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Maia Lana S. Balieiro Lorena C. S. Teixeira Ericson J. O. Rodrigues Luciano M. Rosa Derval S. Mulinari Daniella R. 《Journal of Material Cycles and Waste Management》2023,25(4):2295-2311
Journal of Material Cycles and Waste Management - The use of lignocellulosic fibers as fillers in polymer matrices has aroused the interest of the scientific community and industrial sectors. In... 相似文献
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Barbosa Rennan Felix da Silva Zanini Noelle Cardoso Mulinari Daniella Regina Rosa Derval dos Santos 《Journal of Polymers and the Environment》2022,30(9):3852-3864
Journal of Polymers and the Environment - Exposure to potentially toxic metallic elements (PTME) released in watercourses by industries results in irreversible damage to living beings or even... 相似文献
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Cortat Lucas Ornellas Zanini Noelle C. Barbosa Rennan F. S. de Souza Alana G. Rosa Derval S. Mulinari Daniella R. 《Journal of Polymers and the Environment》2021,29(10):3210-3226
Journal of Polymers and the Environment - Macadamia is a nut widely used globally in food, personal hygiene products, and human health. After removing the nut, high amounts of the shell residual,... 相似文献
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Biodegradable Polyester-Based Blend Reinforced with Curauá Fiber: Thermal,Mechanical and Biodegradation Behaviour 总被引:1,自引:1,他引:0
Fernanda Harnnecker Derval dos Santos Rosa Denise Maria Lenz 《Journal of Polymers and the Environment》2012,20(1):237-244
Biodegradable composites can be produced by the combination of biodegradable polymers (BP) as matrix and vegetal fibers as
reinforcement. Composites of a commercial biodegradable polymer blend and curauá fibers (loaded at 5, 15 and 20 wt%) were
prepared by melt mixing in a twin-screw extruder. Chemical treatments such as alkali treatment of the fiber and addition of
maleic anhydride grafted polypropylene (MA-g-PP) as coupling agent were performed to promote polymer/fiber interfacial adhesion so that mechanical performance can be
improved. The resulting composites were evaluated through hardness, melt flow index and tensile, flexural and impact strengths
as well as water absorption. Thermal analysis and Fourier transform infrared spectroscopy were also employed to characterize
the composites. The polymer/fiber interface was investigated through scanning electron microscopy analysis. The biodegradability
of composites was evaluated by compost-soil burial test. The addition of curauá fiber promoted an increase in the mechanical
strengths and composites treated with 2 wt% MA-g-PP with 20 wt% curauá fiber showed an increase of nearly 75% in tensile and 56% in flexural strengths besides an improvement
in impact strength with respect to neat polymer blend. Nevertheless, treated composites showed an increase in water absorption
and biodegradation tests showed that the addition of fiber retards degradation time. The retained mass of BP/20 wt% fiber
composite with MA-g-PP and neat BP was 68 and 26%, respectively, after 210 days of degradation test. 相似文献
5.
Derval dos Santos Rosa Maria Regina Calil Cristina das Graças Fassina Guedes Carlos Eduardo O. Santos 《Journal of Polymers and the Environment》2001,9(3):109-113
The biodegradability of poly--hydroxybutyrate and poly--caprolactone in soil compostage before and after irradiation of the polymers for 192, 425, and 600 h in a Weather-Ometer was examined. The biodegradability tests were done in soil compostage at pH 7.0, 9.0, and 11.0 to assess the influence of this parameter on degradation. The rate of degradation was directly proportional to the soil alkalinity. Poly--hydroxybutyrate showed the greatest weight loss and aging in a Weather-Ometer did not significantly increase the biodegradation, except when the polymer was aged for 425 h and buried in soil compostage of pH 11.0. 相似文献
6.
Derval?dos?Santos RosaEmail author Maria?Regina?Calil Cristina?das?Gra?as?Fassina?Guedes Túlio?César?Rodrigues 《Journal of Polymers and the Environment》2004,12(4):239-245
The biodegradability of poly--hydroxybutyrate (PHB), poly--hydroxybutyrate-co-valerate (PHB-V) and poly--caprolactone (PCL) were examined following thermal aging in an oven for 192, 425 and 600 h. Different temperatures, 100, 120 and 140°C for PHB and PHB-V and 30, 40 and 50oC for PCL were used to assess the influence of this parameter on biodegradation. The biodegradability tests were done in soil compostage at pH 11.0 and involved measuring the residual mass of polymer. Thermal analysis of the polymers was done using a differential scanning calorimeter (DSC). The melting temperature and crystallinity were also determined. Thermal ageing increased the biodegradability only for PHB at 120 and 140oC, and there was no correlation between crystallinity and the biodegradation of the polymers. 相似文献
7.
José Eduardo Volponi Lúcia Helena Innocentini Mei Derval dos Santos Rosa 《Journal of Polymers and the Environment》2004,12(1):11-16
The widespread use of polymeric materials in many applications requires polymers that are weather resistant. The aim of this study is to examine the usefulness of oxidation onset temperature measurements as a tool for evaluating oxidative degradation of isotatic polypropylene. Differential scanning calorimetry was used to measure the oxidation onset temperature in formulations of isotatic polypropylene containing different concentrations of light and thermal stabilizers after aging in a Weather-Ometer. Oxidation onset temperature gave better results than oxidation induction time for evaluating the degradation of isotatic polypropylene during aging in a Weather-Ometer. However, both tests showed a poor correlation with the appearance of cracks seen by optical microscopy. 相似文献
8.
de Oliveira Sueli Aparecida Camani Paulo Henrique da Silva Barbosa Rennan Felix Rocha Daniel Belchior Mitra Sushanta K. dos Santos Rosa Derval 《Journal of Polymers and the Environment》2022,30(1):270-294
Journal of Polymers and the Environment - There is a scientific consensus that the use of membranes for water filtration presents itself as a promising research area for removing a wide range of... 相似文献
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