Migration of aluminum from food contact materials to food—a health risk for consumers? Part III of III: migration of aluminum to food from camping dishes and utensils made of aluminum

Background

When cooking on a barbecue grill, consumers often use aluminum grill pans. For one, the pan catches the fats and oils that would drip into the embers causing the formation of potentially noxious smoke, and the pan also protects the food from being burned by direct heat from the coals. In addition, new aluminum products for use in ovens and grills are becoming increasingly popular. Due to their light weight and excellent heat transfer camping, utensils made of aluminum are, for example, often used by fishermen and mountain climbers. Preparing food in aluminum utensils can, however, result in migration of the aluminum to the foodstuffs.

Results/Conclusions

In this study presented here, it was found that the transfer limit of 5.00 mg/L for aluminum is not exceeded using simulants for oil or for tap water; however, with an aqueous solution of 0.5% citric acid, the limit is clearly exceeded at 638 mg/L. This means that the Tolerable Weekly Intake (TWI) is exceeded by 298% for a child weighing 15 kg and for an adult weighing 70 kg it is equivalent to 63.8% of the TWI, assuming a daily uptake of 10 mL marinade containing lemon juice over a period of 1 week. Preparation of a fish dish with a marinade containing lemon juice in camping dishes would result in the TWI being exceeded by 871% for a child weighing 15 kg and by 187% for an adult weighing 70 kg assuming a daily uptake of 250 g over a period of 1 week.

     

Towards a multi‐foci approach to workplace aggression: A meta‐analytic review of outcomes from different perpetrators

Using meta‐analysis, we compare three attitudinal outcomes (i.e., job satisfaction, affective commitment, and turnover intent), three behavioral outcomes (i.e., interpersonal deviance, organizational deviance, and work performance), and four health‐related outcomes (i.e., general health, depression, emotional exhaustion, and physical well being) of workplace aggression from three different sources: Supervisors, co‐workers, and outsiders. Results from 66 samples show that supervisor aggression has the strongest adverse effects across the attitudinal and behavioral outcomes. Co‐worker aggression had stronger effects than outsider aggression on the attitudinal and behavioral outcomes, whereas there was no significant difference between supervisor, co‐worker, and outsider aggression for the majority of the health‐related outcomes. These results have implications for how workplace aggression is conceptualized and measured, and we propose new research questions that emphasize a multi‐foci approach. Copyright © 2009 John Wiley & Sons, Ltd.     

Mass transfer coefficients for volatilization of polychlorinated biphenyls from the Hudson River,New York measured using micrometeorological approaches

Air–water exchange is an important process controlling the fate of many organic chemicals in the environment. Modeling this process is hampered by the lack of direct observations. Thus, the purpose of this work was to derive direct measurements of the mass transfer coefficients for air–water exchange (v_aw) of polychlorinated biphenyls (PCBs) that may be used to check the validity of values derived from tracer gas experiments. v_aw values for PCBs were determined using previously published turbulent fluxes divided by the corresponding dissolved phase concentrations. The median v_aw values for each homolog decreased with increasing molecular weight and ranged from 0.29 for hexachlorobiphenyls to 2.2 m d^?1 for monochlorobiphenyls with a propagated uncertainty of about 70%, lower than in previous studies. Due to relatively low wind speeds and possible sorption of PCBs to colloids, these numbers may be biased low. These field measurements of v_aw differ by as much as a factor of 23 from predictions based on the widely-used Whitman two-film model. Therefore a new formulation for the calculation of v_aw based on field measurements is needed. This study demonstrates that micrometeorological approaches are a viable option for the measurement of v_aw for hydrophobic organics such as PCBs and should be used to generate enough field data on the air–water exchange of hydrophobic organics to allow the development of new predictive models.     

Associative learning of odor with food- or blood-meal by Culex quinquefasciatus Say (Diptera: Culicidae)

The ability of many insects to learn has been documented. However, a limited number of studies examining associative learning in medically important arthropods has been published. Investigations into the associative learning capabilities of Culex quinquefasciatus Say were conducted by adapting methods commonly used in experiments involving Hymenoptera. Male and female mosquitoes were able to learn a conditioned stimulus that consisted of an odor not normally encountered in nature (synthetic strawberry or vanilla extracts) in association with an unconditioned stimulus consisting of either a sugar (males and females) or blood (females) meal. Such information could lead to a better understanding of the ability of mosquitoes to locate and select host and food resources in nature.     

Leaching study of polycyclic aromatic hydrocarbon bioavailability from a coal-derived solid product

The leaching behavior of selected four- to six-ring polycyclic aromatic hydrocarbons (PAH) from a tumorigenic coal-derived solid product was determined using three media to evaluate their potential bioavailabilities. Equilibrium PAH concentrations generally exceeded the aqueous solubilities after less than five days of leaching. PAH selectively accumulated in phospholipid vesicles at individual concentrations greater than 1 μg/g, which is ca. 100-fold over that in the bulk aqueous leachate. The results suggest that the PAH are quite bioavailable from the solid product, and that cell membranes can be exposed to considerable quantities of these PAH over an extended bioassay.     

Idiosyncratic deals in contemporary organizations: A qualitative and meta‐analytical review

Idiosyncratic deals (i‐deals) research focuses on the emergence of customized work arrangements employees negotiate with their employers. This article provides a critical review and synthesis of i‐deals research, combining a qualitative review of i‐deals theory and research with a supplementary meta‐analysis of 23 empirical studies (k = 27 samples, N = 8110 individuals). The qualitative review examines the conceptualization and measurement of i‐deals and identifies patterns and gaps in i‐deals research, while the quantitative meta‐analysis tests the moderating effect of societal cultures on the predictors and consequences of ideals investigated to date. In each section, attention is given to strengths and weaknesses of current approaches to i‐deals theory and research. Future research directions are identified with particular emphasis on the largely unexamined role of i‐deals from a multilevel perspective. Copyright © 2014 John Wiley & Sons, Ltd.