in conjunction with tools to improve the situation were developed during the project in order to help the companies improve their documentation associated with chemical safety during shutdowns.     

Effect of weathering on abundance and release of potentially toxic elements in soils developed on Lower Cambrian black shales, P. R. China

This paper examines the geochemical features of 8 soil profiles developed on metalliferous black shales distributed in the central parts of the South China black shale horizon. The concentrations of 21 trace elements and 8 major elements were determined using ICP-MS and XRF, respectively, and weathering intensity (W) was calculated according to a new technique recently proposed in the literature. The data showed that the black shale soils inherited a heterogeneous geochemical character from their parent materials. A partial least square regression model and EF_bedrock (enrichment factor normalized to underlying bedrock) indicated that W was not a major control in the redistribution of trace metals. Barium, Sn, Cu, V, and U tended to be leached in the upper soil horizons and trapped by Al and Fe oxides, whereas Sb, Cd, and Mo with negative EF values across the whole profiles may have been leached out during the first stage of pedogenesis (mainly weathering of black shale). Compared with the Chinese average soils, the soils were strongly enriched in the potentially toxic metals Mo, Cd, Sb, Sn, U, V, Cu, and Ba, among which the 5 first listed were enriched to the highest degrees. Elevated concentrations of these toxic metals can have a long-term negative effect on human health, in particular, the soils in mining areas dominated by strongly acidic conditions. As a whole, the black shale soils have much in common with acid sulfate soils. Therefore, black shale soils together with acid sulfate soils deserve more attention in the context of metal exposure and human health.     

Comparing the greenhouse gas emissions from three alternative waste combustion concepts

Three alternative condensing mode power and combined heat and power (CHP) waste-to-energy concepts were compared in terms of their impacts on the greenhouse gas (GHG) emissions from a heat and power generation system. The concepts included (i) grate, (ii) bubbling fluidised bed (BFB) and (iii) circulating fluidised bed (CFB) combustion of waste. The BFB and CFB take advantage of advanced combustion technology which enabled them to reach electric efficiency up to 35% and 41% in condensing mode, respectively, whereas 28% (based on the lower heating value) was applied for the grate fired unit. A simple energy system model was applied in calculating the GHG emissions in different scenarios where coal or natural gas was substituted in power generation and mix of fuel oil and natural gas in heat generation by waste combustion. Landfilling and waste transportation were not considered in the model. GHG emissions were reduced significantly in all of the considered scenarios where the waste combustion concepts substituted coal based power generation. With the exception of condensing mode grate incinerator the different waste combustion scenarios resulted approximately in 1 Mton of fossil CO₂-eq. emission reduction per 1 Mton of municipal solid waste (MSW) incinerated. When natural gas based power generation was substituted by electricity from the waste combustion significant GHG emission reductions were not achieved.     

Model Computations on Sequestration of Carbon in Managed Forests and Wood Products under Changing Climatic Conditions in Finland

The aim of this study was to assess the effects of forest management on carbon sequestration in forests and wood products by using a gap-type forest model interfaced with a wood product model. The assessment is based on total carbon sequestration, i.e. the amount of carbon left in vegetation, litter, soil organic matter and products when the flows of carbon back to the atmosphere have been subtracted. Thirty mixed-species stands, representing medium fertility sites in southern Finland, were included in each simulation for 300 years under current climatic conditions and predicted conditions of changing climate. The average total balance for the first 100 years was higher in the unmanaged system than in the managed system, but for the second and third 100-year periods the results were clearly opposite. Differences in the total balance between the treatments were larger during the first 100 years than over the whole 300-year period. Under conditions of changing climate, differences in carbon sequestration between management options were more pronounced than under current climatic conditions. Under current climatic conditions with the 100-year time frame, the ratio between the total annual balance and annual gross production was 0·208–0·289. Over the whole 300 years, however, efficiency was much lower, 0·088–0·121. Under changing climatic conditions, efficiency was also lower, 0·182–0·252 and 0·081–0·096, respectively. Different management alternatives clearly produced different amounts of timber for the production process; under conditions of changing climate, timber production was substantially enhanced. However, total carbon storages at the end of the simulation varied less than timber production. In the managed system, the flow back into the atmosphere was largest from litter, 41–51% of the total outflow, the flow from vegetation was 23–28%, from soil organic matter 22–25%, emissions from products 1–7%, and emissions from landfills 0–3%. If emissions due to the use of machinery in timber harvesting and transportation were included, they made up only 0·03–0·33% of the total outflow.     

Polychlorinated phenols,guaiacols and catechols in environment

Emissions, bioaccumulation and possible food chain enrichment of polychlorinated phenols, guaiacols and catechols have been studied by analyses of water, snow, ash, benthic animal, fish and bird samples in Finland. Seventeen individual compounds were analyzed using authentic reference model compounds and internal standard by GC/ECD. Although the enrichment potential of the studied compounds appeared to be lower than that of the chlorinated hydrocarbons, they proved to be very general pollutants and some of them showed specific bioaccumulation to certain species and high persistency thus forming environmental hazards.     

Determinants of parental effort: a behavioural study in the Eurasian kestrel,Falco tinnunculus

We recorded behaviour of kestrels (Falco tinnunculus) in western Finland during the courtship (1988–1992), incubation (1989–1991), early nestling (age of young 1–2 weeks, 1989–1992) and late nestling stages (3–4 weeks, 1989–1991) to examine determinants of their parental effort (PE). In males, PE was estimated as the hunting effort (the proportion of budget time spent in flight-hunting) and in females as the food provisioning rate (number of prey items delivered to the nest per hour). The following predictions derived from the parental investment theory were examined. (1) Parents rearing large clutches and broods should invest more in breeding than do parents rearing small clutches and broods. The hunting effort of parents did not increase with clutch or brood size, but males tending large broods had a higher prey delivery rate than males tending small broods (Figs 1–2). (2) PE of parents should increase in the course of the breeding season. In males, this was true only between the incubation and early nestling phases (Fig. 3). (3) The early pairs should invest more in breeding than late ones. This tended to be true during the early (for males) and late nestling phases (for females) (Fig. 4). (4) There should be a negative correlation between PE of mates within pairs, but no evidence for such adjustment was found (Fig. 5). (5) Females mated with bright-coloured attractive males should show higher PE than females mated with dull-coloured males but our results were inconsistent with this prediction. We conclude that PE decisions of kestrels are mainly based on cost-benefit estimates of residual reproductive value, rather than on current investment indicators, like clutch or brood size. This might be beneficial in environments with highly variable survival prospects of offspring caused by pronounced among-year variation in abundance of the main food (microtine rodents). The results also show that hypotheses explaining variation in PE in the short term are not necessarily valid for long-term PE, e.g. tending clutches or broods, which also reflects the demands of female and young.     

Increased deposition of polychlorinated biphenyls (PCBs) under an AC high-voltage power line

There is considerable public concern regarding the potential risks to health of electromagnetic fields in general and high-voltage power lines in particular. As epidemiological findings are not supported by a clearly defined mechanism of direct magnetic field interactions with the human body, potential indirect effects are of interest. It has been suggested that an increased exposure to chemical pollutants could occur near high-voltage power lines due to formation and deposition of charged aerosols. The current study reports empirical evidence that seems to support this hypothesis. The deposition of 18 congeners of polychlorinated biphenyls (PCBs) was studied by collecting samples of pine needles under a 400 kV AC power line and at reference sites in the vicinity. Compared to the reference sites, the average deposition of PCB congeners under the power line was almost double. This difference between the two groups of samples was statistically significant. While it is premature to draw any conclusions regarding the human exposure near high-voltage power lines, the issue deserves attention and further investigations.