Determination of Cu and Ni incorporation ratios in Portland cement clinker

Cu and Ni are metals found in galvanic sludges; these sludges are considered hazardous due to their heavy metal content. The main objective of this work is to determine the incorporation amount of Cu and Ni in Portland clinker when a galvanic sludge containing these metals is added to the clinker raw-material. The influence of this addition on the clinkering reactions is evaluated as well as the possibility of co-incinerating galvanic sludges containing Cu and Ni in rotary cement kilns. This study also characterizes the galvanic sludge. Samples were prepared by additions from 0.25 to 5 wt.% of a galvanic sludge to an industrial clinker raw-material. The clinkering process was simulated in a laboratory device. The following techniques were applied to characterize the raw materials and the products of the tests: chemical analysis, differential thermal analysis (DTA) and thermogravimetric analysis (TG). Leaching tests were performed in the produced clinker samples in order to verify the incorporation of the studied metals in the clinker structure. The results led to the conclusion that additions of up to 2 wt.% of a galvanic sludge containing 2.4 wt.%Cu and 1.2 wt.% Ni to clinker raw-material do not affect the clinkering reactions and that these metals are totally incorporated into the clinker.     

Socioeconomic indicators and the survival of the tropical rainforest of cross river state of Nigeria

An internal household survey of socioeconomic indicators in the Cross River State forest communities showed that basic infrastructural facilities such as clean water supply, adequate waste disposal system, good roads and electricity are grossly inadequate. There is a total absence of modern family planning practices in the communities, and population is projected to increase by 44.8% between 2000 and 2015 and 85.4% between 2000 and 2025. The study revealed that about 65% of the population of the rainforest communities consists of subsistence farmers and power chain operators, and besides the 19% of the Cross River State Tropical High Forestry (THF) already reported to have been lost to agriculture and plantation between 1972 and 1991, about 9% was lost between 1991 and 2000. An additional 25% of the THF will be lost by 2025, leaving only 470600 hectares (4706 km²). With 84.1% of community members having an annual income less than $300, the survival potential of the Cross River State rainforest in the next fifty years is very low, unless an effective forest management programme is encouraged by government in partnership with all stakeholders.