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Journal of Polymers and the Environment - Outdoor building materials made of wood require preservatives containing chromated copper arsenate and other carcinogenic substances but still are subject...  相似文献   
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Adav SS  Chen MY  Lee DJ  Ren NQ 《Chemosphere》2007,67(8):1566-1572
Aerobic granules effectively degrade phenol at high concentrations from which no Acinetobacter species, that can effectively degrade high concentrations of phenol, have ever been isolated from aerobic granules. The phenol-fed aerobic granule studied was made by merging several smaller granules, each with a core of proteins and nucleic acids surrounded by an outer layer enriched with polysaccharides. In the present study, a strain of Acinetobacter sp. was isolated from the phenol-fed aerobic granules and was identified using DNA sequencing. The fluorescent in situ hybridisation combined with the confocal laser scanning microscope test revealed that the isolated Acinetobacter strain was mainly distributed in the core regime of granule. Batch tests revealed that the suspended Acinetobacter strain could effectively degrade phenol at an initial phenol concentration of up to 1000 mg l(-1) with no cell growth taking place at a phenol concentration of 1500 mg l(-1). The Haldane model describes the inhibitory kinetics of the phenol degradation data. The suspended Acinetobacter strain had a propensity to attach to the surface of sterilized polyurethane foam at a concentration of 12.3mg dry cells mg(-1) dry foam. The immobilized cells could not only degrade phenol at a rate similar to the suspended cells at phenol concentration of 500 mg l(-1), but also effectively degraded phenol at 1500 mg l(-1). The polysaccharides outer layer protected the Acinetobacter strain from phenol's toxicity; while the strain may also contribute to bioaggregation of the granule for its high propensity to attach to solid surface.  相似文献   
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In this study, sulfuric acid and potassium hydroxide are used as the electrolytes, separated by proton exchange membrane, to produce hydrogen. The effects of electrolyte concentrations, applied voltage, single or dual cells, and temperature on the hydrogen production rate and energy efficiency are investigated. Experimental results show that the amount of hydrogen production increases with voltage, and the dual electrolytes and cells can yield the best hydrogen production rate and energy efficiency. With 1-M KOH plus 1-M H2SO4 as electrolytes in separated cells, the highest hydrogen production rate is about 0.95 L/hr. Results also show that the rise of electrolyte temperature can significantly increase the hydrogen production rate up to 50%, and the energy efficiency up to 20%. Keeping a low PH value in cathodeand high anode PH value in anode indeed enhances the efficiency of hydrogen production rate.  相似文献   
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