AVGWLF‐Based Estimation of Nonpoint Source Nitrogen Loads Generated Within Long Island Sound Subwatersheds1

Abstract: The Generalized Watershed Loading Functions (GWLF) model and its ArcView interface (AVGWLF) were used to estimate and examine the components of the total nitrogen (TN) nonpoint source (NPS) load generated within New York and Connecticut (CT) watersheds surrounding Long Island Sound (LIS, the Sound). The majority of data used as model inputs were generally available from online sources, and the work involved an overall calibration to streamflow and TN data in accordance with generic guidelines recommended in the GWLF manual. The GWLF model performance for three calibration and two validation watersheds in CT was compared with results of a detailed model, Hydrological Simulation Program in Fortran, developed in a previous study. The results of the application illustrate the usefulness of the relatively simpler, less parameter‐intensive GWLF model in performing exploratory loading analysis in preparation for adaptive nutrient management in the LIS watersheds. The presented methodology is valuable for identification of priority watersheds for NPS pollution reduction and also for planning‐level evaluation of best management practices to achieve the desired reductions. It is estimated that ground‐water base flow may be the largest pathway for NPS TN to the Sound, contributing about 54% of the total NPS TN load, a finding with significant implications for LIS total maximum daily load reduction scenarios. In addition to ground water, septic systems are estimated to contribute about 17% of the total load, with the remaining TN load being mostly runoff from urban (17%), agricultural (5%), and low impact (e.g., forest) areas (6%).     

粉尘在巷道中的紊流传递分析

建立的粉尘在巷道中的传递方程是一个二维平流扩散输运方程。在巷道顶底板为吸收壁的条件下，导出了粉尘浓度分布函数。传统的工业沉降室沉降效率公式（横向混合模型）只是论文所列方程的一个特例。降低紊流强度和减小紊流扩散系数和纵向弥散系数均可提高沉降效率     

重力作用下尘粒运动的数值解法

提出了重力作用下尘粒运动的数值解法。依据尘粒的重力、浮力及所受到的阻力推出了尘粒自然沉降时的运动方程。当尘粒的运动在斯托克斯领域内时采用理论公式求解其运动轨迹,当尘粒的运动进入非斯托克斯领域内时,提出了修正斯托克斯公式的方法以达到用理论公式来近似模拟该领域内的尘粒自然沉降运动     

Leaching mechanisms of Cr(VI) from chromite ore processing residue

Batch leaching tests, qualitative and quantitative x-ray powder diffraction (XRPD) analyses, and geochemical modeling were used to investigate the leaching mechanisms of Cr(VI) from chromite ore processing residue (COPR) samples obtained from an urban area in Hudson County, New Jersey. The pH of the leaching solutions was adjusted to cover a wide range between 1 and 12.5. The concentration levels for total chromium (Cr) and Cr(VI) in the leaching solutions were virtually identical for pH values >5. For pH values <5, the concentration of total Cr exceeded that of Cr(VI) with the difference between the two attributed to Cr(III). Geochemical modeling results indicated that the solubility of Cr(VI) is controlled by Cr(VI)-hydrocalumite and Cr(VI)-ettringite at pH >10.5 and by adsorption at pH <8. However, experimental results suggested that Cr(VI) solubility is controlled partially by Cr(VI)-hydrocalumite at pH >10.5 and by hydrotalcites at pH >8 in addition to adsorption of anionic chromate species onto inherently present metal oxides and hydroxides at pH <8. As pH decreased to <10, most of the Cr(VI) bearing minerals become unstable and their dissolution contributes to the increase in Cr(VI) concentration in the leachate solution. At low pH ( <1.5), Cr(III) solid phases and the oxides responsible for Cr(VI) adsorption dissolve and release Cr(III) and Cr(VI) into solution.