Specific Conductance and pH as Indicators of Watershed Disturbance in Streams of the New Jersey Pinelands, USA

/ We used linear regression to independently and jointly relate specific conductance and pH measured at New Jersey Pinelands stream sites to the percentage of altered land in a watershed. Percentage altered land included developed and agricultural land uses and represented watershed disturbance for a given site. Median values calculated for a 2-year period (September 1992 through August 1994) characterized pH and specific conductance at the study sites. We found the relationships between the median values for both water-quality measures and percentage altered land for a site to be consistent across subregion and dominant altered-land use. Our results also demonstrated that the water-quality/altered-land relationships developed using median values were similar to relationships developed using data from any single-sample period within the entire study period. Individually, pH and specific conductance explained 48% and 56%, respectively, of the variability in watershed disturbance among study sites. The joint use of pH and specific conductance explained 79% of the watershed disturbance variability among sites. The joint use of these easily obtained water-quality measures can provide a quick assessment of instream water-quality impacts from upstream watershed disturbance at any Pinelands stream site. Additionally, a range in pH and specific conductance, and hence a range in ambient water quality, can be predicted for a given altered-land percentage or a change in existing altered-land conditions.     

USING REFERENCE SITES AND SIMPLE LINEAR REGRESSION TO ESTIMATE LONG‐TERM WATER LEVELS IN COASTAL PLAIN FORESTS1

ABSTRACT: The ability of regulators, resource managers, and consultants to assess accurately wetland hydrology is crucial when identifying and delineating wetlands. In this study, simple linear regression and long‐term (ten year) New Jersey Pinelands stream gaging and pitch pine lowland water‐level data sets were used to estimate long‐term hydroperiods at lowland test sites with short‐term (two year) records. Separate regression equations were developed for each test site using reference site data and stream gaging data, and two sets of equations for selected test sites were produced using two different short‐term periods of record. Test sites had long‐term records ranging from four to ten years, allowing validation of the regression models. Measured and predicted test site growing season water levels were similar regardless of which short‐term period of record was used. The results based on the stream gaging site data were similar, although the difference between measured and estimated growing season water levels was greater when this approach was used. Excellent agreement was found between measured and estimated frequencies of near‐surface saturation at test sites for each growing season month, and these relationships improved when cumulative, seasonal frequencies were considered. The reference wetland approach used in this study may have its greatest value in regions with both high development pressures and problem wetlands and may provide an effective way of resolving costly wetland delineation disputes.     

Assessing land-use/water-quality relationships across contrasting geologic areas in New Jersey

In all, 13 stream water-quality parameters, including specific conductance (SC), pH, dissolved oxygen (DO), dissolved organic carbon (DOC), three nutrients, and six major ions were compared between the northern bedrock and southern coastal plain regions of New Jersey, USA and related to watershed-disturbance gradients characterized by the percentage of urban land, impervious surface (IS), agriculture, and altered land (sum of urban land and agriculture) in the watersheds. SC, DO, calcium, magnesium, sodium, and chloride concentrations were greater in the north. DOC was higher and pH was lower in the south. Nutrient, potassium, and sulfate concentrations did not differ between regions. Regional water-quality differences are attributed to geologic setting and land use. Except for DO in southern streams, all water-quality parameters were related to urban land, agriculture, or both. Significant correlations between urban land and IS and water-quality variables were similar in both regions with differences in unitless correlation coefficients ranging from 0.00 to 0.06. Compared to urban land and agriculture, relationships between most water-quality variables and altered land were stronger in the south. The extent of urban and agricultural lands in the watersheds did not differ by region. Altered land was correlated with urban land in both regions and with agriculture only in the south. Although focused on New Jersey, this study has broader implications for watershed planning.     

Landscape Changes in the Mullica River Basin of the Pinelands National Reserve,New Jersey,USA

In 1979, the Pinelands Commission was established as a regional land-use planning and regulatory agency charged with the implementation of a Comprehensive Management Plan (CMP) for the Pinelands National Reserve (New Jersey, USA). The CMP was created to balance land preservation and development interests in the Reserve. Because water-quality degradation from developed and agricultural landscapes is associated with changes in the composition of biological communities, monitoring landscape changes provides one of the most direct measures of the impact of land-use policies on the Pinelands ecosystem. In this study, we prepared detailed, land-cover maps within randomly selected aerial-photograph plots for a major watershed in the Reserve. We used these land-cover maps to quantify changes in landscape composition and structure (i.e., patch size, patch area, and number of patches) and characterize land-cover transitions in the basin between 1979 and 1991. Because the study period represented the first 12 years of the regional-planning effort in the Reserve, we evaluated the relationship between land-cover transitions and Commission management-area designations which permit different land-use intensities. Although the landscape composition was similar in 1979 and 1991, we found an increase in the total area and number of developed-land, managed-grassland, and barren-land patches. An increase in the number of patches and a decrease in the total area and median and third-quartile patch sizes for forest land and for all patches regardless of cover type indicated that fragmentation of forest land and the landscape as a whole occurred during the study period. The major land-cover transitions that occurred during the period were the loss of forest land to development and associated cover types and the conversion of one agricultural type to another. Overall, land-cover transitions during the period were found to be consistent with the Commission management-area designations, which indicated that the regional-planning effort has been successful in directing human activities to appropriate areas of the basin.     

WETLAND BOUNDARIES IN THE NEW JERSEY PINELANDS: ECOLOGICAL RELATIONSHIPS AND DELINEATION1

Wetland protection regulations and guidelines often require the delineation of precise wetland boundaries on a case-by-case basis. In this study, conducted in the New Jersey Pinelands, an ecological characterization of vegetation composition, soil and hydrologic relationships along upland to wetland Pinus rigida - dominated transittions provided the basis for a multiparameter approach to wetland boundary delineation. The transitional data set was analyzed by direct gradient analysis, cluster analysis and ordination. It is concluded that vegetation composition can be a principal factor in delineating wetland boundaries along natural upland to wetland transitions. However, where distinct vegetation changes are not observed, a feature of our study sites, a multiparameter approach should be used.     

Chemical composition and Zn bioavailability of the soil solution extracted from Zn amended variable charge soils

A study on variable charge soils (volcanic Italian and podzolic Scottish soils) was performed to investigate the influence of soil properties on the chemical composition of soil solution. Zinc speciation, bioavailability and toxicity in the soil solution were examined. The soils were spiked with increasing amounts of Zn (0, 100, 200, 400 and 1000 mg/kg) and the soil solutions were extracted using rhizon soil moisture samplers. The pH, total organic carbon (TOC), base cations, anions, total Zn and free Zn2+ in soil solution were analysed. A rapid bioassay with the luminescent bacterium Escherichia coli HB101 pUCD607 was performed to assess Zn toxicity. The influence of soil type and Zn treatments on the chemical composition of soil solution and on Zn toxicity was considered and discussed. Di erent trends of total and free Zn concentrations, base cations desorption and luminescence of E. coli HB101 pUCD607 were observed. The soil solution extracted from the volcanic soils had very low total and free Zn concentrations and showed specific Zn2+/Ca2+ exchange. The soil solution from the podzolic soil had much higher total and free Zn concentrations and showed no evidence of specific Zn2+/Ca2+ exchange. In comparison with the subalkaline volcanic soils, the acidic podzol showed enhanced levels of toxic free Zn2+ and consequently stronger effects on E. coli viability.     

Impact of river overflowing on trace element contamination of volcanic soils in south Italy: part I. Trace element speciation in relation to soil properties

Volcanic soils affected by different numbers of polluted river flooding events were investigated. Chromium and Cu were the major soil contaminants. Nickel, Fe, Zn and Mn total content never exceeded the Italian mandatory limits. The distribution of Cr and Cu total contents among studied soils indicated that only Cr contamination was related to overflowing events. In polluted soils, sequential chemical extractions revealed a preferential association of Cr and Cu with organic forms. A progressive Cr insolubilization with ageing was observed. Significant amounts of Cr and Cu were extracted by NH(4)-oxalate, suggesting metals association with short-range-order aluminosilicates and organo-mineral complexes. Possible methodological drawbacks in the use of the EU-BCR chemical speciation protocol on volcanic soils are discussed. Micromorphology and SEM/WDS analyses revealed Cr and Cu enriched silt and clay coatings in surface and subsurface soil horizons, suggesting a transfer of metal-rich sediments along the soil pore network with water movement.     

CHARACTERIZATION OF SURFACE WATER QUALITY ALONG A WATERSHED DISTURBANCE GRADIENT1

ABSTRACT. Characterizing ecological indicators such as water quality is necessary to effectively manage human-dominated systems such as the New Jersey Pinelands. Pinelands surface waters are naturally acidic and low in nutrients and other dissolved substances. Water quality for 14 Pinelands stream sites monitored by the U.S. Geological Survey was characterized in relation to land use. A gradient of increasing pH, specific conductance, and concentration of dissolved calcium, dissolved magnesium, total nitrite + nitrate-nitrogen, total ammonia-nitrogen, and total phosphorus was associated with a watershed disturbance gradient of increasing land use intensity and waste water flow. These two parallel gradients emphasized the significant effect that watershed disturbance can have on natural water chemistry in the Pinelands. The results of this study can be applied to planning and regulatory programs in the Pinelands.     

Distribution of Diatoms in Relation to Land Use and pH in Blackwater Coastal Plain Streams

We compared the composition of diatom assemblages collected from New Jersey Pinelands blackwater streams draining four different land uses, including forest land, abandoned-cranberry bogs, active-cranberry bogs, and developed and upland-agricultural land. Over a 2-year period (2002-2003), we collected 132 diatom taxa at 14 stream sites. Between-year variability in the composition of stream samples was high. Most diatom species were rarely encountered and were found in low abundance. Specific conductance and pH were higher at developed/agricultural sites compared with all other site types. Neither species richness nor genus richness was significantly different between stream types. However, clear community patterns were evident, and a significant difference in species composition existed between the developed/agricultural sites and both cranberry and forest sites. The primary community gradient, represented by the first axis of a DCA ordination, was associated with variations in pH and specific conductance. Although community patterns revealed by ordinating the data collected in 2002 differed from those obtained using the 2003 data, both ordinations contrasted the developed/agricultural sites and the other sites. Acidobiontic and acidophilous diatoms characterized the dominant species at forest, abandoned-bog, and cranberry sites, whereas indifferent species dominated the developed/agricultural samples. Although our study demonstrated a relationship between the composition of diatom assemblages and watershed conditions, several factors, including taxonomic problems, the large number of diatom species, incomplete pH classifications, and year-to-year variability may limit the utility of diatom species as indicators of watershed conditions in the New Jersey Pinelands.